期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 135, 期 13, 页码 4988-4991出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja401908m
关键词
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资金
- NIH [GM069990]
- UNCF/Merck
- GlaxoSmithKline
- Bristol-Myers Squibb
A novel class of chiral 5,5'-di(2,4,6-trialkyl)-aryl salen-metal complexes have been developed and shown to catalyze highly enantioselective Nazarov cyclization reactions, giving rise to cyclopentenoids in 90:10-98:2 er. Significantly, the catalysts also promote, for the first time, highly enantioselective Nazarov reactions of unactivated dienones, producing hydrindenone products having in place three contiguous chiral centers.
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