N-Triftosylhydrazones: A New Chapter for Diazo-Based Carbene Chemistry

Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds

(2022) Shunxi Dong et al.   ACCOUNTS OF CHEMICAL RESEARCH

Direct gem‐Difluoroalkenylation of X–H Bonds with Trifluoromethyl Ketone N‐Triftosylhydrazones for Synthesis of Tetrasubstituted Heteroatomic gem‐Difluoroalkenes

(2022) Xinyu Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silver-catalyzed site-selective C(sp3)−H benzylation of ethers with N-triftosylhydrazones

(2022) Zhaohong Liu et al.   Nature Communications

Fluoroalkyl N-sulfonyl hydrazones: An efficient reagent for the synthesis of fluoroalkylated compounds

(2021) Paramasivam Sivaguru et al.   Science China-Chemistry

Fluoroalkyl N-Triftosylhydrazones as Easily Decomposable Diazo Surrogates for Asymmetric [2 + 1] Cycloaddition: Synthesis of Chiral Fluoroalkyl Cyclopropenes and Cyclopropanes

(2021) Xinyu Zhang et al.   ACS Catalysis

A Carbene Strategy for Progressive (Deutero)Hydrodefluorination of Fluoroalkyl Ketones

(2021) Xiaolong Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Carbene Coupling Reactions of Cyclobutanone N-Sulfonylhydrazones

(2021) Xiaoqin Ning et al.   ORGANIC LETTERS

Catalytic Asymmetric C(sp3)–H Carbene Insertion Approach to Access Enantioenriched 3-Fluoroalkyl 2,3-Dihydrobenzofurans

(2021) Xinyu Zhang et al.   ACS Catalysis

Difluoroacetaldehyde N -Triftosylhydrazone (DFHZ-Tfs) as a Bench-Stable Crystalline Diazo Surrogate for Diazoacetaldehyde and Difluorodiazoethane

(2020) Yongquan Ning et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Three-Component Reaction for the Synthesis of Highly Functionalized Propargyl Ethers

(2020) Guillaume Pisella et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal-Catalyzed Cross-Coupling with Ketones or Aldehydes via N-Tosylhydrazones

(2020) Ying Xia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition Metal Catalyzed Insertion Reactions with Donor/Donor Carbenes

(2020) Jared Thomas Shaw et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-Selective C–H Benzylation of Alkanes with N-Triftosylhydrazones Leading to Alkyl Aromatics

(2020) Zhaohong Liu et al.   Chem

2,2,2-Trifluorodiazoethane (CF3CHN2): A Long Journey since 1943

(2020) Pavel K. Mykhailiuk   CHEMICAL REVIEWS

Palladium(II)-Catalyzed Cross-Coupling of Diazo Compounds and Isocyanides to Access Ketenimines

(2020) Zhaohong Liu et al.   ACS Catalysis

Use of trifluoroacetaldehyde N-tfsylhydrazone as a trifluorodiazoethane surrogate and its synthetic applications

(2019) Xinyu Zhang et al.   Nature Communications

Dirhodium tetracarboxylates as catalysts for selective intermolecular C–H functionalization

(2019) Huw M. L. Davies et al.   Nature Reviews Chemistry

Thermal Stability and Explosive Hazard Assessment of Diazo Compounds and Diazo Transfer Reagents

(2019) Sebastian P. Green et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Modern Approaches for Asymmetric Construction of Carbon–Fluorine Quaternary Stereogenic Centers: Synthetic Challenges and Pharmaceutical Needs

(2018) Yi Zhu et al.   CHEMICAL REVIEWS

The Generation of Diazo Compounds in Continuous-Flow

(2018) Katharina J. Hock et al.   CHEMISTRY-A EUROPEAN JOURNAL

Picking one out of three: selective single C-F activation in trifluoromethyl groups

(2018) Florian Jaroschik   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Copper-Catalyzed Oxy-Alkynylation of Diazo Compounds

(2017) Durga Prasad Hari et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Radical Cyclopropanation of Alkenes with In Situ-Generated Donor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis

(2017) Yong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-selective and stereoselective functionalization of non-activated tertiary C–H bonds

(2017) Kuangbiao Liao et al.   NATURE

Silver-Catalyzed Cyclopropanation of Alkenes Using N-Nosylhydrazones as Diazo Surrogates

(2017) Zhaohong Liu et al.   ORGANIC LETTERS

New Approaches to the Synthesis of Metal Carbenes

(2016) Minqiang Jia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Site-selective and stereoselective functionalization of unactivated C–H bonds

(2016) Kuangbiao Liao et al.   NATURE

Fluorinated diazoalkanes – a versatile class of reagents for the synthesis of fluorinated compounds

(2016) Lucas Mertens et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Modern Organic Synthesis with α-Diazocarbonyl Compounds

(2015) Alan Ford et al.   CHEMICAL REVIEWS

Catalytic Stereoselective [2,3]-Rearrangement Reactions

(2015) Thomas H. West et al.   ACS Catalysis

Recent applications of the divinylcyclopropane–cycloheptadiene rearrangement in organic synthesis

(2014) Sebastian Krüger et al.   Beilstein Journal of Organic Chemistry

Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks

(2014) Theresia Ahrens et al.   CHEMICAL REVIEWS

Lewis and Brønsted Acid Cocatalyzed Reductive Deoxyallenylation of Propargylic Alcohols with 2-Nitrobenzenesulfonylhydrazide

(2014) Zhaohong Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Insertion of a Carbenoid Carbon into a C–C Bond To Expand Cyclobutanols to Cyclopentanols

(2014) Akira Yada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic X–H insertion reactions based on carbenoids

(2013) Dennis Gillingham et al.   CHEMICAL SOCIETY REVIEWS

Diazo Compounds and N-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions

(2012) Qing Xiao et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions

(2012) Shou-Fei Zhu et al.   ACCOUNTS OF CHEMICAL RESEARCH

The thriving chemistry of ketenimines

(2012) Ping Lu et al.   CHEMICAL SOCIETY REVIEWS

Tosylhydrazones: New Uses for Classic Reagents in Palladium-Catalyzed Cross-Coupling and Metal-Free Reactions

(2011) José Barluenga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Silver-Catalyzed C-C Bond Formation Between Methane and Ethyl Diazoacetate in Supercritical CO2

(2011) A. Caballero et al.   SCIENCE