Stereodivergent Synthesis of Enantioenriched 2,3-Disubstituted Dihydrobenzofurans via a One-Pot C–H Functionalization/Oxa-Michael Addition Cascade

Regiospecific and Enantioselective Arylvinylcarbene Insertion of a C–H Bond of Aniline Derivatives Enabled by a Rh(I)-Diene Catalyst

(2021) Dong-Xing Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Isochroman Derivatives

(2020) Tamanna et al.   ADVANCED SYNTHESIS & CATALYSIS

Stereodivergent Pd/Cu Catalysis for the Dynamic Kinetic Asymmetric Transformation of Racemic Unsymmetrical 1,3-Disubstituted Allyl Acetates

(2020) Rui He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Advances in Synthetic Strategies to 2,3-Dihydrobenzofurans

(2020) Paolo Lupattelli et al.   SYNTHESIS-STUTTGART

Recent Advances in Squaramide‐Catalyzed Asymmetric Mannich Reactions

(2020) Xi‐Qiang Hou et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent Advances in Asymmetric Organomulticatalysis

(2020) Xiao Xiao et al.   ADVANCED SYNTHESIS & CATALYSIS

Synergistic Dual Transition Metal Catalysis

(2020) U Bin Kim et al.   CHEMICAL REVIEWS

Stereodivergent Synthesis through Catalytic Asymmetric Reversed Hydroboration

(2019) Tao-Tao Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Catalytic [4+1]‐Cyclization of ortho ‐Hydroxy‐ para ‐Quinone Methides with Allenoates

(2019) Katharina Zielke et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Synthesis of Enantioenriched 2-Aryl-2,3-Dihydro-benzofuran via a Lewis Acid-Catalyzed Tandem Cyclopropanation/ Intramolecular Rearrangement

(2019) Do Hyun Ryu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodivergent Construction of Tertiary Fluorides in Vicinal Stereogenic Pairs by Allylic Substitution with Iridium and Copper Catalysts

(2019) Zhi-Tao He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergetic iridium and amine catalysis enables asymmetric [4+2] cycloadditions of vinyl aminoalcohols with carbonyls

(2019) Mao-Mao Zhang et al.   Nature Communications

Stereodivergent Coupling of 1,3-Dienes with Aldimine Esters Enabled by Synergistic Pd and Cu Catalysis

(2019) Qinglong Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bifunctional Phosphonium Salt Directed Enantioselective Formal [4 + 1] Annulation of Hydroxyl-Substituted para-Quinone Methides with α-Halogenated Ketones

(2019) Jian-Ping Tan et al.   ORGANIC LETTERS

Synergistic Pd/Cu Catalysis in Organic Synthesis

(2019) Yue Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Different Strategies for Designing Dual-Catalytic Enantioselective Processes: From Fully Cooperative to Non-cooperative Systems

(2019) Filippo Romiti et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sequence-Dependent Stereodivergent Allylic Alkylation/Fluorination of Acyclic Ketones

(2019) Xi-Jia Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodivergent assembly of tetrahydro-γ-carbolines via synergistic catalytic asymmetric cascade reaction

(2019) Shi-Ming Xu et al.   Nature Communications

Diastereodivergent synthesis of enantioenriched α,β-disubstituted γ-butyrolactones via cooperative N-heterocyclic carbene and Ir catalysis

(2019) Santanu Singha et al.   Nature Catalysis

Stereodivergent Catalysis

(2018) Irina P. Beletskaya et al.   CHEMICAL REVIEWS

Stereodivergent Synthesis of α,α-Disubstituted α-Amino Acids via Synergistic Cu/Ir Catalysis

(2018) Liang Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Allylation of Azaaryl Acetamides and Acetates by Synergistic Iridium and Copper Catalysis

(2018) Xingyu Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ir/Cu Dual Catalysis: Enantio- and Diastereodivergent Access to α,α-Disubstituted α-Amino Acids Bearing Vicinal Stereocenters

(2018) Xiaohong Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective [3 + 2] Formal Cycloaddition of 1-Styrylnaphthols with Quinones Catalyzed by a Chiral Phosphoric Acid

(2018) Wang Feng et al.   ORGANIC LETTERS

Stereodivergent synthesis of vicinal quaternary-quaternary stereocenters and bioactive hyperolactones

(2018) Haifeng Zheng et al.   Nature Communications

Asymmetric Phosphine-Catalyzed [4 + 1] Annulations of o-Quinone Methides with MBH Carbonates

(2018) Tao Zhou et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Rh(I)-Catalyzed Functionalization of the 3-C(sp3)–H Bond of Benzofuranones with α-Diazoesters

(2018) Yuanhong Liu et al.   ORGANIC LETTERS

Stereodivergent synthesis of 1,4-dicarbonyls by traceless charge–accelerated sulfonium rearrangement

(2018) Dainis Kaldre et al.   SCIENCE

Phosphine-mediated enantioselective [4 + 1] annulations between ortho-quinone methides and Morita–Baylis–Hillman carbonates

(2018) Yuyu Cheng et al.   Organic Chemistry Frontiers

Phosphoric Acid Catalyzed [4 + 1]-Cycloannulation Reaction of ortho-Quinone Methides and Diazoketones: Catalytic, Enantioselective Access toward cis-2,3-Dihydrobenzofurans

(2018) Arun Suneja et al.   ORGANIC LETTERS

Stereodivergent Coupling of Aldehydes and Alkynes via Synergistic Catalysis Using Rh and Jacobsen’s Amine

(2017) Faben A. Cruz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergence in Asymmetric Catalysis

(2017) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative bimetallic catalysis in asymmetric allylic substitution

(2017) Jingke Fu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Synthesis of gem-Diaryl Benzofuran-3(2H)-ones via One-Pot Asymmetric Rhodium/Palladium Relay Catalysis

(2017) Zong-Feng Zhang et al.   ORGANIC LETTERS

Bimetallic catalysis for C–C and C–X coupling reactions

(2017) Dominic R. Pye et al.   Chemical Science

Enantioselective Oxy-Heck-Matsuda Arylations: Expeditious Synthesis of Dihydrobenzofuran Systems and Total Synthesis of the Neolignan (−)-Conocarpan

(2017) Allan R. Silva et al.   ADVANCED SYNTHESIS & CATALYSIS

Diastereo- and enantioselective construction of an indole-based 2,3-dihydrobenzofuran scaffold via catalytic asymmetric [3+2] cyclizations of quinone monoimides with 3-vinylindoles

(2016) Xiao-Xue Sun et al.   CHEMICAL COMMUNICATIONS

Combinations of Aminocatalysts and Metal Catalysts: A Powerful Cooperative Approach in Selective Organic Synthesis

(2016) Samson Afewerki et al.   CHEMICAL REVIEWS

Isochromans and Related Constituents from the Endophytic Fungus Annulohypoxylon truncatum of Zizania caduciflora and Their Anti-Inflammatory Effects

(2016) Wei Li et al.   JOURNAL OF NATURAL PRODUCTS

An Ir/Zn Dual Catalysis for Enantio- and Diastereodivergent α-Allylation of α-Hydroxyketones

(2016) Xiaohong Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis

(2016) Xingyu Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium(I)-Catalyzed Highly Enantioselective Insertion of Carbenoid into Si–H: Efficient Access to Functional Chiral Silanes

(2016) Diao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalysed enantioselective stereodivergent synthesis of amino alcohols

(2016) Shi-Liang Shi et al.   NATURE

Enantioselective synthesis of 2,3-disubstituted trans-2,3-dihydrobenzofurans using a Brønsted base/thiourea bifunctional catalyst

(2016) Diego-Javier Barrios Antúnez et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Chiral Phosphoric Acid Catalyzed [3 + 2] Cycloaddition and Tandem Oxidative [3 + 2] Cycloaddition: Asymmetric Synthesis of Substituted 3-Aminodihydrobenzofurans

(2016) Coralie Gelis et al.   ORGANIC LETTERS

Recent application of oxa-Michael reaction in complex natural product synthesis

(2016) Jialei Hu et al.   TETRAHEDRON LETTERS

Stereodivergent Dual Catalytic α-Allylation of Protected α-Amino- and α-Hydroxyacetaldehydes

(2015) Tobias Sandmeier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(I)-Catalyzed Asymmetric Carbene Insertion into B–H Bonds: Highly Enantioselective Access to Functionalized Organoboranes

(2015) Diao Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combined Asymmetric Aminocatalysis and Carbene Catalysis

(2015) Ying-Chun Chen et al.   SYNTHESIS-STUTTGART

Catalytic asymmetric synthesis of (−)-E-δ-viniferin via an intramolecular C–H insertion of diaryldiazomethane using Rh2(S-TFPTTL)4

(2015) Yoshihiro Natori et al.   TETRAHEDRON LETTERS

Asymmetric Organocatalysis Combined with Metal Catalysis: Concept, Proof of Concept, and Beyond

(2014) Dian-Feng Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

An Ylide Transformation of Rhodium(I) Carbene: Enantioselective Three-Component Reaction through Trapping of Rhodium(I)-Associated Ammonium Ylides by β-Nitroacrylates

(2014) Xiaochu Ma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodivergent Total Synthesis of Δ9-Tetrahydrocannabinols

(2014) Michael A. Schafroth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic–cooperative combination of enamine catalysis with transition metal catalysis

(2014) Yongming Deng et al.   CHEMICAL COMMUNICATIONS

Stereodivergent Organocatalytic Intramolecular Michael Addition/Lactonization for the Asymmetric Synthesis of Substituted Dihydrobenzofurans and Tetrahydrofurans

(2014) Dorine Belmessieri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Asymmetric Reactions by Metal and Chiral Phosphoric Acid Sequential Catalysis

(2014) Ze-Peng Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereodivergent α-Allylation of Linear Aldehydes with Dual Iridium and Amine Catalysis

(2014) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Intramolecular C–H Insertion Reactions of Donor–Donor Metal Carbenoids

(2014) Cristian Soldi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Insertion of a Carbenoid Carbon into a C–C Bond To Expand Cyclobutanols to Cyclopentanols

(2014) Akira Yada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Powerful Hydrogen-Bond-Donating Organocatalyst for the Enantioselective Intramolecular Oxa-Michael Reaction of α,β-Unsaturated Amides and Esters

(2013) Yusuke Kobayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dual Catalysis Becomes Diastereodivergent

(2013) Maria Teresa Oliveira et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Inner Workings of a Cinchona Alkaloid Catalyzed Oxa-Michael Cyclization: Evidence for a Concerted Hydrogen-Bond-Network Mechanism

(2013) Lukas Hintermann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bifunctional Primary Amine-Squaramide Catalyzed Enantioselective Intramolecular Michael Addition of Keto-enones: A Convenient Process to the Stereocontrolled Construction oftrans-Dihydrobenzofuran Skeletons

(2013) Yunting Liu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis, Structure, and Cytotoxicity Studies of Some Fungal Isochromanes

(2013) Kouji Kuramochi et al.   JOURNAL OF NATURAL PRODUCTS

Sequential C–H Functionalization Reactions for the Enantioselective Synthesis of Highly Functionalized 2,3-Dihydrobenzofurans

(2013) Hengbin Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A New Twist on Cooperative Catalysis

(2013) C. S. Schindler et al.   SCIENCE

Enantio- and Diastereodivergent Dual Catalysis:  -Allylation of Branched Aldehydes

(2013) S. Krautwald et al.   SCIENCE

Copper-Catalyzed Enantioselective Allylic Substitution with Readily Accessible Carbonyl- and Acetal-Containing Vinylboron Reagents

(2012) Fang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis, Stereochemistry, Structural Classification, and Chemical Reactivity of Natural Pterocarpans

(2012) Atul Goel et al.   CHEMICAL REVIEWS

Stereocontrolled Organocatalytic Strategy for the Synthesis of Optically Active 2,3-Disubstitutedcis-2,3-Dihydrobenzofurans

(2012) Jannie Christensen et al.   Chemistry-An Asian Journal

Enantioselective Synthesis of trans-Dihydrobenzofurans via Primary Amine-Thiourea Organocatalyzed Intramolecular Michael Addition

(2012) Aidang Lu et al.   JOURNAL OF ORGANIC CHEMISTRY

Synergistic catalysis: A powerful synthetic strategy for new reaction development

(2012) Anna E. Allen et al.   Chemical Science

Recent developments in the field of oxa-Michael reactions

(2011) Carl F. Nising et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of Oxacycles Employing the Oxa-Pictet-Spengler Reaction: Recent Developments and New Prospects

(2011) Enrique L. Larghi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Bifunctional organo/metal cooperative catalysis with cinchona alkaloid scaffolds

(2011) Linus Stegbauer et al.   Chemical Science

Asymmetric Cyclopropanation of Alkenes with Dimethyl Diazomalonate Catalyzed by Chiral Diene-Rhodium Complexes

(2010) Takahiro Nishimura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

When Organocatalysis Meets Transition-Metal Catalysis

(2010) Cheng Zhong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cycle-Specific Organocascade Catalysis: Application to Olefin Hydroamination, Hydro-oxidation, and Amino-oxidation, and to Natural Product Synthesis

(2009) Bryon Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

COX, LOX and platelet aggregation inhibitory properties of Lauraceae neolignans

(2009) Ericsson David Coy et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Combining transition metal catalysis and organocatalysis: a broad new concept for catalysis

(2009) Zhihui Shao et al.   CHEMICAL SOCIETY REVIEWS

Pseudoanguillosporin A and B: Two New Isochromans Isolated from the Endophytic FungusPseudoanguillosporasp.

(2009) Ines Kock et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthetic Analogue of Rocaglaol Displays a Potent and Selective Cytotoxicity in Cancer Cells: Involvement of Apoptosis Inducing Factor and Caspase-12

(2009) Frédéric Thuaud et al.   JOURNAL OF MEDICINAL CHEMISTRY

Organocatalytic Asymmetric Formal [3 + 2] Cycloaddition with in Situ-GeneratedN-Carbamoyl Nitrones

(2009) Claudio Gioia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric catalysis with bifunctional cinchona alkaloid-based urea and thiourea organocatalysts

(2008) Stephen J. Connon   CHEMICAL COMMUNICATIONS

The oxa-Michael reaction: from recent developments to applications in natural product synthesis

(2008) Carl F. Nising et al.   CHEMICAL SOCIETY REVIEWS

Guanidine-Catalyzed Asymmetric Synthesis of 2,2-Disubstituted Chromane Skeletons by Intramolecular Oxa-Michael Addition

(2008) Noriko Saito et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Lignans and Other Constituents of the Fruits ofEuterpe oleracea(Açai) with Antioxidant and Cytoprotective Activities

(2008) Young-Won Chin et al.   JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY