Rhodium(III)-Catalyzed C–H Activation in Indole: A Comprehensive Report (2017–2022)

Rh(III)‐Catalyzed Csp2‐Csp3 Bond Cleavage/Carbonylethylation of α‐Indolyl Alcohols

(2021) Wei Zeng et al.   ADVANCED SYNTHESIS & CATALYSIS

Additive-Controlled Divergent Synthesis of Tetrasubstituted 1,3-Enynes and Alkynylated 3H-Pyrrolo[1,2-a]indol-3-ones via Rhodium Catalysis

(2021) Fei Zhao et al.   ORGANIC LETTERS

Recent Advances in Metal‐Catalyzed Functionalization of Indoles

(2021) Kelvin Urbina et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(I)‐Catalyzed C2‐Selective Decarbonylative C−H Alkylation of Indoles with Alkyl Carboxylic Acids and Anhydrides

(2021) Haiyang Yu et al.   Asian Journal of Organic Chemistry

Rh(III)-Catalyzed Chemodivergent Annulations between Indoles and Iodonium Carbenes: A Rapid Access to Tricyclic and Tetracyclic N-Heterocylces

(2021) Saiprasad Nunewar et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Divergent Synthesis of Alkynylated Imidazo[1,5-a]indoles and α,α-Difluoromethylene Tetrasubstituted Alkenes

(2021) Fei Zhao et al.   ORGANIC LETTERS

Rh(III)-Catalyzed [5 + 1] Annulation of Indole-enaminones with Diazo Compounds To Form Highly Functionalized Carbazoles

(2021) Zhidong Jiang et al.   ORGANIC LETTERS

Rhodium(III)‐Catalyzed Direct C7‐Selective Alkenylation and Alkylation of Indoles with Maleimides

(2021) Yaoguang Sheng et al.   ADVANCED SYNTHESIS & CATALYSIS

Weak Coordination Enabled Switchable C4-Alkenylation and Alkylation of Indoles with Allyl Alcohols

(2020) Sourav Pradhan et al.   ORGANIC LETTERS

Weak Coordinating Carbonyl-Directed Rhodium(III)-Catalyzed C–H Activation at the C4-Position of Indole with Allyl Alcohols

(2020) Mahadev Sharanappa Sherikar et al.   JOURNAL OF ORGANIC CHEMISTRY

Direct Carbon–Carbon σ Bond Amination of Unstrained Arylalkylketones

(2020) Xinwei Hu et al.   ACS Catalysis

Mechanochemical Solvent‐Free Catalytic C‐H Methylation

(2020) Shengjun Ni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactivity-Controlling Factors in Carboxylate-Assisted C–H Activation under 4d and 3d Transition Metal Catalysis

(2020) Torben Rogge et al.   ACS Catalysis

Rhodium(III)-Catalyzed C–H Alkenylation/Directing Group Migration for the Regio- and Stereoselective Synthesis of Tetrasubstituted Alkenes

(2020) Xiaowei Wu et al.   ORGANIC LETTERS

Harnessing the Chemistry of the Indole Heterocycle to Drive Discoveries in Biology and Medicine

(2019) Verrill M. Norwood IV et al.   CHEMBIOCHEM

Rh(III)-Catalyzed Hydroarylation of Alkyne MIDA Boronates via C–H Activation of Indole Derivatives

(2019) Xiao Fei et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed Selective C–H Trideuteromethylation of Indole at C7 Position Using Acetic-d6 Anhydride

(2019) Xiaowei Han et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed C–H Amidation of 2-Arylindoles with Dioxazolones: A Route to Indolo[1,2-c]quinazolines

(2019) Xiaogang Wang et al.   ORGANIC LETTERS

Chameleon-like Behavior of the Directing Group in the Rh(III)-Catalyzed Regioselective C–H Amidation of Indole: An Experimental and Computational Study

(2019) Jinquan Zhang et al.   ACS Catalysis

Weak Coordination-Guided Regioselective Direct Redox-Neutral C4 Allylation of Indoles with Morita–Baylis–Hillman Adducts

(2019) Sourav Pradhan et al.   ORGANIC LETTERS

Photoredox Catalysis for Building C–C Bonds from C(sp2)–H Bonds

(2018) Chang-Sheng Wang et al.   CHEMICAL REVIEWS

Synthesis of Terminal Vinylindoles via RhIII -Catalyzed Direct C−H Alkenylation with Potassium Vinyltrifluoroborate

(2018) Chun-Ni Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Regioselective Direct C4-Alkylation and C2-Annulation of Indoles: Straightforward Access to Indolopyridone

(2018) Aniruddha Biswas et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Weak Directing Group Steered Formal Oxidative [2+2+2]-Cyclization for Selective Benzannulation of Indoles

(2018) Kiran R. Bettadapur et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalyzed Oxidative Coupling of N-Phenylindole-3-carboxylic Acids with Alkenes and Alkynes via C4–H and C2–H/C2′–H Bond Cleavage

(2018) Takeshi Okada et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed Acceptorless Dehydrogenative Coupling of (Hetero)arenes with 2-Carboxyl Allylic Alcohols

(2018) Jintao Xia et al.   ORGANIC LETTERS

Rhodium(iii)-catalyzed C–H activation at the C4-position of indole: switchable hydroarylation and oxidative Heck-type reactions of maleimides

(2018) Mahadev Sharanappa Sherikar et al.   CHEMICAL COMMUNICATIONS

A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

(2018) Carlo Sambiagio et al.   CHEMICAL SOCIETY REVIEWS

Rhodium(iii)-catalyzed C–H allylation of indoles with allyl alcohols via β-hydroxide elimination

(2018) Xiaowei Wu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Thioether-Directed Selective C4 C–H Alkenylation of Indoles under Rhodium Catalysis

(2018) Chandrababu Naidu Kona et al.   ORGANIC LETTERS

PIII -Chelation-Assisted Indole C7-Arylation, Olefination, Methylation, and Acylation with Carboxylic Acids/Anhydrides by Rhodium Catalysis

(2018) Xiaodong Qiu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh-Catalyzed Removable Directing Group Assisted sp2 or sp3-C-H Bond Functionalization

(2018) Naoto Chatani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

3d Transition Metals for C–H Activation

(2018) Parthasarathy Gandeepan et al.   CHEMICAL REVIEWS

Rhodium(III)-catalyzed C-H alkylation of heterocycles with allylic alcohols in water: A reusable catalytic system for the synthesis of β-aryl ketones

(2018) Xiang Li et al.   TETRAHEDRON

Regioselective Direct C-4 Functionalization of Indole: Total Syntheses of (−)-Agroclavine and (−)-Elymoclavine

(2017) Jianbo Lv et al.   ORGANIC LETTERS

Rhodium-Catalyzed Site-Selective Coupling of Indoles with Diazo Esters: C4-Alkylation versus C2-Annulation

(2017) Xiaohong Chen et al.   ORGANIC LETTERS

Three-Component Catalytic Carboxygenation of Activated Alkenes Enabled by Bimetallic Rh(III)/Cu(II) Catalysis

(2017) Shang-Shi Zhang et al.   ORGANIC LETTERS

Plausible Rh(V) Intermediates in Catalytic C–H Activation Reactions

(2017) Suhelen Vásquez-Céspedes et al.   ACS Catalysis

Enantioselective C–H Annulation of Indoles with Diazo Compounds through a Chiral Rh(III) Catalyst

(2017) Xiaohong Chen et al.   ACS Catalysis

Beyond C2 and C3: Transition-Metal-Catalyzed C–H Functionalization of Indole

(2017) Jamie A. Leitch et al.   ACS Catalysis

Palladium-Catalyzed Transformations of Alkyl C–H Bonds

(2016) Jian He et al.   CHEMICAL REVIEWS

Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

(2016) Joshua R. Hummel et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed Regioselective C7-Olefination of Indazoles Using an N-Amide Directing Group

(2016) Lei Guo et al.   Chemistry-An Asian Journal

Rh(III)-Catalyzed Aryl and Alkenyl C–H Bond Addition to Diverse Nitroalkenes

(2016) Tyler J. Potter et al.   ACS Catalysis

Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

(2016) John F. Hartwig et al.   ACS Central Science

Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

(2015) Guoyong Song et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C–H Functionalizations

(2015) Baihua Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition Metal-Catalyzed CH Activation of Indoles

(2015) Alexander H. Sandtorv   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Regioselective C7-Functionalization of N -Pivaloylindoles

(2015) Lanting Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A review on recent developments of indole-containing antiviral agents

(2015) Ming-Zhi Zhang et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Marine Indole Alkaloids

(2015) Natalie Netz et al.   Marine Drugs

Formal SN-Type Reactions in Rhodium(III)-Catalyzed CH Bond Activation

(2014) Nadine Kuhl et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of most polyene natural product motifs using just 12 building blocks and one coupling reaction

(2014) Eric M. Woerly et al.   Nature Chemistry

A multitasking functional group leads to structural diversity using designer C–H activation reaction cascades

(2014) Ying Chen et al.   Nature Communications

Indole Synthesis by Rhodium(III)-Catalyzed Hydrazine-Directed CH Activation: Redox-Neutral and Traceless by NN Bond Cleavage

(2013) Dongbing Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Redox-Neutral Coupling ofN-Phenoxyacetamides and Alkynes with Tunable Selectivity

(2013) Guixia Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

General and Efficient Synthesis of Indoles through Triazene-Directed C-H Annulation

(2013) Chengming Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-CatalyzedorthoAlkenylation ofN-Phenoxyacetamides withN-Tosylhydrazones or Diazoesters through CH Activation

(2013) Fangdong Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Indole Synthesis Using N–N Bond as an Internal Oxidant

(2013) Baoqing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Synthesis of Unsymmetrical Acridines and Phenazines by a Rh(III)-Catalyzed Amination/Cyclization/Aromatization Cascade

(2013) Yajing Lian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed C–H Olefination for the Synthesis of ortho-Alkenyl Phenols Using an Oxidizing Directing Group

(2013) Yangyang Shen et al.   ORGANIC LETTERS

Palladium-catalyzed benzo[d]isoxazole synthesis by C–H activation/[4 + 1] annulation

(2013) Pingping Duan et al.   Chemical Science

Rhodium(III)-Catalyzed Oxidative CH Functionalization of Azomethine Ylides

(2012) Wencui Zhen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed CH Activation of Arenes Using a Versatile and Removable Triazene Directing Group

(2012) Chengming Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Dehydrogenative Heck Reaction of Salicylaldehydes

(2012) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

(2012) Percia Beatrice Arockiam et al.   CHEMICAL REVIEWS

Ir(I)-Catalyzed C–H Bond Alkylation of C2-Position of Indole with Alkenes: Selective Synthesis of Linear or Branched 2-Alkylindoles

(2012) Shiguang Pan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed Intermolecular Carbenoid Functionalization of Aromatic C–H Bonds by α-Diazomalonates

(2012) Wai-Wing Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights

(2011) Alison E. Wendlandt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

C—H Bond Activation in Transition Metal Species from a Computational Perspective

(2010) David Balcells et al.   CHEMICAL REVIEWS

Overview of the Mechanistic Work on the Concerted Metallation–Deprotonation Pathway

(2010) David Lapointe et al.   CHEMISTRY LETTERS

An Efficient Low-Temperature Route to Polycyclic Isoquinoline Salt Synthesis via C−H Activation with [Cp*MCl2]2(M = Rh, Ir)

(2008) Ling Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents

(2008) Lutz Ackermann et al.   ORGANIC LETTERS