Catalytic diastereo- and enantioselective additions of versatile allyl groups to N–H ketimines

Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes

(2016) Richard Y. Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Generation of Adjacent Stereocenters in a Copper-Catalyzed Three-Component Coupling of Imines, Allenes, and Diboranes

(2016) Kay Yeung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Homoallylic Boronates by Chemo-, SN2′-, Diastereo- and Enantioselective Catalytic Sequence of Cu−H Addition to Vinyl-B(pin)/Allylic Substitution

(2016) Jaehee Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Short Enantioselective Total Syntheses of trans-Clerodane Diterpenoids: Convergent Fragment Coupling Using a trans-Decalin Tertiary Radical Generated from a Tertiary Alcohol Precursor

(2016) Yuriy Slutskyy et al.   JOURNAL OF ORGANIC CHEMISTRY

Tri(1-adamantyl)phosphine: Expanding the Boundary of Electron-Releasing Character Available to Organophosphorus Compounds

(2016) Liye Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dispersion-Energy-Driven Wagner–Meerwein Rearrangements in Oligosilanes

(2016) Lena Albers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

London Dispersion in Molecular Chemistry-Reconsidering Steric Effects

(2015) J. Philipp Wagner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Discovery of a Series of Efficient, Centrally Efficacious BACE1 Inhibitors through Structure-Based Drug Design

(2015) Christopher R. Butler et al.   JOURNAL OF MEDICINAL CHEMISTRY

N-Heterocyclic Carbene–Copper-Catalyzed Group-, Site-, and Enantioselective Allylic Substitution with a Readily Accessible Propargyl(pinacolato)boron Reagent: Utility in Stereoselective Synthesis and Mechanistic Attributes

(2015) Ying Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity

(2015) Yi-Shuang Zhao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

The Isomerization of Allylrhodium Intermediates in the Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines

(2014) Hamish B. Hepburn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Asymmetric Mannich-Type Reaction of α-Isocyanoacetates with Ketimines using Cinchona Alkaloid/Copper(II) Catalysts

(2014) Masashi Hayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Diastereoselective and Enantiospecific Allylation of Ketones and Imines Using Borinic Esters: Contiguous Quaternary Stereogenic Centers

(2014) Jack L.-Y. Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and structure–activity relationship of dihydrobenzofuran derivatives as novel human GPR119 agonists

(2014) Xiang-Yang Ye et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Diastereo- and Enantioselective Reactions of Bis(pinacolato)diboron, 1,3-Enynes, and Aldehydes Catalyzed by an Easily Accessible Bisphosphine–Cu Complex

(2014) Fanke Meng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Broadly Applicable NHC–Cu-Catalyzed Approach for Efficient, Site-, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis

(2014) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Olefin Hydroamination with Aminium Radical Cations: A Photoredox Method for Direct C–N Bond Formation

(2014) Andrew J. Musacchio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multifunctional organoboron compounds for scalable natural product synthesis

(2014) Fanke Meng et al.   NATURE

Catalytic Enantioselective Protoboration of Disubstituted Allenes. Access to Alkenylboron Compounds in High Enantiomeric Purity

(2014) Hwanjong Jang et al.   ORGANIC LETTERS

Enantioselective Synthesis of Quaternary Carbon Stereogenic Centers through Copper-Catalyzed Conjugate Additions of Aryl- and Alkylaluminum Reagents to Acyclic Trisubstituted Enones

(2013) Jennifer A. Dabrowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cu-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their In Situ Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones

(2013) Fanke Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Allylation of Ketimines by Using Palladium Pincer Complexes with Chiral Bis(imidazoline)s

(2013) Shuichi Nakamura et al.   CHEMISTRY-A EUROPEAN JOURNAL

ExceptionallyE- and β-Selective NHC-Cu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes

(2013) Fanke Meng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Sulfination of Aryl and Heteroaryl Halides: Direct Access to Sulfones and Sulfonamides

(2013) Andrei Shavnya et al.   ORGANIC LETTERS

Enantioselective Rhodium-Catalyzed Nucleophilic Allylation of Cyclic Imines with Allylboron Reagents

(2012) Yunfei Luo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Diastereo- and Enantioselective Mannich Reactions of Synthetically Flexible Ketimines with Secondary Amine Organocatalysts

(2011) Taichi Kano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NHC-Cu-Catalyzed Enantioselective Hydroboration of Acyclic and Exocyclic 1,1-Disubstituted Aryl Alkenes

(2011) Rosa Corberán et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Quaternary centres bearing nitrogen (α-tertiary amines) as products of molecular rearrangements

(2011) Jonathan Clayden et al.   CHEMICAL COMMUNICATIONS

Catalytic Enantioselective Allylation of Carbonyl Compounds and Imines

(2011) Miguel Yus et al.   CHEMICAL REVIEWS

Catalytic Enantioselective Formation of C−C Bonds by Addition to Imines and Hydrazones: A Ten-Year Update

(2011) Shu̅ Kobayashi et al.   CHEMICAL REVIEWS

Discrete, Solvent-Free Alkaline-Earth Metal Cations: Metal···Fluorine Interactions and ROP Catalytic Activity

(2011) Yann Sarazin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

syn-Selective Rhodium(I)-Catalyzed Allylations of Ketimines Proceeding through a Directed CH Activation/Allene Addition Sequence

(2010) Duc N. Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The novel benzopyran class of selective cyclooxygenase-2 inhibitors. Part 2: The second clinical candidate having a shorter and favorable human half-life

(2010) Jane L. Wang et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Enantioselective Construction of Highly Substituted Pyrrolidines by Palladium-Catalyzed Asymmetric [3+2] Cycloaddition of Trimethylenemethane with Ketimines

(2010) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Hydroamination of Unbiased and Functionalized Primary Aminoalkenes Catalyzed by a Rhodium Aminophosphine Complex

(2010) Lisa D. Julian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions

(2010) Aikomari Guzman-Martinez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereoselective Alkylation of Glycinates by Assistance of Intramolecular Potassium⋅⋅⋅Fluorine Interactions

(2009) Takashi Yamazaki et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper(I)-Catalyzed Aryl Bromides To Form Intermolecular and Intramolecular Carbon−Oxygen Bonds

(2009) Jiajia Niu et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Hydrogenation of N−H Imines

(2009) Guohua Hou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Boron−Copper Additions to Aryl-Substituted Alkenes Promoted by NHC−Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC−Cu-Catalyzed Boron−Copper Additions to Terminal Alkynes

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Tertiary Alcohols and α-Tertiary Amines via Cu-Catalyzed C−C Bond Formation to Ketones and Ketimines

(2008) Masakatsu Shibasaki et al.   CHEMICAL REVIEWS

Asymmetric Reductive Mannich Reaction to Ketimines Catalyzed by a Cu(I) Complex

(2008) Yao Du et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ag-Catalyzed Diastereo- and Enantioselective Vinylogous Mannich Reactions of α-Ketoimine Esters. Development of a Method and Investigation of its Mechanism

(2008) Laura C. Wieland et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthetic Access to the Hetisine Alkaloids: Total Synthesis of (+)-Nominine

(2007) Kevin M. Peese et al.   CHEMISTRY-A EUROPEAN JOURNAL