Nickel-Catalyzed 1,1-Aminoborylation of Unactivated Terminal Alkenes

Native Amides as Enabling Vehicles for Forging sp3–sp3 Architectures via Interrupted Deaminative Ni-Catalyzed Chain-Walking

(2023) Jesus Rodrigalvarez et al.   Journal of the American Chemical Society

Enantioselective Synthesis of α-Aminoboronic Acid Derivatives via Copper-Catalyzed N-Alkylation

(2023) Giuseppe Zuccarello et al.   Journal of the American Chemical Society

Hydroamination, Aminoboration, and Carboamination with Electrophilic Amination Reagents: Umpolung-Enabled Regio- and Stereoselective Synthesis of N-Containing Molecules from Alkenes and Alkynes

(2022) Koji Hirano et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Primary trifluoroborate-iminiums enable facile access to chiral α-aminoboronic acids via Ru-catalyzed asymmetric hydrogenation and simple hydrolysis of the trifluoroborate moiety

(2022) Andrej Šterman et al.   Chemical Science

Streamlined Alkylation via Nickel-Hydride-Catalyzed Hydrocarbonation of Alkenes

(2022) Zhikun Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boron Chemicals in Drug Discovery and Development: Synthesis and Medicinal Perspective

(2022) Bhaskar C. Das et al.   MOLECULES

Ni-Catalyzed Regio- and Stereoselective Alkylarylation of Unactivated Alkenes in γ,δ-Alkenylketimines

(2022) Vivek Aryal et al.   ACS Catalysis

The Boron Advantage: The Evolution and Diversification of Boron’s Applications in Medicinal Chemistry

(2022) Katia Messner et al.   Pharmaceuticals

Practical Synthesis of Chiral Allylboronates by Asymmetric 1,1‐Difunctionalization of Terminal Alkenes

(2022) Caocao Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective synthesis of α-aminoboronates by NiH-catalysed asymmetric hydroamidation of alkenyl boronates

(2022) Yao Zhang et al.   Nature Communications

General and selective metal-free radical α-C–H borylation of aliphatic amines

(2022) Sumon Sarkar et al.   Chem

NiH-Catalyzed Functionalization of Remote and Proximal Olefins: New Reactions and Innovative Strategies

(2022) You Wang et al.   Accounts of Chemical Research

sp3 Bis‐Organometallic Reagents via Catalytic 1,1‐Difunctionalization of Unactivated Olefins

(2021) Ruben Martin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt‐Catalyzed One‐Pot Asymmetric Difunctionalization of Alkynes to Access Chiral gem ‐(Borylsilyl)alkanes

(2021) Yang'en You et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Overcoming the Naphthyl Requirement in Stereospecific Cross-Couplings to Form Quaternary Stereocenters

(2021) Jianyu Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Low-Valent Tungsten Catalysis Enables Site-Selective Isomerization–Hydroboration of Unactivated Alkenes

(2021) Tanner C. Jankins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aza-Matteson Reactions via Controlled Mono- and Double-Methylene Insertions into Nitrogen–Boron Bonds

(2021) Qiqiang Xie et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed 1,2-Carboamination of Alkenyl Alcohols

(2021) Taeho Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in Mono‐ and Difunctionalization of Unactivated Olefins

(2021) Monak Patel et al.   Asian Journal of Organic Chemistry

Site-Selective Palladium-Catalyzed 1,1-Arylamination of Terminal Alkenes

(2021) Chunhua Han et al.   CCS Chemistry

Recent Advances in Nickel-Catalyzed Three-Component Difunctionalization of Unactivated Alkenes

(2020) Hai-Yong Tu et al.   SYNTHESIS-STUTTGART

Versatile cobalt-catalyzed regioselective chain-walking double hydroboration of 1,n-dienes to access gem-bis(boryl)alkanes

(2020) Ming Hu et al.   Nature Communications

Role of Electron-Deficient Olefin Ligands in a Ni-Catalyzed Aziridine Cross-Coupling To Generate Quaternary Carbons

(2020) Jesús G. Estrada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Chemodivergent 1,1-Difunctionalization of Unactivated α-Olefins with Alkynyl Electrophiles and B2pin2

(2020) Yangyang Li et al.   ACS Catalysis

Nickel-Catalyzed Dicarbofunctionalization of Alkenes

(2020) Xiaoxu Qi et al.   ACS Catalysis

Developments in Photoredox/Nickel Dual-Catalyzed 1,2-Difunctionalizations

(2020) Shorouk O. Badir et al.   Chem

Ni(4-tBustb)3: A Robust 16-Electron Ni(0) Olefin Complex for Catalysis

(2020) Lukas Nattmann et al.   ORGANOMETALLICS

Progress in the medicinal chemistry of organoboron compounds

(2020) Anna N. Tevyashova et al.   RUSSIAN CHEMICAL REVIEWS

Migratory Arylboration of Unactivated Alkenes Enabled by Nickel Catalysis

(2019) Wang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed 1,1-Alkylboration of Electronically Unbiased Terminal Alkenes

(2019) Yangyang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Differential Dihydrofunctionalization of Terminal Alkynes: Synthesis of Benzylic Alkyl Boronates through Reductive Three-Component Coupling

(2019) Megan K. Armstrong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Regioselective Hydroalkylation and Hydroarylation of Alkenyl Boronic Esters

(2019) Srikrishna Bera et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rapid Access to Highly Functionalized Alkyl Boronates by NiH-Catalyzed Remote Hydroarylation of Boron-Containing Alkenes

(2019) Yao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective 1,1-Difunctionalization of Unactivated Alkenes Enabled by Cationic Palladium Catalysis

(2019) Jinwon Jeon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Electrophilic Amination of gem-Diborylalkanes with Hydroxylamines Providing α-Aminoboronic Acid Derivatives

(2019) Soshi Nishino et al.   ORGANIC LETTERS

Tackling Remote sp 3 C−H Functionalization via Ni‐Catalyzed “chain‐walking” Reactions

(2019) Daniel Janssen‐Müller et al.   ISRAEL JOURNAL OF CHEMISTRY

α-Branched amines by catalytic 1,1-addition of C–H bonds and aminating agents to terminal alkenes

(2019) Soham Maity et al.   Nature Catalysis

Site-Selective Catalytic Deaminative Alkylation of Unactivated Olefins

(2019) Shang-Zheng Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Difunctionalization of Alkenes Involving Metal Migration

(2019) Yuqiang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cascade CuH-catalysed conversion of alkynes into enantioenriched 1,1-disubstituted products

(2019) De-Wei Gao et al.   Nature Catalysis

An air-stable binary Ni(0)–olefin catalyst

(2019) Lukas Nattmann et al.   Nature Catalysis

Synthesis and biological evaluation of curcumin derivatives modified with α-amino boronic acid as proteasome inhibitors

(2018) Wenjie Zhang et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Transition Metal-Catalyzed Dicarbofunctionalization of Unactivated Olefins

(2018) Roshan K. Dhungana et al.   CHEMICAL RECORD

Strategies toward Dicarbofunctionalization of Unactivated Olefins by Combined Heck Carbometalation and Cross-Coupling

(2018) Ramesh Giri et al.   JOURNAL OF ORGANIC CHEMISTRY

Facile synthesis of α-aminoboronic acids from amines and potassium acyltrifluoroborates (KATs) via trifluoroborate-iminiums (TIMs)

(2018) Tomoya Shiro et al.   Chemical Science

Nickel-catalyzed difunctionalization of allyl moieties using organoboronic acids and halides with divergent regioselectivities

(2018) Wanfang Li et al.   Chemical Science

Walking Metals for Remote Functionalization

(2018) Heiko Sommer et al.   ACS Central Science

Site-Selective Ni-Catalyzed Reductive Coupling of α-Haloboranes with Unactivated Olefins

(2018) Shang-Zheng Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigations of the Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Benzyl Acrylates

(2017) Manuel Orlandi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote Migratory Cross-Electrophile Coupling and Olefin Hydroarylation Reactions Enabled by in Situ Generation of NiH

(2017) Fenglin Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild and Regioselective Benzylic C–H Functionalization: Ni-Catalyzed Reductive Arylation of Remote and Proximal Olefins

(2017) Yuli He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO2 and Water

(2017) Morgane Gaydou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide

(2017) Francisco Juliá-Hernández et al.   NATURE

Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes

(2017) Lei Li et al.   Nature Communications

Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

(2016) Steven W. M. Crossley et al.   CHEMICAL REVIEWS

Synthesis of α-aminoboronic acids

(2016) Patricia Andrés et al.   CHEMICAL SOCIETY REVIEWS

Development and Analysis of a Pd(0)-Catalyzed Enantioselective 1,1-Diarylation of Acrylates Enabled by Chiral Anion Phase Transfer

(2016) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote functionalization through alkene isomerization

(2016) Alexandre Vasseur et al.   Nature Chemistry

Discovery of a Cyclic Boronic Acid β-Lactamase Inhibitor (RPX7009) with Utility vs Class A Serine Carbapenemases

(2015) Scott J. Hecker et al.   JOURNAL OF MEDICINAL CHEMISTRY

Palladium-Catalyzed Enantioselective 1,1-Fluoroarylation of Aminoalkenes

(2015) Ying He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective 1,1-Arylborylation of Alkenes: Merging Chiral Anion Phase Transfer with Pd Catalysis

(2015) Hosea M. Nelson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of α-Aminoboronic Acid Derivatives by Copper-Catalyzed Enantioselective Hydroamination

(2015) Daiki Nishikawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design of Modified Amine Transfer Reagents Allows the Synthesis of α-Chiral Secondary Amines via CuH-Catalyzed Hydroamination

(2015) Dawen Niu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(0)-Catalyzed 1,1-Diarylation of Ethylene and Allylic Carbonates

(2013) Vaneet Saini et al.   ORGANIC LETTERS

Palladium-Catalyzed 1,1-Difunctionalization of Ethylene

(2012) Vaneet Saini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Developments in Transition-Metal-Catalyzed Reactions Using Electrophilic Nitrogen Sources

(2011) Elizabeth Jarvo et al.   SYNTHESIS-STUTTGART

Palladium-Catalyzed Oxidative Intermolecular Difunctionalization of Terminal Alkenes with Organostannanes and Molecular Oxygen

(2009) Kaveri Balan Urkalan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidatively Intercepting Heck Intermediates:  Pd-Catalyzed 1,2- and 1,1-Arylhalogenation of Alkenes

(2008) Dipannita Kalyani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY