Tandem Iridium Catalysis as a General Strategy for Atroposelective Construction of Axially Chiral Styrenes

Enantioselective Construction of Axially Chiral Amino Sulfide Vinyl Arenes by Chiral Sulfide-Catalyzed Electrophilic Carbothiolation of Alkynes

(2020) Yaoyu Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Axially Chiral Styrenes through Pd-Catalyzed Asymmetric C−H Olefination Enabled by an Amino Amide Transient Directing Group

(2020) Hong Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atroposelective Synthesis of Axially Chiral Styrenes via an Asymmetric C–H Functionalization Strategy

(2020) Liang Jin et al.   Chem

Axially Chiral Aryl‐Alkene‐Indole Framework: A Nascent Member of the Atropisomeric Family and Its Catalytic Asymmetric Construction

(2020) Cong‐Shuai Wang et al.   CHINESE JOURNAL OF CHEMISTRY

Stereospecific Isomerization of Allylic Halides via Ion Pairs with Induced Noncovalent Chirality

(2020) Samuel Martinez-Erro et al.   ORGANIC LETTERS

BIMP‐Catalyzed 1,3‐Prototropic Shift for the Highly Enantioselective Synthesis of Conjugated Cyclohexenones

(2020) Jonathan C. Golec et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unraveling the Mechanism of the Ir(III)‐Catalyzed Regiospecific Synthesis of α‐Chlorocarbonyl Compounds from Allylic Alcohols

(2020) Belén Martín-Matute et al.   CHEMISTRY-A EUROPEAN JOURNAL

Atroposelective Access to Oxindole-Based Axially Chiral Styrenes via the Strategy of Catalytic Kinetic Resolution

(2020) Chun Ma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Branched-Selective Direct α-Alkylation of Cyclic Ketones with Simple Alkenes

(2019) Dong Xing et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Asymmetric Allylic Aromatization Reaction

(2019) Shuli You et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Asymmetric Synthesis of Functionally Rich Molecules Enabled by (Phosphoramidite,Olefin) Ligands

(2019) Simon L. Rössler et al.   ACCOUNTS OF CHEMICAL RESEARCH

Asymmetric Construction of Axially Chiral 2-Arylpyrroles via Chirality Transfer of Atropisomeric Alkenes

(2019) Bin Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Allylic Dearomatization of β-Naphthols: Enantioselective Control of Prochiral Nucleophiles

(2019) Sheng-Biao Tang et al.   ORGANIC LETTERS

Base-Catalyzed [1,n]-Proton Shifts in Conjugated Polyenyl Alcohols and Ethers

(2019) Nagaraju Molleti et al.   ACS Catalysis

Construction of Axially Chiral Compounds via Asymmetric Organocatalysis

(2018) Yong-Bin Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Organocatalytic Enantioselective Construction of Axially Chiral Sulfone-Containing Styrenes

(2018) Shiqi Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism, selectivity, and reactivity of iridium- and rhodium-catalyzed intermolecular ketone α-alkylation with unactivated olefins via an enamide directing strategy

(2018) Xiaojie Li et al.   Catalysis Science & Technology

Mechanism and Origins of Regio- and Stereoselectivities in Iridium-Catalyzed Isomerization of 1-Alkenes to trans-2-Alkenes

(2018) Lingfei Hu et al.   ORGANIC LETTERS

Asymmetric Mannich Reaction and Construction of Axially Chiral Sulfone-Containing Styrenes in One Pot from α-Amido Sulfones Based on the Waste–Reuse Strategy

(2018) Dongmei Li et al.   ORGANIC LETTERS

Iridium‐Catalyzed Propenylation Reactions for the Synthesis of 4‐Pyridone Derivatives

(2018) Xue‐dan Bai et al.   ADVANCED SYNTHESIS & CATALYSIS

Iridium-Catalyzed Asymmetric Allylic Substitution Reactions

(2018) Qiang Cheng et al.   CHEMICAL REVIEWS

Enantioselective Construction of Vicinal Diaxial Styrenes and Multiaxis System via Organocatalysis

(2018) Yu Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific 1,3-H Transfer of Indenols Proceeds via Persistent Ion-Pairs Anchored by NH···π Interactions

(2018) David M. H. Ascough et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric One-Pot Construction of Three Stereogenic Elements: Chiral Carbon Center, Stereoisomeric Alkenes, and Chirality of Axial Styrenes

(2018) Anqi Huang et al.   ORGANIC LETTERS

Organocatalytic Asymmetric Atroposelective Construction of Axially Chiral 1,4-Distyrene 2,3-Naphthalene Diols

(2018) Shan Li et al.   ORGANIC LETTERS

An Approach to the Synthesis of 1-Propenylnaphthols and 3-Arylnaphtho[2,1-b]furans

(2017) Jin Huang et al.   JOURNAL OF ORGANIC CHEMISTRY

Isomerization of N-Allyl Amides To Form Geometrically Defined Di-, Tri-, and Tetrasubstituted Enamides

(2017) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic enantioselective synthesis of atropisomeric biaryls by a cation-directed O-alkylation

(2017) John D. Jolliffe et al.   Nature Chemistry

Organocatalytic synthesis of axially chiral atropisomers

(2017) P. Renzi   ORGANIC & BIOMOLECULAR CHEMISTRY

Organocatalytic atroposelective synthesis of axially chiral styrenes

(2017) Sheng-Cai Zheng et al.   Nature Communications

Rhodium-Catalyzed Dynamic Kinetic Asymmetric Allylation of Phenols and 2-Hydroxypyridines

(2016) Changkun Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cinchonium Betaines as Efficient Catalysts for Asymmetric Proton Transfer Catalysis: The Development of a Practical Enantioselective Isomerization of Trifluoromethyl Imines

(2016) Xiao Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective γ-Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement

(2016) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base-Catalyzed Stereospecific Isomerization of Electron-Deficient Allylic Alcohols and Ethers through Ion-Pairing

(2016) Samuel Martinez-Erro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Diastereo-, Enantio-, and Regioselective Allylic Alkylation with Prochiral Enolates

(2016) J. Caleb Hethcox et al.   ACS Catalysis

Mechanism and Origins of Ligand-Controlled Linear Versus Branched Selectivity of Iridium-Catalyzed Hydroarylation of Alkenes

(2016) Genping Huang et al.   ACS Catalysis

Enantioselective Synthesis of Atropisomeric Vinyl Arene Compounds by Palladium Catalysis: A Carbene Strategy

(2015) Jia Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Isomerization of Allylbenzenes

(2015) Mohammad Hassam et al.   CHEMICAL REVIEWS

Nonbiaryl and Heterobiaryl Atropisomers: Molecular Templates with Promise for Atropselective Chemical Transformations

(2015) Elango Kumarasamy et al.   CHEMICAL REVIEWS

Recent advances and new concepts for the synthesis of axially stereoenriched biaryls

(2015) J. Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

An Alternative Mechanism for the Cobalt-Catalyzed Isomerization of Terminal Alkenes to (Z)-2-Alkenes

(2014) Anastasia Schmidt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Well-defined transition metal hydrides in catalytic isomerizations

(2014) Evgeny Larionov et al.   CHEMICAL COMMUNICATIONS

Z-Selective Alkene Isomerization by High-Spin Cobalt(II) Complexes

(2014) Chi Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Intermolecular Asymmetric Allylic Dearomatization Reaction of Naphthol Derivatives

(2013) Chun-Xiang Zhuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combining NHC-Cu and Brønsted Base Catalysis: Enantioselective Allylic Substitution/Conjugate Additions with Alkynylaluminum Reagents and Stereospecific Isomerization of the Products to Trisubstituted Allenes

(2013) Jennifer A. Dabrowski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Tandem Isomerization/Prins Strategy: Iridium(III)/Brønsted Acid Cooperative Catalysis

(2013) Vince M. Lombardo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism and Selectivity of Bioinspired Cinchona Alkaloid Derivatives Catalyzed Asymmetric Olefin Isomerization: A Computational Study

(2013) Xiao-Song Xue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Induction via Short-Lived Chiral Enolates with a Chiral C–O Axis

(2013) Tomoyuki Yoshimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters via Ir-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation and Applications in Sequential Pd Catalysis

(2013) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio-, Diastereo-, and Regioselective Iridium-Catalyzed Asymmetric Allylic Alkylation of Acyclic β-Ketoesters

(2013) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Redox Isomerization of Trifluoromethylated Allylic Alcohols: Mechanistic Evidence for an Enantiospecific Pathway

(2012) Vincent Bizet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Olefin Isomerization by Iridium Pincer Catalysts. Experimental Evidence for an η3-Allyl Pathway and an Unconventional Mechanism Predicted by DFT Calculations

(2012) Soumik Biswas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Trifluoromethylated Amines via Catalytic Enantioselective Isomerization of Imines

(2012) Yongwei Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Alkene Isomerization over One Position

(2012) Casey R. Larsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances and applications of iridium-catalysed asymmetric allylic substitution

(2012) Paolo Tosatti et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Olefin Isomerization of Butenolides via Proton Transfer Catalysis by an Organic Molecule

(2011) Yongwei Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

H/D Exchange Processes Catalyzed by an Iridium-Pincer Complex

(2011) Vlad M. Iluc et al.   ORGANOMETALLICS

Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution

(2010) John F. Hartwig et al.   ACCOUNTS OF CHEMICAL RESEARCH

Atroposelective Total Synthesis of Axially Chiral Biaryl Natural Products

(2010) Gerhard Bringmann et al.   CHEMICAL REVIEWS

Catalytic Asymmetric Synthesis of R207910

(2010) Yutaka Saga et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Ir-Catalyzed Allylic Substitution Reaction of Allyl Sulfinates and Isomerization

(2010) Qing-Long Xu et al.   ORGANIC LETTERS

Stereochemical Relay via Axially Chiral Styrenes: Asymmetric Synthesis of the Antibiotic TAN-1085

(2009) Keiji Mori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen-Bond Control in Axially Chiral Styrenes: Selective Synthesis of Enantiomerically PureC2-Symmetric Paracyclophanes

(2009) Keiji Mori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total synthesis of chiral biaryl natural products by asymmetric biaryl coupling

(2009) Marisa C. Kozlowski et al.   CHEMICAL SOCIETY REVIEWS

Ir-Catalyzed Asymmetric Allylic Substitutions with (Phosphoramidite)Ir Complexes-Resting States, Synthesis, and Characterization of Catalytically Active (π-Allyl)Ir Complexes

(2009) Stephanie Spiess et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium‐Catalyzed H/D Exchange at Vinyl Groups without Olefin Isomerization

(2008) Jianrong Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Double bond migration in N-allylic systems catalyzed by transition metal complexes

(2007) S KROMPIEC et al.   COORDINATION CHEMISTRY REVIEWS