Stereo‐ and Site‐Selective Crotylation of Alcohol Proelectrophiles via Ruthenium‐Catalyzed Hydrogen Auto‐Transfer Mediated by Methylallene and Butadiene

Total Synthesis of the Spliceosome Modulator Pladienolide B via Asymmetric Alcohol‐Mediated syn ‐ and anti ‐Diastereoselective Carbonyl Crotylation

(2021) Minjin Yoo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Hydrogenation to Transfer Hydrogenation to Hydrogen Auto-Transfer in Enantioselective Metal-Catalyzed Carbonyl Reductive Coupling: Past, Present, and Future

(2021) Catherine Gazolla Santana et al.   ACS Catalysis

Allenes and Dienes as Chiral Allylmetal Pronucleophiles in Catalytic Enantioselective C=X Addition: Historical Perspective and State‐of‐The‐Art Survey

(2021) Ming Xiang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Ruthenium-BINAP-Catalyzed Carbonyl Reductive Coupling of Alkoxyallenes: Convergent Construction of syn-sec,tert-Diols via (Z)-σ-Allylmetal Intermediates

(2021) Ming Xiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Late-stage C–H functionalization offers new opportunities in drug discovery

(2021) Lucas Guillemard et al.   Nature Reviews Chemistry

Understanding Halide Counterion Effects in Enantioselective Ruthenium-Catalyzed Carbonyl (α-Aryl)allylation: Alkynes as Latent Allenes and Trifluoroethanol-Enhanced Turnover in The Conversion of Ethanol to Higher Alcohols via Hydrogen Auto-transfer

(2021) Eliezer Ortiz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Control of Absolute Stereochemistry in Transition‐Metal‐Catalyzed Hydrogen Borrowing Reactions

(2020) Timothy Kwok et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper‐Catalyzed Borylative Couplings with C−N Electrophiles

(2020) Fabien J. T. Talbot et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Borylative Difunctionalization of π-Systems

(2020) Andrew Whyte et al.   ACS Catalysis

Enantioselective Allylation Using Allene, a Petroleum Cracking Byproduct

(2019) Richard Y. Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemical syntheses and chemical genetics of carboxyl polyether ionophores: Recent highlights

(2019) Han Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Feedstock Reagents in Metal-Catalyzed Carbonyl Reductive Coupling: Minimizing Preactivation for Efficiency in Target-Oriented Synthesis

(2019) Rosalie S. Doerksen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Inversion of Enantioselectivity in Allene Gas versus Allyl Acetate Reductive Aldehyde Allylation Guided by Metal-Centered Stereogenicity: An Experimental and Computational Study

(2019) Seung Wook Kim et al.   ACS Catalysis

Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines

(2018) Michael Holmes et al.   CHEMICAL REVIEWS

Catalytic nucleophilic ‘umpoled’ π-allyl reagents

(2018) Kim Spielmann et al.   CHEMICAL SOCIETY REVIEWS

Organic synthesis provides opportunities to transform drug discovery

(2018) David C. Blakemore et al.   Nature Chemistry

Cu-Catalyzed Borylative and Silylative Transformations of Allenes: Use of β-Functionalized Allyl Copper Intermediates in Organic Synthesis

(2018) Tetsuaki Fujihara et al.   SYNTHESIS-STUTTGART

Recent advances in homogeneous borrowing hydrogen catalysis using earth-abundant first row transition metals

(2018) Benjamin G. Reed-Berendt et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Site-Selective Functionalization of Hydroxyl Groups in Carbohydrate Derivatives

(2018) Victoria Dimakos et al.   CHEMICAL REVIEWS

Hydrogen-Mediated C−C Bond Formation: Stereo- and Site-Selective Chemical Synthesis Beyond Stoichiometric Organometallic Reagents

(2017) Leyah A. Schwartz et al.   ISRAEL JOURNAL OF CHEMISTRY

Catalytic Deuteration of Aldehydes with D2O

(2017) Stephen Newman et al.   SYNLETT

Enantioselective copper catalysed, direct functionalisation of allenes via allyl copper intermediates

(2017) Alexander P. Pulis et al.   Chemical Science

Catalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges

(2016) Adrien Quintard et al.   CHEMICAL COMMUNICATIONS

The medicinal chemist's toolbox for late stage functionalization of drug-like molecules

(2016) Tim Cernak et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Alcohol C–H Functionalization for Polyketide Construction: Unlocking Redox-Economy and Site-Selectivity for Ideal Chemical Synthesis

(2016) Jiajie Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-BINAP Catalyzed Alcohol C–H tert-Prenylation via 1,3-Enyne Transfer Hydrogenation: Beyond Stoichiometric Carbanions in Enantioselective Carbonyl Propargylation

(2016) Khoa D. Nguyen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of the C9–C25 Subunit of Spirastrellolide B

(2016) Soma Maitra et al.   ORGANIC LETTERS

Homogeneous Ethanol to Butanol Catalysis—Guerbet Renewed

(2016) Hope Aitchison et al.   ACS Catalysis

Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation

(2015) Qin Yang et al.   CHEMICAL SOCIETY REVIEWS

Ruthenium-Catalyzed Asymmetric Hydrohydroxyalkylation of Butadiene: The Role of the Formyl Hydrogen Bond in Stereochemical Control

(2015) Matthew N. Grayson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species

(2015) Kazuhiko Semba et al.   TETRAHEDRON

Catalyst-Directed Diastereo- and Site-Selectivity in Successive Nucleophilic and Electrophilic Allylations of Chiral 1,3-Diols: Protecting-Group-Free Synthesis of Substituted Pyrans

(2014) Inji Shin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Polyketide construction via hydrohydroxyalkylation and related alcohol C–H functionalizations: reinventing the chemistry of carbonyl addition

(2014) Anne-Marie R. Dechert-Schmitt et al.   NATURAL PRODUCT REPORTS

Catalytic asymmetric allylation of carbonyl compounds and imines with allylic boronates

(2014) Hua-Xing Huo et al.   Organic Chemistry Frontiers

Protecting-Group-Free Diastereoselective CC Coupling of 1,3-Glycols and Allyl Acetate through Site-Selective Primary Alcohol Dehydrogenation

(2013) Anne-Marie R. Dechert-Schmitt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of 6-Deoxyerythronolide B via C–C Bond-Forming Transfer Hydrogenation

(2013) Xin Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral-Anion-Dependent Inversion of Diastereo- and Enantioselectivity in Carbonyl Crotylation via Ruthenium-Catalyzed Butadiene Hydrohydroxyalkylation

(2012) Emma L. McInturff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C-H Crotylation of Primary Alcohols via Hydrohydroxyalkylation of Butadiene

(2012) J. R. Zbieg et al.   SCIENCE

The Catalytic Amination of Alcohols

(2011) Sebastian Bähn et al.   ChemCatChem

Catalytic Enantioselective Allylation of Carbonyl Compounds and Imines

(2011) Miguel Yus et al.   CHEMICAL REVIEWS

Diastereo- and Enantioselective Ruthenium-Catalyzed Hydrohydroxyalkylation of 2-Silyl-butadienes: Carbonylsyn-Crotylation from the Alcohol Oxidation Level

(2011) Jason R. Zbieg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nature and strength of C–H⋯O interactions involving formyl hydrogen atoms: computational and experimental studies of small aldehydes

(2011) Tejender S. Thakur et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Hydrogen/Deuterium Exchange Reactions of Olefins with Deuterium Oxide Mediated by the Carbonylchlorohydrido- tris(triphenylphosphine)ruthenium(II) Complex

(2010) Sunny Kai San Tse et al.   ADVANCED SYNTHESIS & CATALYSIS

Dehydrogenation as a Substrate-Activating Strategy in Homogeneous Transition-Metal Catalysis

(2009) Graham E. Dobereiner et al.   CHEMICAL REVIEWS

anti-Aminoallylation of Aldehydes via Ruthenium-Catalyzed Transfer Hydrogenative Coupling of Sulfonamido Allenes: 1,2-Aminoalcohols

(2009) Eduardas Skucas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Carbonyl Reverse Prenylation from the Alcohol or Aldehyde Oxidation Level Employing 1,1-Dimethylallene as the Prenyl Donor

(2009) Soo Bong Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Drug Discovery and Natural Products: End of an Era or an Endless Frontier?

(2009) J. W.-H. Li et al.   SCIENCE

Synthetic Efforts toward the Macrolactone Core of Leucascandrolide A

(2008) Laurent Ferrié et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed C−C Bond Forming Transfer Hydrogenation: Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Employing Acyclic 1,3-Dienes as Surrogates to Preformed Allyl Metal Reagents

(2008) Fumitoshi Shibahara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Spirastrellolide B: The Synthesis of Southern (C9−C25) Region

(2008) Srivari Chandrasekhar et al.   ORGANIC LETTERS