Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis

A General Strategy for Aliphatic C–H Functionalization Enabled by Organic Photoredox Catalysis

(2018) Kaila A. Margrey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

δ-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer

(2018) Anhua Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective sp3 C–H alkylation via polarity-match-based cross-coupling

(2017) Chip Le et al.   NATURE

Photocatalytic C−C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex

(2016) Jing-Jing Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Applications of Continuous-Flow Photochemistry in Organic Synthesis, Material Science, and Water Treatment

(2016) Dario Cambié et al.   CHEMICAL REVIEWS

Fine Control over Site and Substrate Selectivity in Hydrogen Atom Transfer-Based Functionalization of Aliphatic C–H Bonds

(2016) Michela Salamone et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible-Light-Promoted Activation of Unactivated C(sp3)–H Bonds and Their Selective Trifluoromethylthiolation

(2016) Satobhisha Mukherjee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective Aliphatic C–H Chlorination Using N-Chloroamides Enables a Synthesis of Chlorolissoclimide

(2016) Ryan K. Quinn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Hexachlorocerate(III) Anion: A Potent, Benchtop Stable, and Readily Available Ultraviolet A Photosensitizer for Aryl Chlorides

(2016) Haolin Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct C(sp3)–H Cross Coupling Enabled by Catalytic Generation of Chlorine Radicals

(2016) Benjamin J. Shields et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Amide-directed photoredox-catalysed C–C bond formation at unactivated sp3 C–H bonds

(2016) John C. K. Chu et al.   NATURE

Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer

(2016) Gilbert J. Choi et al.   NATURE

Catalytic borylation of methane

(2016) K. T. Smith et al.   SCIENCE

Catalyst-controlled selectivity in the C-H borylation of methane and ethane

(2016) A. K. Cook et al.   SCIENCE

Tuning Reactivity and Selectivity in Hydrogen Atom Transfer from Aliphatic C–H Bonds to Alkoxyl Radicals: Role of Structural and Medium Effects

(2015) Michela Salamone et al.   ACCOUNTS OF CHEMICAL RESEARCH

Trap-Free Halogen Photoelimination from Mononuclear Ni(III) Complexes

(2015) Seung Jun Hwang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Luminescent Ce(III) Complexes as Stoichiometric and Catalytic Photoreductants for Halogen Atom Abstraction Reactions

(2015) Haolin Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The direct arylation of allylic sp3 C–H bonds via organic and photoredox catalysis

(2015) James D. Cuthbertson et al.   NATURE

O-H hydrogen bonding promotes H-atom transfer from   C-H bonds for C-alkylation of alcohols

(2015) J. L. Jeffrey et al.   SCIENCE

Site-Selective Aliphatic C–H Bromination Using N-Bromoamides and Visible Light

(2014) Valerie A. Schmidt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Monooxidation of Light Alkanes Using Chloride and Iodate

(2014) George C. Fortman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-Group Compounds Selectively Oxidize Mixtures of Methane, Ethane, and Propane to Alcohol Esters

(2014) B. G. Hashiguchi et al.   SCIENCE

Thermal Hydrogen-Atom Transfer from Methane: The Role of Radicals and Spin States in Oxo-Cluster Chemistry

(2012) Nicolas Dietl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed C-C Bond Formation Between Methane and Ethyl Diazoacetate in Supercritical CO2

(2011) A. Caballero et al.   SCIENCE