Nazarov reaction: current trends and recent advances in the synthesis of natural compounds and their analogs

The progress in the chemistry of N-acyliminium ions and their use in stereoselective organic synthesis

(2017) M G Vinogradov et al.   RUSSIAN CHEMICAL REVIEWS

Nazarov cyclization of 1,4-pentadien-3-ols: preparation of cyclopenta[b]indoles and spiro[indene-1,4′-quinoline]s

(2016) Zhiming Wang et al.   CHEMICAL COMMUNICATIONS

Challenges in the development of organic and hybrid molecular systems

(2016) Valentine P. Ananikov et al.   MENDELEEV COMMUNICATIONS

One-pot relay catalysis: divergent synthesis of furo[3,4-b]indoles and cyclopenta[b]indoles from 3-(2-aminophenyl)-1,4-enynols

(2016) Manisha Manisha et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Nazarov cyclization of divinyl ketones bearing an ester group at the β-position: a remarkable effect of α-substitution and alkene geometry on regioselectivity

(2016) Gangarajula Sudhakar et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Approach to Merosesquiterpenes via Lewis Acid Catalyzed Nazarov-Type Cyclization: Total Synthesis of Akaol A

(2016) Badrinath N. Kakde et al.   ORGANIC LETTERS

The first intermolecular interrupted imino-Nazarov reaction: expeditious access to carbocyclic nucleoside analogues

(2016) Ronny William et al.   Chemical Science

A photo-induced C–C bond formation methodology to construct tetrahydrofluorenones and their related structures

(2016) Shujun Cai et al.   Organic Chemistry Frontiers

Enantioselective Palladium(0)-Catalyzed Nazarov-Type Cyclization

(2015) Kei Kitamura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An efficient synthesis of pyrido[1,2-a]indoles through aza-Nazarov type cyclization

(2015) Iyyanar Karthikeyan et al.   CHEMICAL COMMUNICATIONS

Cu-catalyzed transannulation reaction of pyridotriazoles: general access to fused polycyclic indolizines

(2015) Yi Shi et al.   CHEMICAL COMMUNICATIONS

Nazarov Cyclization of Divinyl and Arylvinyl Epoxides: Application in the Synthesis of Resveratrol-Based Natural Products

(2015) Gangarajula Sudhakar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Annulated N-Heterocycles by Tandem Gold(I)-Catalyzed [3,3]-Rearrangement/Nazarov Reaction of Propargylic Ester Derivatives: an Experimental and Computational Study

(2015) Martina Petrović et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Interception of Nazarov Reactions of Allenyl Vinyl Ketones with Dienes: (3+2)- versus (4+3)-Cycloaddition and Subsequent Rearrangement

(2015) Timothy D. R. Morgan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Nazarov Reactions Intercepted by (4 + 3) Cycloadditions with Oxygen-Substituted Dienes

(2015) François M. LeFort et al.   JOURNAL OF ORGANIC CHEMISTRY

Torquoselectivity in the Nazarov Reactions of Allenyl Vinyl Ketones

(2015) Timothy D. R. Morgan et al.   JOURNAL OF ORGANIC CHEMISTRY

Total Synthesis of (±)-Taiwaniaquinol F and Related Taiwaniaquinoids

(2015) Badrinath N. Kakde et al.   JOURNAL OF ORGANIC CHEMISTRY

Origins of the Stereoselectivity in a Thiourea–Primary Amine-Catalyzed Nazarov Cyclization

(2015) Austin H. Asari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic Asymmetric Tandem Nazarov Cyclization/Semipinacol Rearrangement: Rapid Construction of Chiral Spiro[4.4]nonane-1,6-diones

(2015) Bin-Miao Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

4π electrocyclisation in domino processes: contemporary trends and synthetic applications towards natural products

(2015) Nadeem S. Sheikh   ORGANIC & BIOMOLECULAR CHEMISTRY

Assembly of functionalized carbocycles or N-heterocycles through a domino electrocyclization–[1,2] migration reaction sequence

(2015) Navendu Jana et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

One-Pot Relay Gold(I) and Brønsted Acid Catalysis: Cyclopenta[b]annulation of Indoles via Hydroamination/Nazarov-Type Cyclization Cascade of Enynols

(2015) Seema Dhiman et al.   ORGANIC LETTERS

Hydroxylamine catalyzed Nazarov cyclizations of divinyl ketones

(2015) Joseph Z. Hamilton et al.   TETRAHEDRON LETTERS

Enantioselective Nazarov cyclization catalyzed by a cinchona alkaloid derivative

(2015) Yu-Wen Huang et al.   TETRAHEDRON LETTERS

Cooperative benzylic–oxyallylic stabilized cations: regioselective construction of α-quaternary centers in ketone-derived compounds

(2015) Nitin S. Dange et al.   Chemical Science

Lewis acid catalyzed Nazarov type cyclization for the synthesis of a substituted indane framework: total synthesis of (±)-mutisianthol

(2015) Dattatraya H. Dethe et al.   Organic Chemistry Frontiers

Au(i) π-bis(tert-butyldimethylsilyl)acetylene triphenylphosphine complex, an effective pre-catalyst for Au(i)-catalyzed reactions

(2015) Dapeng Zhu et al.   Organic Chemistry Frontiers

Efficient catalytic enantioselective Nazarov cyclizations of divinyl ketoesters

(2015) Zhou Xu et al.   Organic Chemistry Frontiers

Synthesis of (±)-Tetrapetalone A-Me Aglycon

(2014) Peter N. Carlsen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of theIsodonDiterpene Sculponeatin N

(2014) Benjamin J. Moritz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of Gracilamine

(2014) Yingbo Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Experimental and Computational Study of the Catalytic Asymmetric 4π-Electrocyclization of N-Heterocycles

(2014) Sadiya Raja et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

α-Hydroxycyclopentanones via one-pot oxidation of the trimethylaluminum-mediated Nazarov reaction with triplet oxygen

(2014) Yonghoon Kwon et al.   CHEMICAL COMMUNICATIONS

Cyclization and annulation reactions of nitrogen-substituted cyclopropanes and cyclobutanes

(2014) F. de Nanteuil et al.   CHEMICAL COMMUNICATIONS

The Photo-Nazarov Reaction: Scope and Application

(2014) Shujun Cai et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Nazarov Cyclization: A Valuable Method to Synthesize Fully Substituted Carbon Stereocenters

(2014) Donald R. Wenz et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ready Access to Alkylidenecyclopentenones by Nazarov Cyclization/β-Elimination of 2-Hydroxyalkyl-1,4-dien-3-ones

(2014) Owen Scadeng et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Convergent Access to Polycyclic Cyclopentanoids from α,β-Unsaturated Acid Chlorides and Alkynes through a Reductive Coupling, Nazarov Cyclization Sequence

(2014) Jason H. Chaplin et al.   JOURNAL OF ORGANIC CHEMISTRY

Protecting-Group-Free Synthesis of Taiwaniaquinone H Using a One-Pot Thermal Ring Expansion/4π-Electrocyclization Strategy

(2014) Xiuxiang Yan et al.   JOURNAL OF ORGANIC CHEMISTRY

Experimental and Computational Studies on Interrupted Nazarov Reactions: Exploration of Umpolung Reactivity at the α-Carbon of Cyclopentanones

(2014) Yen-Ku Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nazarov-like cyclization reactions

(2014) Martin J. Di Grandi   ORGANIC & BIOMOLECULAR CHEMISTRY

Cationic Cyclizations and Rearrangements Promoted by a Heterogeneous Gold Catalyst

(2014) Tulaza Vaidya et al.   ORGANIC LETTERS

Gold(I)/(III)-Catalyzed Rearrangement of Divinyl Ketones and Acyloxyalkynyloxiranes into Cyclopentenones

(2014) Marie Hoffmann et al.   ORGANIC LETTERS

Formal Homologous Aldol Reactions: Interrupting the Nazarov Cyclization via Carboalkoxylation of Alkynes

(2014) Yen-Ku Wu et al.   ORGANIC LETTERS

Catalysis and Chemodivergence in the Interrupted, Formal Homo-Nazarov Cyclization Using Allylsilanes

(2014) Raynold Shenje et al.   ORGANIC LETTERS

Titanium-mediated cross-coupling reactions of 1,3-butadiynes with α-iminonitriles to 3-aminopyrroles: observation of an imino aza-Nazarov cyclization

(2014) Xu You et al.   Organic Chemistry Frontiers

Diastereospecific Nazarov Cyclization of Fully Substituted Dienones: Generation of Vicinal All-Carbon-Atom Quaternary Stereocenters

(2013) Anais Jolit et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Allene ether Nazarov cyclization

(2013) Marcus A. Tius   CHEMICAL SOCIETY REVIEWS

Efficient Nazarov Cyclization/Wagner-Meerwein Rearrangement Terminated by a CuII-Promoted Oxidation: Synthesis of 4-Alkylidene Cyclopentenones

(2013) David Lebœuf et al.   CHEMISTRY-A EUROPEAN JOURNAL

Beyond the Divinyl Ketone: Innovations in the Generation and Nazarov Cyclization of Pentadienyl Cation Intermediates

(2013) William T. Spencer III et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Lewis acid–surfactant-combined catalyzed synthesis of 4-aminocyclopentenones from glycals in water

(2013) Siming Wang et al.   GREEN CHEMISTRY

Salen Promoted Enantioselective Nazarov Cyclizations of Activated and Unactivated Dienones

(2013) Gerri E. Hutson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient synthesis of trifluoromethylated cyclopentadienes/fulvenes/norbornenes from divinyl ketones

(2013) Xiao Liu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Nazarov Reactions of Vinyl Cyclopropylamines: An Approach to the Imino-Nazarov Problem

(2013) Sara A. Bonderoff et al.   ORGANIC LETTERS

Synthesis of 2-bromo-1-aryl-1 H -indenes via a Ag(I) promoted domino 2π-electrocyclic ring-opening/4π-electrocyclization reaction of 1,2-diaryl substituted gem -dibromocyclopropanes

(2013) Gregory Rosocha et al.   TETRAHEDRON

Bioinspired Total Synthesis of Agelastatin A

(2012) Jeremy Chris P. Reyes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Neutral Nazarov-Type Cyclization Catalyzed by Palladium(0)

(2012) Naoyuki Shimada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Brønsted Acid-Catalyzed Nazarov Cyclization of Acyclic α-Alkoxy Dienones

(2012) Sadiya Raja et al.   Chemistry-An Asian Journal

Total Synthesis of (±)-Rocaglamide via Oxidation-Initiated Nazarov Cyclization

(2012) John A. Malona et al.   JOURNAL OF ORGANIC CHEMISTRY

Formal Synthesis of (±)-Methyl Rocaglate Using an Unprecedented Acetyl Bromide Mediated Nazarov Reaction

(2012) Philip Magnus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and Theoretical Studies on the Nazarov Cyclization/Wagner–Meerwein Rearrangement Sequence

(2012) David Lebœuf et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Approach to Highly Substituted Cyclopentanoids from a Concise Formal Synthesis of (+)-Roseophilin

(2012) Daniel J. Kerr et al.   ORGANIC LETTERS

α-Aryl-Substituted Allenamides in an Imino-Nazarov Cyclization Cascade Catalyzed by Au(I)

(2012) Zhi-Xiong Ma et al.   ORGANIC LETTERS

Mild boronic acid catalyzed Nazarov cyclization of divinyl alcohols in tandem with Diels–Alder cycloaddition

(2012) Hongchao Zheng et al.   TETRAHEDRON LETTERS

Using Nazarov Electrocyclization to Stage Chemoselective [1,2]-Migrations: Stereoselective Synthesis of Functionalized Cyclopentenones

(2011) David Lebœuf et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of ent-Nanolobatolide

(2011) Hau Man Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Nazarov Cyclization: The State of the Art

(2011) Tulaza Vaidya et al.   ChemCatChem

Solvent controlled mechanistic dichotomy in a Au(iii)-catalyzed, heterocyclization triggered, Nazarov reaction

(2011) Marie E. Krafft et al.   CHEMICAL COMMUNICATIONS

Chiral Brønsted acids in enantioselective carbonyl activations – activation modes and applications

(2011) Magnus Rueping et al.   CHEMICAL SOCIETY REVIEWS

Charge Delocalization and Enhanced Acidity in Tricationic Superelectrophiles

(2011) Rajasekhar Reddy Naredla et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

PtI2-Catalyzed tandem 3,3-rearrangement/Nazarov reaction of arylpropargylic esters: synthesis of indanone derivatives

(2011) Huaiji Zheng et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Application of Nazarov type electrocyclization to access [6,5,6] and [6,5,5] core embedded new polycycles: an easy entry to tetrahydrofluorene scaffolds related to Taiwaniaquinoids and C-nor-D homosteroids

(2011) Ritesh Singh et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Concise Total Synthesis of (±)-Cephalotaxine via a Transannulation Strategy: Development of a Facile Reductive oxy-Nazarov Cyclization

(2011) Wei-Dong Z. Li et al.   ORGANIC LETTERS

Homologous Mukaiyama Reactions via Trapping of the Nazarov Intermediate with Silyloxyalkenes

(2011) Yen-Ku Wu et al.   ORGANIC LETTERS

Enantiospecific synthesis of the ABC and ABD ring systems of the marine diterpenes aberraranes

(2011) A. Srikrishna et al.   TETRAHEDRON

Asymmetric Nazarov cyclizations

(2011) Naoyuki Shimada et al.   TETRAHEDRON

A concise total synthesis of bruceolline E

(2011) Jason A. Jordan et al.   TETRAHEDRON LETTERS

Asymmetric Nazarov Reaction Catalyzed by Chiral Tris(oxazoline)/Copper(II)

(2010) Peng Cao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Highly Reactive Dicationic Iridium(III) Catalyst for the Polarized Nazarov Cyclization Reaction

(2010) Tulaza Vaidya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic asymmetric aza-Nazarov cyclization of an azirine

(2010) Naoyuki Shimada et al.   CHEMICAL COMMUNICATIONS

The (4+3)-cycloaddition reaction: simple allylic cations as dienophiles

(2010) Michael Harmata   CHEMICAL COMMUNICATIONS

Brønsted Acid-Mediated Nazarov Cyclization of Vinylallenes

(2010) Yen-Ku Wu et al.   JOURNAL OF ORGANIC CHEMISTRY

An Organocatalytic Asymmetric Nazarov Cyclization

(2010) Ashok K. Basak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nazarov Cyclizations of an Allenyl Vinyl Ketone with Interception of the Oxyallyl Cation Intermediate for the Formation of Carbon−Carbon Bonds

(2010) Vanessa M. Marx et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbo- and heterocyclisation of oxygen- and nitrogen-containing electrophiles by platinum, gold, silver and copper species

(2010) Arindam Das et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A Novel Approach to Indoloditerpenes by Nazarov Photocyclization: Synthesis and Biological Investigations of Terpendole E Analogues

(2010) Fátima Churruca et al.   ORGANIC LETTERS

Oxidation-Initiated Nazarov Cyclization of Vinyl Alkoxyallenes

(2010) William T. Spencer et al.   ORGANIC LETTERS

Intermolecular [3 + 3]-Cycloadditions of Azides with the Nazarov Intermediate

(2010) Owen Scadeng et al.   ORGANIC LETTERS

Total synthesis of (±)-xanthocidin using FeCl3-mediated Nazarov reaction

(2010) Kentaro Yaji et al.   TETRAHEDRON

Construction of a fully substituted cyclopentenone as the core skeleton of stemonamide via a Nazarov cyclization

(2010) Kentaro Yaji et al.   TETRAHEDRON LETTERS

Aza-Nazarov cyclization cascades

(2010) Kiran Kumar Solingapuram Sai et al.   TETRAHEDRON LETTERS

Chiral synthons from campholenaldehyde: enantiospecific synthesis of diquinane and linear triquinanes

(2010) Adusumilli Srikrishna et al.   TETRAHEDRON-ASYMMETRY

Silver and Brønsted Acid Catalyzed Nazarov-Type Cyclizations To Generate Benzofulvenes

(2009) Pierre Cordier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Interrupting the Nazarov reaction: domino and cascade processes utilizing cyclopentenyl cations

(2009) Tina N. Grant et al.   CHEMICAL COMMUNICATIONS

1,5-Diaryl-3-oxo-1,4-pentadienes: A Case for Antineoplastics with Multiple Targets

(2009) U. Das et al.   CURRENT MEDICINAL CHEMISTRY

Nazarov Cyclization Initiated by Peracid Oxidation: The Total Synthesis of (±)-Rocaglamide

(2009) John A. Malona et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Application of Nazarov cyclization to access [6-5-6] and [6-5-5]tricyclic core embedded new heterocycles: an easy entry to structures related to Taiwaniaquinoids

(2009) Ritesh Singh et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A new class of conjugated strigolactone analogues with fluorescent properties: synthesis and biological activity

(2009) Chaitali Bhattacharya et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of 5-Hydroxycyclopent-2-enones from Allenyl Vinyl Ketones via an Interrupted Nazarov Cyclization

(2009) Vanessa M. Marx et al.   ORGANIC LETTERS

Enamine-Iminium Ion Nazarov Cyclization of α-Ketoenones

(2009) William F. Bow et al.   ORGANIC LETTERS

Formation of halogenated cyclopent-2-enone derivatives by interrupted Nazarov cyclizations

(2009) Vanessa M. Marx et al.   TETRAHEDRON LETTERS

Gold(I)-Catalyzed Tandem Reactions Initiated by 1,2-Indole Migrations

(2008) Roberto Sanz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of aryl-substituted triquinanes through the interrupted Nazarov reaction

(2008) Curtis J. Rieder et al.   CHEMICAL COMMUNICATIONS

Ni(ii)-catalyzed enantioselective Nazarov cyclizations

(2008) Irene Walz et al.   CHEMICAL COMMUNICATIONS

2H-Pyrrole Derivatives from an Aza-Nazarov Reaction Cascade Involving Indole as the Neutral Leaving Group

(2008) Nugzar Ghavtadze et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis and Structure Revision of Nakiterpiosin

(2008) Shuanhu Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Synthesis of Polycyclic Enones from Carbon Tethered 1,3-Enynyl Carbonyls via Tandem Heteroenyne Metathesis and Nazarov Reaction

(2008) Tienan Jin et al.   ORGANIC LETTERS

Interrupting the Nazarov Cyclization with Indoles§

(2008) Ashok K. Basak et al.   ORGANIC LETTERS

Intermolecular Reaction of Internal Alkynes and Imines: Propargyl Tosylates as Key Partners in a Gold-Catalyzed [4 + 1] Unusual Cyclization Leading to Cyclopent-2-enimines

(2008) Samuel Suárez-Pantiga et al.   ORGANIC LETTERS

Total Synthesis of (±)-Merrilactone A

(2007) Wei He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY