Combining NHC-Cu and Brønsted Base Catalysis: Enantioselective Allylic Substitution/Conjugate Additions with Alkynylaluminum Reagents and Stereospecific Isomerization of the Products to Trisubstituted Allenes

Catalytic Asymmetric Synthesis of Cyclic Ethers Containing an α-Tetrasubstituted Stereocenter

(2013) Nick Cox et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed γ-Selective and Stereospecific Direct Allylic Alkylation of Terminal Alkynes: Synthesis of Skipped Enynes

(2013) Yusuke Makida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of 5,7-Bicyclic Ring Systems from Axially Chiral Allenes Using a Rh(I)-Catalyzed Cyclocarbonylation Reaction

(2013) Francois Grillet et al.   JOURNAL OF ORGANIC CHEMISTRY

Simple organic molecules as catalysts for enantioselective synthesis of amines and alcohols

(2013) Daniel L. Silverio et al.   NATURE

Unexpected Diels–Alder/Carbonyl-ene Cascade toward the Biomimetic Synthesis of Chloropupukeananin

(2013) Takahiro Suzuki et al.   ORGANIC LETTERS

Enantioselective Synthesis and Cross-Coupling of Tertiary Propargylic Boronic Esters Using Lithiation-Borylation of Propargylic Carbamates

(2012) Benjamin M. Partridge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses

(2012) Shichao Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Brønsted acid catalyzed enantioselective allenylation of aldehydes

(2012) Leleti Rajender Reddy   CHEMICAL COMMUNICATIONS

Propargyl Claisen rearrangement: allene synthesis and beyond

(2012) David Tejedor et al.   CHEMICAL SOCIETY REVIEWS

Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC–Cu-Catalyzed Allylic Substitution

(2012) Byunghyuck Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Conjugated Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Aryl- or Alkenylboronates

(2012) Mingyu Yang et al.   ORGANIC LETTERS

Copper-Catalyzed Enantioselective Synthesis of Axially Chiral Allenes

(2012) Hailing Li et al.   ORGANIC LETTERS

Enantioselective Synthesis of Alkyne-Substituted Quaternary Carbon Stereogenic Centers through NHC−Cu-Catalyzed Allylic Substitution Reactions with (i-Bu)2(Alkynyl)aluminum Reagents

(2011) Jennifer A. Dabrowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

General Approach to Allenes through Copper-Catalyzed γ-Selective and Stereospecific Coupling between Propargylic Phosphates and Alkylboranes

(2011) Hirohisa Ohmiya et al.   ORGANIC LETTERS

Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes

(2010) Takahiro Nishimura et al.   CHEMICAL COMMUNICATIONS

Allenes as Three-Carbon Units in Catalytic Cycloadditions: New Opportunities with Transition-Metal Catalysts

(2010) Fernando López et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct Catalytic Asymmetric Conjugate Addition of Terminal Alkynes to α,β-Unsaturated Thioamides

(2010) Ryo Yazaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Enantioenriched Allenes from 1,1-Cyclopropanediesters

(2010) Pascal Cérat et al.   ORGANIC LETTERS

Enantioselective synthesis of butadien-2-ylcarbinols via (silylmethyl)allenic alcohols from chromium-catalyzed additions to aldehydes utilizing chiral carbazole ligands

(2010) María Durán-Galván et al.   TETRAHEDRON

Asymmetric Synthesis of β-Alkynyl Aldehydes by Rhodium-Catalyzed Conjugate Alkynylation

(2009) Takahiro Nishimura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

First Regio- and Enantioselective Chromium-Catalyzed Homoallenylation of Aldehydes

(2009) Vincent Coeffard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Reactivity of Enantiomerically Enriched Thiiranium Ions

(2009) Scott E. Denmark et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Rhodium-Catalyzed Conjugate Alkynylation of 5-Benzylidene Meldrum’s Acids with TMS-acetylene

(2009) Eric Fillion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Chiral Allenoates by Guanidine-Catalyzed Isomerization of 3-Alkynoates

(2009) Hongjun Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Asymmetric Conjugate Alkynylation of Enones with Alkynylsilanols

(2009) Takahiro Nishimura et al.   ORGANIC LETTERS

Ni(II)-Catalyzed Enantioselective Conjugate Addition of Acetylenes to α,β-Enones

(2009) Oleg V. Larionov et al.   ORGANIC LETTERS

Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions

(2008) A. Alexakis et al.   CHEMICAL REVIEWS

Organozinc Reagents in DMSO Solvent: Remarkable Promotion of SN2′ Reaction for Allene Synthesis

(2008) Koji Kobayashi et al.   ORGANIC LETTERS

Highly Site- and Enantioselective Cu-Catalyzed Allylic Alkylation Reactions with Easily Accessible Vinylaluminum Reagents

(2007) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY