Rh(III)-Catalyzed Divergent Synthesis of Alkynylated Imidazo[1,5-a]indoles and α,α-Difluoromethylene Tetrasubstituted Alkenes

Additive-Controlled Divergent Synthesis of Tetrasubstituted 1,3-Enynes and Alkynylated 3H-Pyrrolo[1,2-a]indol-3-ones via Rhodium Catalysis

(2021) Fei Zhao et al.   ORGANIC LETTERS

Rh(III)‐Catalyzed [3+2] Annulation and C−H Alkenylation of Indoles with 1,3‐Diynes by C−H Activation

(2021) Sanjeev Kumar et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Rhodium‐Catalyzed Cascade Reactions of Indoles with 4‐Hydroxy‐2‐Alkynoates for the Synthesis of Indole‐Fused Polyheterocycles

(2020) Xiaowei Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

C7‐Indole Amidations and Alkenylations by Ruthenium(II) Catalysis

(2020) Isaac Choi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed C–H Alkenylation/Directing Group Migration for the Regio- and Stereoselective Synthesis of Tetrasubstituted Alkenes

(2020) Xiaowei Wu et al.   ORGANIC LETTERS

Iridium-Catalyzed Direct C4- and C7-Selective Alkynylation of Indoles Using Sulfur-Directing Groups

(2019) Masahiro Miura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Re‐Catalyzed Annulations of Weakly Coordinating N ‐Carbamoyl Indoles/Indolines with Alkynes via C−H/C−N Bond Cleavage

(2019) Yunhui Yang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh(III)-Catalyzed Hydroarylation of Alkyne MIDA Boronates via C–H Activation of Indole Derivatives

(2019) Xiao Fei et al.   JOURNAL OF ORGANIC CHEMISTRY

C2/C4 Regioselective Heteroarylation of Indoles by Tuning C–H Metalation Modes

(2019) Shuyou Chen et al.   ACS Catalysis

Highly Selective Synthesis of 1,3-Enynes, Pyrroles, and Furans by Manganese(I)-Catalyzed C–H Activation

(2019) Sara Cembellín et al.   ACS Catalysis

Solvent-Dependent Asymmetric Synthesis of Alkynyl and Monofluoroalkenyl Isoindolinones by CpRhIII -Catalyzed C−H Activation

(2018) Teng Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functionalized Cyclopentadienyl Ligands and Their Substituent Effects on a Rhodium(III)-Catalyzed Oxidative [4+2] Annulation of Indole- and Pyrrole-1-Carboxamides with Alkynes

(2018) Takayuki Yamada et al.   Asian Journal of Organic Chemistry

Indoles as therapeutics of interest in medicinal chemistry: Bird's eye view

(2017) Navriti Chadha et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Arylative Cyclization of Indole-1-carboxamides with 1,6-Enynes for the Synthesis of Polycyclic Indole Scaffolds

(2017) Chatrala Ravikumar Reddy et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Mushroom-Derived Indole Alkaloids

(2017) Joshua A. Homer et al.   JOURNAL OF NATURAL PRODUCTS

Ruthenium(II)-Catalyzed Redox-Neutral [3+2] Annulation of Indoles with Internal Alkynes via C–H Bond Activation: Accessing a Pyrroloindolone Scaffold

(2017) Yanan Xie et al.   JOURNAL OF ORGANIC CHEMISTRY

C–F Bond Cleavage Enabled Redox-Neutral [4+1] Annulation via C–H Bond Activation

(2017) Cheng-Qiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rapid Syntheses of Heteroaryl-Substituted Imidazo[1,5-a]indole and Pyrrolo[1,2-c]imidazole via Aerobic C2–H Functionalizations

(2017) Wei-Jun Kong et al.   ORGANIC LETTERS

Enantioselective C–H Annulation of Indoles with Diazo Compounds through a Chiral Rh(III) Catalyst

(2017) Xiaohong Chen et al.   ACS Catalysis

Beyond C2 and C3: Transition-Metal-Catalyzed C–H Functionalization of Indole

(2017) Jamie A. Leitch et al.   ACS Catalysis

Metal-Catalyzed Annulations through Activation and Cleavage of C−H Bonds

(2016) Moisés Gulías et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Simple and Versatile Amide Directing Group for C−H Functionalizations

(2016) Ru-Yi Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkenylation of Arenes and Heteroarenes with Alkynes

(2016) Vadim P. Boyarskiy et al.   CHEMICAL REVIEWS

Carboxylic Acids as Directing Groups for C−H Bond Functionalization

(2016) Martin Pichette Drapeau et al.   CHEMISTRY-A EUROPEAN JOURNAL

Design, Synthesis, and Biological Evaluation of Indoline and Indole Derivatives as Potent and Selective α1A-Adrenoceptor Antagonists

(2016) Fei Zhao et al.   JOURNAL OF MEDICINAL CHEMISTRY

A review on recent developments of indole-containing antiviral agents

(2015) Ming-Zhi Zhang et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Expedient Synthesis of Pyrroloquinolinones by Rh-Catalyzed Annulation of N-Carbamoyl Indolines with Alkynes through a Directed C–H Functionalization/C–N Cleavage Sequence

(2015) Xiao-Fei Yang et al.   ORGANIC LETTERS

Highly Stereoselective Ruthenium(II)-Catalyzed Direct C2-syn-Alkenylation of Indoles with Alkynes

(2015) Wei Zhang et al.   ORGANIC LETTERS

Facile Synthesis of Isoindolinones via Rh(III)-Catalyzed One-Pot Reaction of Benzamides, Ketones, and Hydrazines

(2015) Yan Zhang et al.   ORGANIC LETTERS

Synthesis of Indolo[1,2-a][1,8]naphthyridines by Rhodium(III)-Catalyzed Dehydrogenative Coupling via Rollover Cyclometalation

(2015) Ryosuke Morioka et al.   ORGANIC LETTERS

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

(2015) Zhengkai Chen et al.   Organic Chemistry Frontiers

Rh(III)-Catalyzed C–H Activation/Cyclization of Indoles and Pyrroles: Divergent Synthesis of Heterocycles

(2014) Yan Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Pyrroloindolone Synthesis via a Cp*CoIII-Catalyzed Redox-Neutral Directed C–H Alkenylation/Annulation Sequence

(2014) Hideya Ikemoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Difunctionalization of Alkynes via C–N and S–N Cleavages: A Versatile Approach to Highly Functional Indoles

(2014) Fei Zhao et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Selective Coupling of N-Methoxy-1H-indole-1-carboxamides and Aryl Boronic Acids

(2014) Jing Zheng et al.   ORGANIC LETTERS

Rh-catalyzed oxidative C2-alkenylation of indoles with alkynes: unexpected cleavage of directing group

(2014) Satyasheel Sharma et al.   TETRAHEDRON LETTERS

Rhodium(III)-Catalyzed Redox-Neutral Coupling ofN-Phenoxyacetamides and Alkynes with Tunable Selectivity

(2013) Guixia Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mild and Efficient C2-Alkenylation of Indoles with Alkynes Catalyzed by a Cobalt Complex

(2012) Zhenhua Ding et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ruthenium-catalyzed aerobic oxidative coupling of alkynes with 2-aryl-substituted pyrroles

(2011) Lutz Ackermann et al.   Chemical Science

Oxidative Coupling of Aromatic Substrates with Alkynes and Alkenes under Rhodium Catalysis

(2010) Tetsuya Satoh et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Intermolecular Hydroarylation of Alkynes

(2010) Derek J. Schipper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzed Cross-Coupling of sp3C−H Bonds with sp2and sp3Boronic Acids Using Air as the Oxidant

(2008) Dong-Hui Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY