Rhodium-Catalyzed Dynamic Kinetic Asymmetric Allylation of Phenols and 2-Hydroxypyridines

Incorporation of the Constrained Peptidomimetic, 5-Methylpyridin-2-one into Peptide Vinyl Sulfones and Peptide Epoxy Ketones is Detrimental for Proteasome Inhibition

(2016) Bo-Tao Xin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Regio- and Enantioselective Synthesis of N-Substituted Pyrazoles by Rhodium-Catalyzed Asymmetric Addition to Allenes

(2015) Alexander M. Haydl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Controlled Regiodivergent Palladium-Catalyzed Decarboxylative Allylation Reaction to Access α,α-Difluoroketones

(2015) Ming-Hsiu Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Rhodium-Catalyzed Addition of Thiols to Allenes: Synthesis of Branched Allylic Thioethers and Sulfones

(2015) Adrian B. Pritzius et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodivergent Dual Catalytic α-Allylation of Protected α-Amino- and α-Hydroxyacetaldehydes

(2015) Tobias Sandmeier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Enantioselective Allylic Alkylation with Functionalized Organozinc Bromides

(2015) James Y. Hamilton et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides

(2015) Ming Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Redox-Neutral Rh-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters

(2015) Philipp Koschker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereospecific Rhodium-Catalyzed Allylic Substitution with Alkenyl Cyanohydrin Pronucleophiles: Construction of Acyclic Quaternary Substituted α,β-Unsaturated Ketones

(2015) Ben W. H. Turnbull et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formaldehyde N,N-Dialkylhydrazones as Neutral Formyl Anion Equivalents in Iridium-Catalyzed Asymmetric Allylic Substitution

(2015) Simon Breitler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-catalysed asymmetric allylic arylation of racemic halides with arylboronic acids

(2015) Mireia Sidera et al.   Nature Chemistry

Enantioselective synthesis of 4-substituted tetrahydroisoquinolines via palladium-catalyzed intramolecular Friedel–Crafts type allylic alkylation of phenols

(2015) Zheng-Le Zhao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric synthesis of N-allylic indoles via regio- and enantioselective allylation of aryl hydrazines

(2015) Kun Xu et al.   Nature Communications

Palladium-Catalyzed Asymmetric Decarboxylative Cycloaddition of Vinylethylene Carbonates with Michael Acceptors: Construction of Vicinal Quaternary Stereocenters

(2014) Ajmal Khan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Enantioselective Allylic Substitution of Unstabilized Enolates Derived from α,β-Unsaturated Ketones

(2014) Ming Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Asymmetric Dearomatization of Pyridines and Pyrazines by Iridium-Catalyzed Allylic Amination Reactions

(2014) Ze-Peng Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Chemo-, Regio-, and Enantioselective Addition of 2-Pyridones to Terminal Allenes

(2014) Changkun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Sequential Allylic Amination and Olefin Hydroacylation Reactions: Enantioselective Synthesis of Seven-Membered Nitrogen Heterocycles

(2014) Jeffrey S. Arnold et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Decarboxylative Cycloaddition of Vinylethylene Carbonates with Formaldehyde: Enantioselective Construction of Tertiary Vinylglycols

(2014) Ajmal Khan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atom-Economic, Regiodivergent, and Stereoselective Coupling of Imidazole Derivatives with Terminal Allenes

(2014) Kun Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Regio- and Enantioselective Synthesis of N-Substituted 2-Pyridones: Iridium-Catalyzed Intermolecular Asymmetric Allylic Amination

(2014) Xiao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Silyl Dienolates Derived from Dioxinones

(2014) Ming Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantio- and Regioselective Iridium-Catalyzed Allylic Esterification

(2014) Jianping Qu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Chemo- and Regioselective Decarboxylative Addition of β-Ketoacids to Allenes: Efficient Construction of Tertiary and Quaternary Carbon Centers

(2014) Changkun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Regio- and Enantioselective Allylic Amination of Racemic 1-Arylallyl Esters

(2014) Motoi Kawatsura et al.   ORGANIC LETTERS

Asymmetric Auto-Tandem Catalysis with a Planar-Chiral Ruthenium Complex: Sequential Allylic Amidation and Atom-Transfer Radical Cyclization

(2013) Naoya Kanbayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides

(2013) Yang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Chiral Sulfoxide-Ligated Ruthenium Complex for Asymmetric Catalysis: Enantio- and Regioselective Allylic Substitution

(2013) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio-, Diastereo-, and Regioselective Iridium-Catalyzed Asymmetric Allylic Alkylation of Acyclic β-Ketoesters

(2013) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigations of the Rhodium Catalyzed Propargylic CH Activation

(2013) Urs Gellrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ir(I)-Catalyzed Enantioselective Decarboxylative Allylic Etherification: A General Method for the Asymmetric Synthesis of Aryl Allyl Ethers

(2013) Dongeun Kim et al.   ORGANIC LETTERS

Regio- and Enantiospecific Rhodium-Catalyzed Allylic Substitution with an Acyl Anion Equivalent

(2013) P. Andrew Evans et al.   ORGANIC LETTERS

Enantio- and Diastereodivergent Dual Catalysis:  -Allylation of Branched Aldehydes

(2013) S. Krautwald et al.   SCIENCE

Enantioselective Rhodium-Catalyzed Synthesis of Branched Allylic Amines by Intermolecular Hydroamination of Terminal Allenes

(2012) Michael L. Cooke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed regio- and enantioselective amination of racemic secondary allylic trichloroacetimidates with N-methyl anilines

(2012) Jeffrey S. Arnold et al.   CHEMICAL COMMUNICATIONS

Rhodium-Catalyzed Dynamic Kinetic Asymmetric Transformations of Racemic Tertiary Allylic Trichloroacetimidates with Anilines

(2012) Jeffrey S. Arnold et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Allylic Substitution with an Acyl Anion Equivalent: Stereospecific Construction of Acyclic Quaternary Carbon Stereogenic Centers

(2012) P. Andrew Evans et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Chiral 9,10-Dihydrophenanthrenes Using Pd-Catalyzed Asymmetric Intramolecular Friedel–Crafts Allylic Alkylation of Phenols

(2012) Yuta Suzuki et al.   ORGANIC LETTERS

Enantioselective Synthesis of Tetrahydroisoquinolines via Iridium-Catalyzed Intramolecular Friedel–Crafts-Type Allylic Alkylation of Phenols

(2012) Qing-Long Xu et al.   ORGANIC LETTERS

Rhodium-Catalyzed Asymmetric Coupling Reaction of Allylic Ethers with Arylboronic Acids

(2012) Hiroyoshi Kiuchi et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Regio- and Enantioselective Allylic Substitution with Water: Direct Synthesis of Chiral Allylic Alcohols

(2011) Naoya Kanbayashi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Chiral Bidentate sp2-N Ligand, Naph-diPIM: Application to CpRu-Catalyzed Asymmetric Dehydrative C-, N-, and O-Allylation

(2011) Kengo Miyata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemo- and Regioselectivity-Tunable Pd-Catalyzed Allylic Alkylation of Imines

(2011) Jian-Ping Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio- and Regioselective Iridium-Catalyzed Allylic Hydroxylation

(2011) Martin Gärtner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Neutral Atom-Economic Rhodium-Catalyzed Coupling of Terminal Alkynes with Carboxylic Acids Toward Branched Allylic Esters

(2011) Alexandre Lumbroso et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Branched Allylic Esters via Rhodium-Catalyzed Coupling of Allenes with Carboxylic Acids

(2011) Philipp Koschker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Enantio- and Diastereoselective Molybdenum-Catalyzed Asymmetric Allylic Alkylation of Cyanoesters

(2011) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exercising Regiocontrol in Palladium-Catalyzed Asymmetric Prenylations and Geranylation: Unifying Strategy toward Flustramines A and B

(2011) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoconvergent Synthesis of Chiral Allylboronates from anE/ZMixture of Allylic Aryl Ethers Using a 6-NHC−Cu(I) Catalyst

(2011) Jin Kyoon Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxazolidine Synthesis by Complementary Stereospecific and Stereoconvergent Methods

(2011) Michael B. Shaghafi et al.   ORGANIC LETTERS

Atom economic macrolactonization and lactonization viaredox-neutral rhodium-catalyzed coupling of terminal alkynes with carboxylic acids

(2011) Alexandre Lumbroso et al.   Chemical Science

Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution

(2010) John F. Hartwig et al.   ACCOUNTS OF CHEMICAL RESEARCH

(Cyclopentadienyl)ruthenium-Catalyzed Regio- and Enantioselective Decarboxylative Allylic Etherification of Allyl Aryl and Alkyl Carbonates

(2010) Martina Austeri et al.   ADVANCED SYNTHESIS & CATALYSIS

Ruthenium(IV) Complexes Featuring P,O-Chelating Ligands: Regioselective Substitution Directly from Allylic Alcohols

(2010) Basker Sundararaju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

InIII-Catalysed Tandem C-C and C-O Bond Formation between Phenols and Allylic Acetates

(2010) Vito Vece et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalyzed Kinetic Asymmetric Transformations of Racemic Allylic Benzoates

(2010) Levi M. Stanley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Allylic Esters via Asymmetric Allylic Substitution with Metal Carboxylates Using Planar-Chiral Cyclopentadienyl Ruthenium Catalysts

(2010) Naoya Kanbayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Chiral Allylic Esters

(2010) Jeffrey S. Cannon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Magnesium Coordination-DirectedN-Selective Stereospecific Alkylation of 2-Pyridones, Carbamates, and Amides Using α-Halocarboxylic Acids

(2010) Yuan-Qing Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Enantioselective Allyl−Allyl Cross-Coupling

(2010) Ping Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pyridones as glucokinase activators: Identification of a unique metabolic liability of the 4-sulfonyl-2-pyridone heterocycle

(2009) Jeffrey A. Pfefferkorn et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Catalytic Double Stereoinduction in Asymmetric Allylic Alkylation of Oxindoles

(2009) Barry M. Trost et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unlocking Ylide Reactivity in the Metal-Catalyzed Allylic Substitution Reaction: Stereospecific Construction of Primary Allylic Amines with Aza-Ylides

(2009) P. Andrew Evans et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Enantioselective Allylic Amination Reaction Using a Commercially Available Chiral Rhodium Catalyst: Resolution of Racemic Allylic Carbonates

(2009) Derek C. Vrieze et al.   ORGANIC LETTERS

Synthesis of Chromans via [3 + 3] Cyclocoupling of Phenols with Allylic Alcohols Using a Mo/o-Chloranil Catalyst System

(2009) Yoshihiko Yamamoto et al.   ORGANIC LETTERS

Enantioselective Palladium(II)-Catalyzed Formal [3,3]-Sigmatropic Rearrangement of 2-Allyloxypyridines and Related Heterocycles†

(2009) Alessandro Rodrigues et al.   ORGANIC LETTERS

Regio- and Enantioselective O-Allylation of Phenol and Alcohol Catalyzed by a Planar-Chiral Cyclopentadienyl Ruthenium Complex

(2008) Kiyotaka Onitsuka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective and Regioselective Ruthenium‐Catalyzed Decarboxylative Etherification of Allyl Aryl Carbonates

(2008) Martina Austeri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold-catalysed allylic alkylation of aromatic and heteroaromatic compounds with allylic alcohols

(2008) Weidong Rao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION