Ir/Phase‐Transfer‐Catalysis Cooperatively Catalyzed Asymmetric Cascade Allylation/2‐aza‐Cope Rearrangement: An Efficient Route to Homoallylic Amines from Aldimine Esters †

Transition Metal–Catalyzed Allylic C(sp 3 )–H Functionalization via η 3 ‐Allylmetal Intermediate

(2019) Ronghua Wang et al.   CHINESE JOURNAL OF CHEMISTRY

Catalytic Asymmetric Synthesis of α-Trifluoromethyl Homoallylic Amines via Umpolung Allylation/2-Aza-Cope Rearrangement: Stereoselectivity and Mechanistic Insight

(2019) Li-Min Shi et al.   ORGANIC LETTERS

Synergistic catalysis for cascade allylation and 2-aza-cope rearrangement of azomethine ylides

(2019) Liang Wei et al.   Nature Communications

Catalytic Asymmetric Umpolung Allylation/2-Aza-Cope Rearrangement for the Construction of α-Tetrasubstituted α-Trifluoromethyl Homoallylic Amines

(2019) Chong Shen et al.   ORGANIC LETTERS

Catalytic Asymmetric Synthesis of α-Tetrasubstituted α-Trifluoromethyl Homoallylic Amines by Ir-Catalyzed Umpolung Allylation of Imines

(2019) Yingwei Wang et al.   ORGANIC LETTERS

Synthesis of β3-Amino Esters by Iridium-Catalyzed Asymmetric Allylic Alkylation Reaction

(2019) Chao-Guo Cao et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Application of Cope rearrangement in synthesis

(2019) Gangliang Huang et al.   SYNTHETIC COMMUNICATIONS

Stereodivergent Synthesis of α,α-Disubstituted α-Amino Acids via Synergistic Cu/Ir Catalysis

(2018) Liang Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Fluorinative Dearomatization of Tryptophol Derivatives by Chiral Anion Phase-Transfer Catalysis

(2018) Xiao-Wei Liang et al.   CHINESE JOURNAL OF CHEMISTRY

2-Azaallyl Anions, 2-Azaallyl Cations, 2-Azaallyl Radicals, and Azomethine Ylides

(2018) Shaojian Tang et al.   CHEMICAL REVIEWS

Iridium-Catalyzed Asymmetric Allylic Substitution Reactions

(2018) Qiang Cheng et al.   CHEMICAL REVIEWS

Catalytic Asymmetric Umpolung Allylation of Imines

(2016) Jie Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iridium-Catalyzed Diastereo-, Enantio-, and Regioselective Allylic Alkylation with Prochiral Enolates

(2016) J. Caleb Hethcox et al.   ACS Catalysis

Asymmetric Synthesis of β-Amino Amides by Catalytic Enantioconvergent 2-Aza-Cope Rearrangement

(2015) C. Guy Goodman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(i)/TF-BiphamPhos-catalyzed asymmetric Michael addition of cyclic ketimino esters to alkylidene malonates

(2015) Zhi-Yong Xue et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective cooperative catalysis

(2015) Suleman M. Inamdar et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Organocatalysis Combined with Metal Catalysis: Concept, Proof of Concept, and Beyond

(2014) Dian-Feng Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Catalytic Asymmetric 1,3-Dipolar [3 + 6] Cycloaddition of Azomethine Ylides with 2-Acyl Cycloheptatrienes: Efficient Construction of Bridged Heterocycles Bearing Piperidine Moiety

(2014) Qing-Hua Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(I)-Catalyzed Regio- and Stereoselective [6 + 3] Cycloaddition of Azomethine Ylides with Tropone: An Efficient Asymmetric Access to Bridged Azabicyclo[4.3.1]decadienes

(2014) Huai-Long Teng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fulvenes as Effective Dipolarophiles in Copper(I)-Catalyzed [6+3] Cycloaddition of Azomethine Ylides: Asymmetric Construction of Piperidine Derivatives

(2013) Zhao-Lin He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric 1,3-Dipolar Cycloaddition of Two Different Ylides: Facile Access to Chiral 1,2,4-Triazinane Frameworks

(2013) Min-Chao Tong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereoselective Allylation of Carbonyl Compounds and Imines: Application to the Synthesis of Natural Products

(2013) Miguel Yus et al.   CHEMICAL REVIEWS

Addition of Organometallic Reagents to ChiralN-Methoxylactams: Enantioselective Syntheses of Pyrrolidines and Piperidines

(2013) Mascha Jäkel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Combining transition metal catalysis and organocatalysis – an update

(2012) Zhenting Du et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Asymmetric Construction of Spiro(γ-butyrolactam-γ-butyrolactone) Moieties through Sequential Reactions of Cyclic Imino Esters with Morita-Baylis-Hillman Bromides

(2012) Huai-Long Teng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium-Catalyzed Allylic Alkylation Reaction with N-Aryl Phosphoramidite Ligands: Scope and Mechanistic Studies

(2012) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergistic catalysis: A powerful synthetic strategy for new reaction development

(2012) Anna E. Allen et al.   Chemical Science

Catalytic Enantioselective Allylation of Carbonyl Compounds and Imines

(2011) Miguel Yus et al.   CHEMICAL REVIEWS

Catalytic Enantioselective Formation of C−C Bonds by Addition to Imines and Hydrazones: A Ten-Year Update

(2011) Shu̅ Kobayashi et al.   CHEMICAL REVIEWS

A Facile Cu(I)/TF-BiphamPhos-Catalyzed Asymmetric Approach to Unnatural α-Amino Acid Derivatives Containinggem-Bisphosphonates

(2011) Zhi-Yong Xue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Catalytic Asymmetric Aminoallylation of Aldehydes: Synergism of Chiral and Nonchiral Brønsted Acids

(2011) Hong Ren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Facile Cu(I)/BINAP-Catalyzed Asymmetric Approach to Functionalized Pyroglutamate Derivatives Bearing a Unique Quaternary Stereogenic Center

(2011) Huai-Long Teng et al.   ORGANIC LETTERS

Iridium-catalyzed allylic alkylation of monosubstituted allylic acetates with azlactone, and separation of diastereoisomers by sequential aza-Cope rearrangement

(2011) Motoi Kawatsura et al.   TETRAHEDRON

Mechanistically Driven Development of Iridium Catalysts for Asymmetric Allylic Substitution

(2010) John F. Hartwig et al.   ACCOUNTS OF CHEMICAL RESEARCH

Phosphoramidites: Privileged Ligands in Asymmetric Catalysis

(2010) Johannes F. Teichert et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Escape from Flatland: Increasing Saturation as an Approach to Improving Clinical Success

(2009) Frank Lovering et al.   JOURNAL OF MEDICINAL CHEMISTRY

Catalytic Asymmetric Aminoallylation of Aldehydes: A Catalytic Enantioselective Aza-Cope Rearrangement

(2008) Magnus Rueping et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective 1,3-Dipolar Cycloaddition of Azomethine Ylides Catalyzed by Copper(I)/TF-BiphamPhos Complexes

(2008) Chun-Jiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY