期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 13, 期 14, 页码 4174-4178出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob00322a
关键词
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资金
- 973 Program [2015CB856600]
- National Natural Science Foundation of China [NSFC 21372243, 21232009, 21102161]
- Shanghai Municipal Committee of Science and Technology [13JC1406900]
- Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)
- State Key Laboratory of Bioorganic and Natural Products Chemistry (SIOC)
Copper-catalyzed asymmetric allylation of chiral N-tert-butane-sulfinyl imines has been described. Dual stereocontrol, through the combination of a chiral auxiliary and a chiral copper complex, has played an important role in achieving the nearly perfect diastereo-selectivities (all dr > 99 : 1), especially for ketimine substrates.
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