Dirhodium tetracarboxylates as catalysts for selective intermolecular C–H functionalization

Electrochemical strategies for C–H functionalization and C–N bond formation

(2018) Markus D. Kärkäs   CHEMICAL SOCIETY REVIEWS

Nickel-Catalyzed Enantioselective Pyridone C–H Functionalizations Enabled by a Bulky N-Heterocyclic Carbene Ligand

(2018) Johannes Diesel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective C(sp3)‒H bond activation by chiral transition metal catalysts

(2018) Tyler G. Saint-Denis et al.   SCIENCE

Remote C–H Functionalization via Selective Hydrogen Atom Transfer

(2018) David Nagib et al.   SYNTHESIS-STUTTGART

The Quest for Selectivity in Hydrogen Atom Transfer Based Aliphatic C–H Bond Oxygenation

(2018) Michela Milan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Visible Light Induced C-H Bonds Functionalization: A Critical Review

(2018) Lekkala Ravindar et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Chemo- and Stereoselective Catalyst-Controlled Allylic C−H Insertion and Cyclopropanation Using Donor/Donor Carbenes

(2018) Dong Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst-Controlled Selective Functionalization of Unactivated C–H Bonds in the Presence of Electronically Activated C–H Bonds

(2018) Wenbin Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective remote meta-C–H arylation and alkylation via a chiral transient mediator

(2018) Hang Shi et al.   NATURE

Design of catalysts for site-selective and enantioselective functionalization of non-activated primary C–H bonds

(2018) Kuangbiao Liao et al.   Nature Chemistry

Enantioselective Cobalt(III)-Catalyzed C−H Activation Enabled by Chiral Carboxylic Acid Cooperation

(2018) Fabio Pesciaioli et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Desymmetrization of cyclohexanes by site- and stereoselective C–H functionalization

(2018) Jiantao Fu et al.   NATURE

Site-selective and stereoselective functionalization of non-activated tertiary C–H bonds

(2017) Kuangbiao Liao et al.   NATURE

C–H functionalisation of cycloalkanes

(2017) Arghya Banerjee et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Site-Selective C–H Functionalization by Decatungstate Anion Photocatalysis: Synergistic Control by Polar and Steric Effects Expands the Reaction Scope

(2017) Davide Ravelli et al.   ACS Catalysis

Site-Selective Carbene-Induced C–H Functionalization Catalyzed by Dirhodium Tetrakis(triarylcyclopropanecarboxylate) Complexes

(2017) Kuangbiao Liao et al.   ACS Catalysis

Chemoselective Aliphatic C–H Bond Oxidation Enabled by Polarity Reversal

(2017) Valeria Dantignana et al.   ACS Central Science

Highly Enantioselective Oxidation of Nonactivated Aliphatic C–H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes

(2017) Michela Milan et al.   ACS Central Science

Rapid Construction of a Benzo-Fused Indoxamycin Core Enabled by Site-Selective C−H Functionalizations

(2016) T. Aaron Bedell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Intramolecular C−H Insertion of Donor and Donor/Donor Carbenes by a Nondiazo Approach

(2016) Dong Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in C–H Functionalization

(2016) Huw M. L. Davies et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(II)-Catalyzed C–H Functionalization of Electron-Deficient Methyl Groups

(2016) Liangbing Fu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-selective and stereoselective functionalization of unactivated C–H bonds

(2016) Kuangbiao Liao et al.   NATURE

Catalyst-controlled selectivity in the C-H borylation of methane and ethane

(2016) A. K. Cook et al.   SCIENCE

Iridium(iii)-bis(imidazolinyl)phenyl catalysts for enantioselective C–H functionalization with ethyl diazoacetate

(2016) N. Mace Weldy et al.   Chemical Science

Catalytic functionalization of low reactive C(sp3)–H and C(sp2)–H bonds of alkanes and arenes by carbene transfer from diazo compounds

(2015) Ana Caballero et al.   DALTON TRANSACTIONS

Enhanced Reactivity in Hydrogen Atom Transfer from Tertiary Sites of Cyclohexanes and Decalins via Strain Release: Equatorial C–H Activation vs Axial C–H Deactivation

(2015) Michela Salamone et al.   JOURNAL OF ORGANIC CHEMISTRY

Alcohols as alkylating agents in heteroarene C–H functionalization

(2015) Jian Jin et al.   NATURE

The direct arylation of allylic sp3 C–H bonds via organic and photoredox catalysis

(2015) James D. Cuthbertson et al.   NATURE

Palladium-catalysed norbornene-mediated C–H functionalization of arenes

(2015) Juntao Ye et al.   Nature Chemistry

Elevated Catalytic Activity of Ruthenium(II)-Porphyrin-Catalyzed Carbene/Nitrene Transfer and Insertion Reactions with N-Heterocyclic Carbene Ligands

(2014) Ka-Ho Chan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H Functionalization in the Synthesis of Amino Acids and Peptides

(2014) Anaïs F. M. Noisier et al.   CHEMICAL REVIEWS

Terminal Olefins to Chromans, Isochromans, and Pyrans via Allylic C–H Oxidation

(2014) Stephen E. Ammann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

2,2,2-Trichloroethyl Aryldiazoacetates as Robust Reagents for the Enantioselective C–H Functionalization of Methyl Ethers

(2014) David M. Guptill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Role of Sterically Demanding Chiral Dirhodium Catalysts in Site-Selective C–H Functionalization of Activated Primary C–H Bonds

(2014) Changming Qin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Intramolecular C–H Insertion Reactions of Donor–Donor Metal Carbenoids

(2014) Cristian Soldi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Overcoming the limitations of directed C–H functionalizations of heterocycles

(2014) Yue-Jin Liu et al.   NATURE

Sequential C–H Functionalization Reactions for the Enantioselective Synthesis of Highly Functionalized 2,3-Dihydrobenzofurans

(2013) Hengbin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

The Combined C–H Functionalization/Cope Rearrangement: Discovery and Applications in Organic Synthesis

(2012) Huw M. L. Davies et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metal-Catalyzed Nitrogen-Atom Transfer Methods for the Oxidation of Aliphatic C–H Bonds

(2012) Jennifer L. Roizen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization

(2012) Sharon R. Neufeldt et al.   ACCOUNTS OF CHEMICAL RESEARCH

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic functionalization of unactivated primary C–H bonds directed by an alcohol

(2012) Eric M. Simmons et al.   NATURE

Design and Synthesis of Chiral Heteroleptic Rhodium(II) Carboxylate Catalysts: Experimental Investigation of Halogen Bond Rigidification Effects in Asymmetric Cyclopropanation

(2012) Vincent N. G. Lindsay et al.   ACS Catalysis

Innate and Guided C–H Functionalization Logic

(2011) Tobias Brückl et al.   ACCOUNTS OF CHEMICAL RESEARCH

Imparting Catalyst Control upon Classical Palladium-Catalyzed Alkenyl C–H Bond Functionalization Reactions

(2011) Matthew S. Sigman et al.   ACCOUNTS OF CHEMICAL RESEARCH

Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions

(2011) Keary M. Engle et al.   ACCOUNTS OF CHEMICAL RESEARCH

If CH Bonds Could Talk: Selective CH Bond Oxidation

(2011) Timothy Newhouse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H Functionalization in organic synthesis

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

C–H functionalization logic in total synthesis

(2011) Will R. Gutekunst et al.   CHEMICAL SOCIETY REVIEWS

Guiding principles for site selective and stereoselective intermolecular C–H functionalization by donor/acceptor rhodium carbenes

(2011) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

D2-Symmetric Dirhodium Catalyst Derived from a 1,2,2-Triarylcyclopropanecarboxylate Ligand: Design, Synthesis and Application

(2011) Changming Qin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combined C–H Functionalization/Cope Rearrangement with Vinyl Ethers as a Surrogate for the Vinylogous Mukaiyama Aldol Reaction

(2011) Yajing Lian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Syntheses of Azetidines, Pyrrolidines, and Indolines via Palladium Catalyzed Intramolecular Amination of C(sp3)–H and C(sp2)–H Bonds at γ and δ Positions

(2011) Gang He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Mechanism and Selectivity of the Combined C−H Activation/Cope Rearrangement

(2011) Jørn H. Hansen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed C-C Bond Formation Between Methane and Ethyl Diazoacetate in Supercritical CO2

(2011) A. Caballero et al.   SCIENCE

Catalyst Control of Site Selectivity in the PdII/IV-Catalyzed Direct Arylation of Naphthalene

(2011) Amanda J. Hickman et al.   ACS Catalysis

The chiral crown conformation in paddlewheel complexes

(2010) Andrew DeAngelis et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

(2010) Thomas W. Lyons et al.   CHEMICAL REVIEWS

Enzymatic functionalization of carbon–hydrogen bonds

(2010) Jared C. Lewis et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Carbene Insertion into C−H Bonds

(2009) Michael P. Doyle et al.   CHEMICAL REVIEWS

Application of donor/acceptor-carbenoids to the synthesis of natural products

(2009) Huw M. L. Davies et al.   CHEMICAL SOCIETY REVIEWS

Computational Study on the Selectivity of Donor/Acceptor-Substituted Rhodium Carbenoids

(2009) Jørn Hansen et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Crown Conformation of Rh2(S-PTTL)4: Enantioselective Cyclopropanation with α-Alkyl-α-diazoesters

(2009) Andrew DeAngelis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Evidence for the All-Up Reactive Conformation of Chiral Rhodium(II) Carboxylate Catalysts: Enantioselective Synthesis ofcis-Cyclopropane α-Amino Acids

(2009) Vincent N. G. Lindsay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium(III) Catalyzed Diastereo- and Enantioselective C−H Bond Functionalization

(2009) Hidehiro Suematsu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Metal Catalysts for Intermolecular Carbenoid Insertion into Primary CH Bonds and Enantioselective CC Bond Formation

(2008) Hung-Yat Thu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Condensed Pyrroloindoles via Pd-Catalyzed Intramolecular C−H Bond Functionalization of Pyrroles

(2008) Seung Jun Hwang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Bond Functionalization via Hydride Transfer: Lewis Acid Catalyzed Alkylation Reactions by Direct Intramolecular Coupling of sp3C−H Bonds and Reactive Alkenyl Oxocarbenium Intermediates

(2008) Kevin M. McQuaid et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE

High symmetry dirhodium(II) paddlewheel complexes as chiral catalysts

(2007) Jørn Hansen et al.   COORDINATION CHEMISTRY REVIEWS