Asymmetric Construction of an Aryl‐Alkene Axis by Palladium‐Catalyzed Suzuki–Miyaura Coupling Reaction

Carbene-catalyzed atroposelective synthesis of axially chiral styrenes

(2022) Jia-Lei Yan et al.   Nature Communications

Chiral Phosphoric Acid Catalyzed Asymmetric Synthesis of Axially Chiral Compounds

(2021) Bing‐Chao Da et al.   CHINESE JOURNAL OF CHEMISTRY

Recent Advances in Catalytic Asymmetric Construction of Atropisomers

(2021) Jun Kee Cheng et al.   CHEMICAL REVIEWS

Tandem Iridium Catalysis as a General Strategy for Atroposelective Construction of Axially Chiral Styrenes

(2021) Jie Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Atroposelective Synthesis of Conjugated Diene-Based Axially Chiral Styrenes via Pd(II)-Catalyzed Thioether-Directed Alkenyl C–H Olefination

(2021) Liang Jin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Synthesis of Axially Chiral Diarylmethylidene Indanones

(2021) Prashant Kumar et al.   ORGANIC LETTERS

Urea group-directed organocatalytic asymmetric versatile dihalogenation of alkenes and alkynes

(2021) San Wu et al.   Nature Catalysis

Rhodium‐Catalyzed Atroposelective Access to Axially Chiral Olefins via C−H Bond Activation and Directing Group Migration

(2021) Ruijie Mi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rational Design of Axially Chiral Styrene‐Based Organocatalysts and Their Application in Catalytic Asymmetric (2+4) Cyclizations

(2021) Si‐Jia Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Axially Chiral Styrenes through Pd-Catalyzed Asymmetric C−H Olefination Enabled by an Amino Amide Transient Directing Group

(2020) Hong Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic Enantioselective Construction of Heterocycle-Substituted Styrenes with Chiral Atropisomerism

(2020) Quan-Zhe Li et al.   ORGANIC LETTERS

Atroposelective Synthesis of Axially Chiral Styrenes via an Asymmetric C–H Functionalization Strategy

(2020) Liang Jin et al.   Chem

Enantioselective Cross-Coupling for Axially Chiral Tetra-ortho-Substituted Biaryls and Asymmetric Synthesis of Gossypol

(2020) He Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition Metal‐Catalyzed Enantioselective C–H Functionalization via Chiral Transient Directing Group Strategy

(2020) Gang Liao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atroposelective Access to Oxindole-Based Axially Chiral Styrenes via the Strategy of Catalytic Kinetic Resolution

(2020) Chun Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Transient Directing Groups in Transition-Metal-Catalyzed Enantioselective C–H Bond Functionalization

(2020) Maria I. Lapuh et al.   ACS Catalysis

Asymmetric Construction of Axially Chiral 2-Arylpyrroles via Chirality Transfer of Atropisomeric Alkenes

(2019) Bin Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rational design, enantioselective synthesis and catalytic applications of axially chiral EBINOLs

(2019) Yong-Bin Wang et al.   Nature Catalysis

A Bulky Chiral N-Heterocyclic Carbene Palladium Catalyst Enables Highly Enantioselective Suzuki–Miyaura Cross-Coupling Reactions for the Synthesis of Biaryl Atropisomers

(2019) Di Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of Axially Chiral Compounds via Asymmetric Organocatalysis

(2018) Yong-Bin Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Stereocontrolled synthesis of ( E )-stilbene derivatives by palladium-catalyzed Suzuki-Miyaura cross-coupling reaction

(2018) Hailee H. Rau et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Organocatalytic Enantioselective Construction of Axially Chiral Sulfone-Containing Styrenes

(2018) Shiqi Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

E–Z isomerization in Suzuki cross-couplings of haloenones: ligand effects and evidence for a separate catalytic cycle

(2018) Navneet K. Chehal et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Unexpected Alkene Isomerization during Iterative Cross-Coupling To Form Hindered, Electron-Deficient Trienes

(2018) Abigail Feceu et al.   ORGANIC LETTERS

Asymmetric Mannich Reaction and Construction of Axially Chiral Sulfone-Containing Styrenes in One Pot from α-Amido Sulfones Based on the Waste–Reuse Strategy

(2018) Dongmei Li et al.   ORGANIC LETTERS

Computationally Assisted Mechanistic Investigation and Development of Pd-Catalyzed Asymmetric Suzuki-Miyaura and Negishi Cross-Coupling Reactions for Tetra-ortho-Substituted Biaryl Synthesis

(2018) Nitinchandra Dahyabhai Patel et al.   ACS Catalysis

Enantioselective Construction of Vicinal Diaxial Styrenes and Multiaxis System via Organocatalysis

(2018) Yu Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric One-Pot Construction of Three Stereogenic Elements: Chiral Carbon Center, Stereoisomeric Alkenes, and Chirality of Axial Styrenes

(2018) Anqi Huang et al.   ORGANIC LETTERS

Organocatalytic Asymmetric Atroposelective Construction of Axially Chiral 1,4-Distyrene 2,3-Naphthalene Diols

(2018) Shan Li et al.   ORGANIC LETTERS

Highly Stereoselective Synthesis of Tetrasubstituted Acyclic All-Carbon Olefins via Enol Tosylation and Suzuki–Miyaura Coupling

(2017) Beryl X. Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalytic atroposelective synthesis of axially chiral styrenes

(2017) Sheng-Cai Zheng et al.   Nature Communications

Synthesis of axially chiral biaryl compounds by asymmetric catalytic reactions with transition metals

(2016) Pauline Loxq et al.   COORDINATION CHEMISTRY REVIEWS

Enantioselective Synthesis of Atropisomeric Vinyl Arene Compounds by Palladium Catalysis: A Carbene Strategy

(2015) Jia Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances and new concepts for the synthesis of axially stereoenriched biaryls

(2015) J. Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Palladium catalyzed asymmetric Suzuki–Miyaura coupling reactions to axially chiral biaryl compounds: Chiral ligands and recent advances

(2015) Dao Zhang et al.   COORDINATION CHEMISTRY REVIEWS

A twist of nature – the significance of atropisomers in biological systems

(2015) Jamie E. Smyth et al.   NATURAL PRODUCT REPORTS

Development of Efficient Asymmetric Suzuki-Miyaura Cross-Coupling and Applications in Synthesis

(2015) Guangqing Xu et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Efficient Syntheses of Korupensamines A, B and Michellamine B by Asymmetric Suzuki-Miyaura Coupling Reactions

(2013) Guangqing Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Effects on the Stereochemical Outcome of Suzuki–Miyaura Couplings

(2012) Guo-Ping Lu et al.   JOURNAL OF ORGANIC CHEMISTRY

Optimised conditions for styrene syntheses using Suzuki–Miyaura couplings and catalyst-ligand-base pre-mixes

(2012) Laura Henderson et al.   TETRAHEDRON LETTERS

A General and Special Catalyst for Suzuki-Miyaura Coupling Processes

(2010) Wenjun Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

(2010) Gerhard Bringmann et al.   CHEMICAL REVIEWS

Studies of microwave-enhanced Suzuki–Miyaura vinylation of electron-rich sterically hindered substrates utilizing potassium vinyltrifluoroborate

(2010) Matthew D. Brooker et al.   TETRAHEDRON LETTERS

The Challenge of Atropisomerism in Drug Discovery

(2009) Jonathan Clayden et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

(2009) Marisa C. Kozlowski et al.   CHEMICAL SOCIETY REVIEWS

C2-Symmetric Bis-Hydrazones as Ligands in the Asymmetric Suzuki−Miyaura Cross-Coupling

(2008) Antonio Bermejo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY