Nitromethane as a nitrogen donor in Schmidt-type formation of amides and nitriles

Direct Catalytic Methanol-to-Ethanol Photo-conversion via Methyl Carbene

(2019) Mingxin Liu et al.   Chem

Activation of nitriles by silver(I) N-heterocyclic carbenes: An efficient on-water synthesis of primary amides

(2019) Narasimha Swamy Thirukovela et al.   TETRAHEDRON

Acetonitrile Activation: An Effective Two-Carbon Unit for Cyclization

(2019) Qixue Qin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Deoxygenation and Reductive Disilylation of Nitroarenes by Organosilicon Reducing Reagents

(2018) Argha Bhattacharjee et al.   CHEMISTRY-A EUROPEAN JOURNAL

4-(Phenoxy) and 4-(benzyloxy)benzamides as potent and selective inhibitors of mono-ADP-ribosyltransferase PARP10/ARTD10

(2018) Sudarshan Murthy et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Synthesis, Characterization, and Antimicrobial Screening of 4″-methyl-2,2″-diaryl-4,2′:4′,5″-terthiazole Derivatives

(2018) Jitendra Nalawade et al.   JOURNAL OF HETEROCYCLIC CHEMISTRY

Design and Synthesis of Novel Deuterated Ligands Functionally Selective for the γ-Aminobutyric Acid Type A Receptor (GABAAR) α6 Subtype with Improved Metabolic Stability and Enhanced Bioavailability

(2018) Daniel E. Knutson et al.   JOURNAL OF MEDICINAL CHEMISTRY

Mechanistic Studies of Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides with Carbon Monoxide and Ammonia

(2018) Justin Y. Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Scope and Mechanism of a True Organocatalytic Beckmann Rearrangement with a Boronic Acid/Perfluoropinacol System under Ambient Conditions

(2018) Xiaobin Mo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A visible-light photocatalytic thiolation of aryl, heteroaryl and vinyl iodides

(2018) M. L. Czyz et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Secondary Amides from Thiocarbamates

(2018) Pieter Mampuys et al.   ORGANIC LETTERS

Direct synthesis of N -arylamides via the coupling of aryl diazonium tetrafluoroborates and nitriles under transition-metal-free conditions

(2018) Biquan Xiong et al.   TETRAHEDRON LETTERS

Synthesis of Nitriles from Primary Amides or Aldoximes under Conditions of a Catalytic Swern Oxidation

(2018) Rui Ding et al.   JOURNAL OF ORGANIC CHEMISTRY

Cooperative asymmetric reactions combining photocatalysis and enzymatic catalysis

(2018) Zachary C. Litman et al.   NATURE

Expanding the medicinal chemistry synthetic toolbox

(2018) Jonas Boström et al.   NATURE REVIEWS DRUG DISCOVERY

Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis

(2018) Anhua Hu et al.   SCIENCE

Copper-Catalyzed Site-Selective Oxidative C−C Bond Cleavage of Simple Ketones for the Synthesis of Anilides and Paracetamol

(2018) Nagaraju Vodnala et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct and Catalytic Amide Synthesis from Ketones via Transoximation and Beckmann Rearrangement under Mild Conditions

(2018) Kengo Hyodo et al.   JOURNAL OF ORGANIC CHEMISTRY

From alkylarenes to anilines via site-directed carbon–carbon amination

(2018) Jianzhong Liu et al.   Nature Chemistry

In Situ Conformational Fixation of the Amide Bond Enables General Access to Medium-Sized Lactams via Ring-Closing Metathesis

(2018) Nina Hegmann et al.   ORGANIC LETTERS

Efficient access to unprotected primary amines by iron-catalyzed aminochlorination of alkenes

(2018) Luca Legnani et al.   SCIENCE

Ketyl radical reactivity via atom transfer catalysis

(2018) Lu Wang et al.   SCIENCE

Site-Selective C–H Functionalization of (Hetero)Arenes via Transient, Non-symmetric Iodanes

(2018) Stacy C. Fosu et al.   Chem

A Convenient Palladium-Catalyzed Aminocarbonylation of Aryl Iodides to Primary Amides under Gas-Free Conditions

(2017) Xinxin Qi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Thermal Activation of Molecular Oxygen Enabled Direct α-CH2-Oxygenation of Free Amines

(2017) Santanu Ghosh et al.   JOURNAL OF ORGANIC CHEMISTRY

Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide

(2017) Francisco Juliá-Hernández et al.   NATURE

1,3-Dibromo-5,5-dimethylhydantoin mediated oxidative amidation of terminal alkenes in water

(2017) Chunhua Ma et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Structure–reactivity correlations of the abnormal Beckmann reaction of dihydrolevoglucosenone oxime

(2017) Amani Alhifthi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Brønsted Acid Catalyzed Nitrile Synthesis from Aldehydes Using Oximes via Transoximation at Ambient Temperature

(2017) Kengo Hyodo et al.   ORGANIC LETTERS

Potassium Iodide/tert-Butyl Hydroperoxide-Mediated Oxidative Annulation for the Selective Synthesis ofN-Substituted 1,2,3-Benzotriazine-4(3H)-ones Using Nitromethane as the Nitrogen Synthon

(2016) Yizhe Yan et al.   ADVANCED SYNTHESIS & CATALYSIS

One for Many: A Universal Reagent for Acylation Processes

(2016) Hyun Kyung Moon et al.   ADVANCED SYNTHESIS & CATALYSIS

Beckmann Fragmentation and Successive Carbon–Carbon Bond Formation Using Grignard Reagents via Phosphonium Salt Intermediates

(2016) Hiromichi Fujioka et al.   CHEMICAL & PHARMACEUTICAL BULLETIN

Fe-Catalyzed Amination of (Hetero)Arenes with a Redox-Active Aminating Reagent under Mild Conditions

(2016) Jianzhong Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Clean synthesis of primary to tertiary carboxamides by CsOH-catalyzed aminolysis of nitriles in water

(2016) Yang Li et al.   GREEN CHEMISTRY

Remodeling and Enhancing Schmidt Reaction Pathways in Hexafluoroisopropanol

(2016) Hashim F. Motiwala et al.   JOURNAL OF ORGANIC CHEMISTRY

Iron(III)-catalysed carbonyl–olefin metathesis

(2016) Jacob R. Ludwig et al.   NATURE

Aldehydes as alkyl carbanion equivalents for additions to carbonyl compounds

(2016) Haining Wang et al.   Nature Chemistry

Aryl Nitriles from Alkynes Using tert-Butyl Nitrite: Metal-Free Approach to C≡C Bond Cleavage

(2016) Uttam Dutta et al.   ORGANIC LETTERS

Direct Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I2–Aqueous NH3

(2016) Shohei Shimokawa et al.   ORGANIC LETTERS

Organoselenium-Catalyzed Synthesis of Oxygen- and Nitrogen-Containing Heterocycles

(2016) Ruizhi Guo et al.   ORGANIC LETTERS

Amine Activation: Synthesis of N-(Hetero)arylamides from Isothioureas and Carboxylic Acids

(2016) Yan-Ping Zhu et al.   ORGANIC LETTERS

Dirhodium-catalyzed C-H arene amination using hydroxylamines

(2016) M. P. Paudyal et al.   SCIENCE

A general catalytic β-C–H carbonylation of aliphatic amines to β-lactams

(2016) Darren Willcox et al.   SCIENCE

Oxidative Coupling between Methylarenes and Ammonia: A Direct Approach to Aromatic Primary Amides

(2015) Zhenguang Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic synthesis of amides via aldoximes rearrangement

(2015) Pascale Crochet et al.   CHEMICAL COMMUNICATIONS

Alcohols as alkylating agents in heteroarene C–H functionalization

(2015) Jian Jin et al.   NATURE

Efficient and Practical Oxidative Bromination and Iodination of Arenes and Heteroarenes with DMSO and Hydrogen Halide: A Mild Protocol for Late-Stage Functionalization

(2015) Song Song et al.   ORGANIC LETTERS

Imidazolium salt-supported Mukaiyama reagent: an efficient condensation reagent for amide bond formation

(2015) Khima Pandey et al.   RSC Advances

Direct Approaches to Nitriles via Highly Efficient Nitrogenation Strategy through C–H or C–C Bond Cleavage

(2014) Teng Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Rhodium-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Dibenzosiloles by Enantioselective [2+2+2] Cycloaddition

(2014) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Design and Synthesis of New Benzimidazole–Carbazole Conjugates for the Stabilization of Human Telomeric DNA, Telomerase Inhibition, and Their Selective Action on Cancer Cells

(2014) Basudeb Maji et al.   JOURNAL OF MEDICINAL CHEMISTRY

Transition metal-free synthesis of primary amides from aldehydes and hydroxylamine hydrochloride

(2014) Wei Wang et al.   TETRAHEDRON LETTERS

A highly efficient, ligand-free and recyclable SBA-15 supported Cu2O catalyzed cyanation of aryl iodides with potassium hexacyanoferrate(ii)

(2014) Wenzhu Yin et al.   RSC Advances

Silver-Catalyzed Nitrogenation of Alkynes: A Direct Approach to Nitriles through CC Bond Cleavage

(2013) Tao Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective C sp 2CspBond Cleavage: The Nitrogenation of Alkynes to Amides

(2013) Chong Qin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemistry of Bridged Lactams and Related Heterocycles

(2013) Michal Szostak et al.   CHEMICAL REVIEWS

Nitro-Mannich Reaction

(2013) Adam Noble et al.   CHEMICAL REVIEWS

Oxidative para-Triflation of Acetanilides

(2013) Amélie Pialat et al.   ORGANIC LETTERS

New Approach to Oximes through Reduction of Nitro Compounds Enabled by Visible Light Photoredox Catalysis

(2013) Shunyou Cai et al.   ORGANIC LETTERS

Sequential one-pot synthesis of benzoxazoles from aryl bromides: successive palladium- and copper-catalyzed reactions

(2013) Xiao-Feng Wu et al.   TETRAHEDRON LETTERS

Palladium-catalyzed aminocarbonylation of aryl iodides using aqueous ammonia

(2013) Tongyu Xu et al.   TETRAHEDRON LETTERS

Synthesis and Evaluation of a Photochromic Surfactant for Organic Reactions in Aqueous Media

(2012) Nicolas Drillaud et al.   JOURNAL OF ORGANIC CHEMISTRY

A non-metal catalysed oxidation of primary azides to nitriles at ambient temperature

(2012) Manjunath Lamani et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Practical one-pot transformation of electron-rich aromatics into aromatic nitriles with molecular iodine and aq NH3 using Vilsmeier–Haack reaction

(2012) Sousuke Ushijima et al.   TETRAHEDRON

Rethinking amide bond synthesis

(2011) Vijaya R. Pattabiraman et al.   NATURE

Iron-Facilitated Direct Oxidative C−H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles

(2010) Chong Qin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Give and Take of Alcohol Activation

(2010) A. J. A. Watson et al.   SCIENCE

One-pot conversion of aromatic bromides and aromatics into aromatic nitriles via aryllithiums and their DMF adduct

(2010) Sousuke Ushijima et al.   TETRAHEDRON

Cost efficient synthesis of amides from oximes with indium or zinc catalysts

(2010) C. Liana Allen et al.   TETRAHEDRON LETTERS

Significant Self-Acceleration Effects of Nitrile Additives in the Rhodium-Catalyzed Conversion of Aldoximes to Amides: A New Mechanistic Aspect

(2009) Min Kim et al.   ADVANCED SYNTHESIS & CATALYSIS

Mitsunobu and Related Reactions: Advances and Applications

(2009) K. C. Kumara Swamy et al.   CHEMICAL REVIEWS

Thio FCMA Intermediates as Strong Acyl Donors: A General Solution to the Formation of Complex Amide Bonds

(2009) Yu Rao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY