期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 131, 期 4, 页码 1410-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja808110d
关键词
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资金
- NIH [R01-GM079554]
- Welch Foundation [I-1596]
- UT Southwestern
- Southwestern Medical Foundation Scholar
This manuscript describes a convergent synthesis and the revision of the relative stereochemistry of nakiterpiosin, a marine C-nor-D-homosteroid. Our synthesis features a late-stage carbonylative Stille cross-coupling reaction and a photo-Nazarov cyclization reaction that deliver the complete nakiterpiosin skeleton efficiently.
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