Enantioselective Synthesis of Atropisomeric Vinyl Arene Compounds by Palladium Catalysis: A Carbene Strategy

Asymmetric Synthesis of Axially Chiral Isoquinolones: Nickel-Catalyzed Denitrogenative Transannulation

(2015) Zhi-Jia Fang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances and new concepts for the synthesis of axially stereoenriched biaryls

(2015) J. Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Simultaneous Induction of Axial and Planar Chirality in Arene-Chromium Complexes by Molybdenum-Catalyzed Enantioselective Ring-Closing Metathesis

(2015) Ken Kamikawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Synthesis of 3-Arylquinazolin-4(3H)-ones via Peptide-Catalyzed Atroposelective Bromination

(2015) Matthew E. Diener et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Direct Functionalization of Indoles by Pd/Sulfoxide-Phosphine-Catalyzed N-Allylic Alkylation

(2015) Li-Yan Chen et al.   ORGANIC LETTERS

Double-Stereodifferentiation in Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition: Chiral Ligand/Chiral Counterion Matched Pair

(2015) Mylène Augé et al.   ORGANIC LETTERS

Pd(II)-Catalyzed P(O)R1R2-Directed Asymmetric C–H Activation and Dynamic Kinetic Resolution for the Synthesis of Chiral Biaryl Phosphates

(2015) Yan-Na Ma et al.   ORGANIC LETTERS

Catalyst-free cross-coupling of N-tosylhydrazones with chromium(0) Fischer carbene complexes: a new approach to diarylethanone

(2015) Fangdong Hu et al.   Organic Chemistry Frontiers

Atroposelective synthesis of axially chiral P,S-ligands based on arynes

(2015) Anaïs Berthelot-Bréhier et al.   Organic Chemistry Frontiers

Construction of Axial Chirality by Rhodium-Catalyzed Asymmetric Dehydrogenative Heck Coupling of Biaryl Compounds with Alkenes

(2014) Jun Zheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Axially Chiral Biaryls through Sulfoxide-Directed Asymmetric Mild CH Activation and Dynamic Kinetic Resolution

(2014) Chinmoy Kumar Hazra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heteroarylboronates in Rhodium-Catalyzed 1,4-Addition to Enones

(2014) Fabian Albrecht et al.   ORGANIC LETTERS

Chiral 1,2-Cyclohexane-Bridged Bis-NHC Palladium Catalysts for Asymmetric Suzuki–Miyaura Coupling: Synthesis, Characterization, and Steric Effects on Enantiocontrol

(2014) Yinle Li et al.   ORGANOMETALLICS

Pd(II)-Catalyzed Intermolecular Direct C–H Bond Iodination: An Efficient Approach toward the Synthesis of Axially Chiral Compounds via Kinetic Resolution

(2014) De-Wei Gao et al.   ACS Catalysis

Enantioselective Synthesis of Axially Chiral Biaryl Monophosphine Oxides via Direct Asymmetric Suzuki Coupling and DFT Investigations of the Enantioselectivity

(2014) Yougui Zhou et al.   ACS Catalysis

Atropodiastereoselective CH Olefination of Biphenylp-Tolyl Sulfoxides with Acrylates

(2013) Thomas Wesch et al.   ADVANCED SYNTHESIS & CATALYSIS

Efficient Syntheses of Korupensamines A, B and Michellamine B by Asymmetric Suzuki-Miyaura Coupling Reactions

(2013) Guangqing Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Cross-Coupling Strategy for the Asymmetric Synthesis of Axially Chiral Heterobiaryls

(2013) Abel Ros et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of QUINAP via Dynamic Kinetic Resolution

(2013) Vikram Bhat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Multisubstituted Biaryl Skeleton by Chiral Phosphoric Acid Catalyzed Desymmetrization/Kinetic Resolution Sequence

(2013) Keiji Mori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Axially Chiral Multifunctionalized Biaryls via Asymmetric Suzuki–Miyaura Coupling

(2013) Yougui Zhou et al.   ORGANIC LETTERS

Chiral PEPPSI Complexes: Synthesis, Characterization, and Application in Asymmetric Suzuki–Miyaura Coupling Reactions

(2013) Laure Benhamou et al.   ORGANOMETALLICS

Diazo Compounds and N-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions

(2012) Qing Xiao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Detection and Reactivity of a Palladium Alkoxycarbene

(2012) Isabel Meana et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phosphino Hydrazones as Suitable Ligands in the Asymmetric Suzuki–Miyaura Cross-Coupling

(2012) Abel Ros et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Efficient Synthesis of a Class of Novel Chiral-Bridged Atropisomeric Monophosphine Ligands via Simple Desymmetrization and Their Applications in Asymmetric Suzuki–Miyaura Coupling Reaction

(2012) Shouliang Wang et al.   ORGANIC LETTERS

Carbenylative Amination with N-Tosylhydrazones

(2012) Avinash Khanna et al.   ORGANIC LETTERS

Catalytic Three-Component One-Pot Reaction of Hydrazones, Dihaloarenes, and Amines

(2012) Maxime Roche et al.   ORGANIC LETTERS

Palladium-Catalyzed Oxidative Cross-Coupling of N-Tosylhydrazones or Diazoesters with Terminal Alkynes: A Route to Conjugated Enynes

(2011) Lei Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Synthesis of Axially Chiral Biarylphosphonates: Asymmetric Suzuki-Miyaura Coupling Using High-Molecular-Weight, Helically Chiral Polyquinoxaline-Based Phosphines

(2011) Takeshi Yamamoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tosylhydrazones: New Uses for Classic Reagents in Palladium-Catalyzed Cross-Coupling and Metal-Free Reactions

(2011) José Barluenga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Tosylhydrazones: versatile reagents for metal-catalyzed and metal-free cross-coupling reactions

(2011) Zhihui Shao et al.   CHEMICAL SOCIETY REVIEWS

Pd-Catalyzed Asymmetric Allylic Alkylation of Indoles and Pyrroles by Chiral Alkene-Phosphine Ligands

(2011) Ziping Cao et al.   ORGANIC LETTERS

Carbonylation of Metal Carbene with Carbon Monoxide: Generation of Ketene

(2011) Zhenhua Zhang et al.   ACS Catalysis

Carbene insertion into transition metal–carbon bonds: a new tool for catalytic C–C bond formation

(2011) Nicole M. G. Franssen et al.   Catalysis Science & Technology

Arylation of α-Chiral Ketones by Palladium-Catalyzed Cross-Coupling Reactions of Tosylhydrazones with Aryl Halides

(2010) José Barluenga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Induction of axially chiral N–C bonds in N-aryl acridane and related complexes by chromium tricarbonyl migration reactions

(2010) Akiyoshi Mori et al.   CHEMICAL COMMUNICATIONS

Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

(2010) Gerhard Bringmann et al.   CHEMICAL REVIEWS

Synthesis of 2-Arylacrylates from Pyruvate by Tosylhydrazide-Promoted Pd-Catalyzed Coupling with Aryl Halides

(2010) José Barluenga et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Synthesis of Axially Chiral Biaryls by the Pd-Catalyzed Suzuki−Miyaura Reaction: Substrate Scope and Quantum Mechanical Investigations

(2010) Xiaoqiang Shen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioenriched Synthesis ofC1-Symmetric BINOLs: Iron-Catalyzed Cross-Coupling of 2-Naphthols and Some Mechanistic Insight

(2010) Hiromichi Egami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Biphenols from 1,4-Diketones by Traceless Central-to-Axial Chirality Exchange

(2010) Fenghai Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Diene as the Ligand for the Synthesis of Axially Chiral Compounds via Palladium-Catalyzed Suzuki−Miyaura Coupling Reaction

(2010) Shu-Sheng Zhang et al.   ORGANIC LETTERS

Pd-Catalyzed Reaction of Sterically Hindered Hydrazones with Aryl Halides: Synthesis of Tetra-Substituted Olefins Related toiso-Combretastatin A4

(2010) Etienne Brachet et al.   ORGANIC LETTERS

Development of Chiral Terminal-Alkene−Phosphine Hybrid Ligands for Palladium-Catalyzed Asymmetric Allylic Substitutions

(2010) Zhaoqun Liu et al.   ORGANIC LETTERS

Asymmetric Synthesis of Axially Chiral Biaryl Diphosphine Ligands by Rhodium-Catalyzed Enantioselective Intramolecular Double [2 + 2 + 2] Cycloaddition

(2010) Fumiya Mori et al.   ORGANIC LETTERS

Synthesis of Polysubstituted Olefins by Pd-Catalyzed Cross-Coupling Reaction of Tosylhydrazones and Aryl Nonaflates

(2010) José Barluenga et al.   ORGANIC LETTERS

Dynamic Kinetic Resolution of Biaryl Atropisomers via Peptide-Catalyzed Asymmetric Bromination

(2010) J. L. Gustafson et al.   SCIENCE

Palladium-Catalyzed Insertion of α-Diazoesters into Vinyl Halides To Generate α,β-Unsaturated γ-Amino Esters

(2009) Romas Kudirka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Suzuki-Miyaura Coupling in Water with a Chiral Palladium Catalyst Supported on an Amphiphilic Resin

(2009) Yasuhiro Uozumi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

(2009) Marisa C. Kozlowski et al.   CHEMICAL SOCIETY REVIEWS

Controlling Axial Conformation in 2-Arylpyridines and 1-Arylisoquinolines: Application to the Asymmetric Synthesis of QUINAP by Dynamic Thermodynamic Resolution

(2009) Jonathan Clayden et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Asymmetric Aerobic Oxidation: Oxidative Coupling of 2-Naphthols

(2009) Hiromichi Egami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Catalyzed Enantioselective Synthesis of Compounds with Non-Centrochirality

(2009) Masamichi Ogasawara et al.   SYNTHESIS-STUTTGART

Asymmetric Suzuki-Miyaura Coupling Reactions Catalyzed by Chiral Palladium Nanoparticles at Room Temperature

(2008) Koji Sawai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-Catalyzed Cross-Coupling Reactions with Carbonyls: Application in a Very Efficient Synthesis of 4-Aryltetrahydropyridines

(2008) José Barluenga et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal-Catalyzed Enantioselective [2+2+2] Cycloadditions for the Synthesis of Axially Chiral Biaryls

(2008) Ken Tanaka   Chemistry-An Asian Journal

C2-Symmetric Bis-Hydrazones as Ligands in the Asymmetric Suzuki−Miyaura Cross-Coupling

(2008) Antonio Bermejo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY