期刊
ORGANIC LETTERS
卷 19, 期 11, 页码 3005-3008出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01263
关键词
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资金
- Kaneka Award in Synthetic Organic Chemistry, Japan, from the MEXT as a Supported Program for the Strategic Research Foundation at Private Universities [S1311040]
- JSPS KAKENHI Grand [JP26107012]
The Bronsted acid-catalyzed synthesis of nitriles is described via transoximation under mild conditions using an O-protected oxime as a more stable equivalent of explosive O-protected hydroxylamines. The nitrile was generated via an O-protected aldoxime produced from the aldehyde and an O-protected oxime through transoximation. The reaction could be performed on a 1 g scale.
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