Synthesis of Terminal Vinylindoles via RhIII -Catalyzed Direct C−H Alkenylation with Potassium Vinyltrifluoroborate

2- and 3-Vinylindoles as 4π Components in Cycloaddition Reactions

(2017) Elisabetta Rossi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Transition-Metal-Free Redox-Neutral One-Pot C3-Alkenylation of Indoles Using Aldehydes

(2017) Samrat Sahu et al.   ORGANIC LETTERS

Recent Advances on the Application of Electrocyclic Reactions in Complex Natural Product Synthesis

(2017) Ming Bian et al.   SYNTHESIS-STUTTGART

Cobalt(III)-Catalyzed Hydroarylation of Allenes via C–H Activation

(2017) Sachiyo Nakanowatari et al.   ACS Catalysis

One-pot synthesis of fluorescent 2,4-dialkenylindoles by rhodium-catalyzed dual C–H functionalization

(2017) Hui Chen et al.   Organic Chemistry Frontiers

Cobalt(iii)-catalyzed alkenylation of arenes and 6-arylpurines with terminal alkynes: efficient access to functional dyes

(2016) Shan Wang et al.   CHEMICAL COMMUNICATIONS

Alkenylation of Arenes and Heteroarenes with Alkynes

(2016) Vadim P. Boyarskiy et al.   CHEMICAL REVIEWS

Mild metal-catalyzed C–H activation: examples and concepts

(2016) T. Gensch et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of 3-Acetoxyoxindole Derivatives by Metal-Free PhI(OAc)2-Mediated Oxidation of 3-Substituted Indoles

(2016) Liang Wang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Diketohexenoic Acid Derivatives by Alkenylation of Indoles and Pyrroles with 4-Pyrones

(2016) Dmitrii L. Obydennov et al.   JOURNAL OF ORGANIC CHEMISTRY

Construction of Pyrrolo[1,2-a]indoles via Cobalt(III)-Catalyzed Enaminylation of 1-(Pyrimidin-2-yl)-1H-indoles with Ketenimines and Subsequent Base-Promoted Cyclization

(2016) Xiaorong Zhou et al.   ORGANIC LETTERS

Cobalt(III)-Catalyzed Regio- and Stereoselective α-Fluoroalkenylation of Arenes with gem-Difluorostyrenes

(2016) Lingheng Kong et al.   ORGANIC LETTERS

Substrate Activation Strategies in Rhodium(III)-Catalyzed Selective Functionalization of Arenes

(2015) Guoyong Song et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium(III)-Catalyzed Direct CH Olefination of Arenes with Aliphatic Olefins

(2015) Xiao Xue et al.   ADVANCED SYNTHESIS & CATALYSIS

Oxidative Coupling between Two Hydrocarbons: An Update of Recent C–H Functionalizations

(2015) Chao Liu et al.   CHEMICAL REVIEWS

Pd(II)-Catalyzed CH Activation of Styrylindoles: Short, Efficient, and Regioselective Synthesis of Functionalized Carbazoles

(2015) Rakesh K. Saunthwal et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Stereoselective Ruthenium(II)-Catalyzed Direct C2-syn-Alkenylation of Indoles with Alkynes

(2015) Wei Zhang et al.   ORGANIC LETTERS

Palladium-Catalyzed Triple Successive C–H Functionalization: Direct Synthesis of Functionalized Carbazoles from Indoles

(2015) Akhilesh K. Verma et al.   ORGANIC LETTERS

A Tandem Approach to Functionalized Carbazoles from Indoles via Two Successive Regioselective Oxidative Heck Reactions Followed by Thermal Electrocyclization

(2015) Joydev K. Laha et al.   ORGANIC LETTERS

Divergent Functionalization of Indoles with Acryloyl Silanes via Rhodium-Catalyzed C–H Activation

(2015) Ping Lu et al.   ORGANIC LETTERS

Rhodium-catalyzed regioselective direct C–H arylation of indoles with aryl boronic acids

(2015) Liang Wang et al.   TETRAHEDRON LETTERS

Sequential one-pot Rh(III)-catalyzed direct C2 and C7 alkylation of (hetero)aromatic C–H bonds of indoles

(2015) Liang Wang et al.   TETRAHEDRON LETTERS

Rhodium-catalysed C(sp2)–C(sp2) bond formation via C–H/C–F activation

(2015) Panpan Tian et al.   Nature Communications

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Rhodium(III)-Catalyzed Direct C-2 Olefination of Unactivated Indoles Utilizing OH/NH2as Directing Group

(2014) Chen-Yu Tang et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Regioselective Direct C-2 Alkenylation of Indoles Assisted by the Removable N-(2-Pyrimidyl) Group

(2014) Binwei Gong et al.   ADVANCED SYNTHESIS & CATALYSIS

An Efficient Rhodium/Oxygen Catalytic System for Oxidative Heck Reaction of Indoles and AlkenesviaCH Functionalization

(2014) Lei Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Rh(i)-catalyzed decarbonylative direct C2-olefination of indoles with vinyl carboxylic acids

(2014) Lingjuan Zhang et al.   CHEMICAL COMMUNICATIONS

Ruthenium(II)-Catalyzed Direct Addition of Indole/Pyrrole C2–H Bonds to Alkynes

(2014) Libo Liang et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh-catalyzed oxidative C–C bond formation and C–N bond cleavage: direct access to C2-olefinated free (NH)-indoles and pyrroles

(2014) Satyasheel Sharma et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group

(2013) Luo-Qiang Zhang et al.   CHEMICAL COMMUNICATIONS

Regioselective C2 Oxidative Olefination of Indoles and Pyrroles through Cationic Rhodium(III)-Catalyzed CH Bond Activation

(2013) Bin Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Regioselective C2-Alkenylation of Indoles Using the N-Benzoyl Directing Group: An Efficient Ru-Catalyzed Coupling Reaction

(2013) Veeranjaneyulu Lanke et al.   ORGANIC LETTERS

One-shot indole-to-carbazole π-extension by a Pd–Cu–Ag trimetallic system

(2013) Kyohei Ozaki et al.   Chemical Science

Mild and Efficient C2-Alkenylation of Indoles with Alkynes Catalyzed by a Cobalt Complex

(2012) Zhenhua Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Progress in palladium-based catalytic systems for the sustainable synthesis of annulated heterocycles: a focus on indole backbones

(2012) Mélanie Platon et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective [4+2] Cycloadditions of 2-Vinyl-1 H-indoles with 3-Nitro-2 H-chromenes Catalyzed by a Zn(OTf)2/Bis(oxazoline) Complex: An Efficient Approach to Fused Heterocycles with a Quaternary Stereocenter

(2012) Fen Tan et al.   Chemistry-An Asian Journal

FeCl3·6H2O-Catalyzed Alkenylation of Indoles with Aldehydes

(2012) Qin Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Intermolecular C3 Alkenylation of Indoles Using Oxygen as the Oxidant

(2012) Wen-Liang Chen et al.   ORGANIC LETTERS

Synthesis of Indolo [1,2-a]Quinoxalines via a Pd-Catalyzed Regioselective C–H Olefination/Cyclization Sequence

(2012) Liang Wang et al.   ORGANIC LETTERS

Organocatalytic Multiple Cascade Reactions: A New Strategy for the Construction of Enantioenriched Tetrahydrocarbazoles

(2011) Yi-Ju Cao et al.   ADVANCED SYNTHESIS & CATALYSIS

Morpholine catalyzed direct C3 alkenylation of indoles with α,β-unsaturated aldehydes

(2011) Shi-Kai Xiang et al.   CHEMICAL COMMUNICATIONS

Catalytic Dehydrogenative Cross-Coupling: Forming Carbon−Carbon Bonds by Oxidizing Two Carbon−Hydrogen Bonds

(2011) Charles S. Yeung et al.   CHEMICAL REVIEWS

Recent advances in the transition metal-catalyzed twofold oxidative C–H bond activation strategy for C–C and C–N bond formation

(2011) Seung Hwan Cho et al.   CHEMICAL SOCIETY REVIEWS

Recent developments in natural product synthesis using metal-catalysed C–H bond functionalisation

(2011) Lindsay McMurray et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of Vinyl-Substituted Polypyridyl Ligands through Suzuki–Miyaura Cross-Coupling of Potassium Vinyltrifluoroborate with Bromopolypyridines

(2011) Hai-Jing Nie et al.   JOURNAL OF ORGANIC CHEMISTRY

One-Pot Eschenmoser Episulfide Contractions in DMSO: Applications to the Synthesis of Fuligocandins A and B and a Number of Vinylogous Amides

(2011) Birgitta Pettersson et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Efficient Hydrogen-Bonding Catalysis of the Diels–Alder Reaction of 3-Vinylindoles and Methyleneindolinones Provides Carbazolespirooxindole Skeletons

(2011) Bin Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of Carbocyclic Ring of Indoles Using Ruthenium-Catalyzed Ring-Closing Olefin Metathesis

(2011) Kazuhiro Yoshida et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Oxidative Vinylation of Heteroarene Carboxylic Acids with Alkenes via Regioselective C−H Bond Cleavage

(2011) Takumi Ueyama et al.   ORGANIC LETTERS

Marine Indole Alkaloids: Potential New Drug Leads for the Control of Depression and Anxiety

(2010) Anna J. Kochanowska-Karamyan et al.   CHEMICAL REVIEWS

PdII-Catalysed CH Functionalisation of Indoles and Pyrroles Assisted by the Removable N-(2-Pyridyl)sulfonyl Group: C2-Alkenylation and Dehydrogenative Homocoupling

(2010) Alfonso García-Rubia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides

(2010) Frederic W. Patureau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(III)-Catalyzed Intermolecular Hydroarylation of Alkynes

(2010) Derek J. Schipper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Enantioselective Approach to Highly Substituted Tetrahydrocarbazoles through Hydrogen Bonding-Catalyzed Cascade Reactions

(2010) Xu-Fan Wang et al.   ORGANIC LETTERS

Palladium(II)-Catalyzed Regioselective Direct C2 Alkenylation of Indoles and Pyrroles Assisted by theN-(2-Pyridyl)sulfonyl Protecting Group

(2009) Alfonso García-Rubia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Brønsted Acid Mediated Tandem Diels−Alder/Aromatization Reactions of Vinylindoles

(2009) Cai-Bao Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Organocatalytic Asymmetric Diels-Alder Reactions of 3-Vinylindoles

(2008) Claudio Gioia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective C−H Functionalization Directed by a Removable Carboxyl Group:  Palladium-Catalyzed Vinylation at the Unusual Position of Indole and Related Heteroaromatic Rings

(2008) Atsushi Maehara et al.   ORGANIC LETTERS

Potassium Organotrifluoroborates:  New Perspectives in Organic Synthesis

(2007) Sylvain Darses et al.   CHEMICAL REVIEWS