Construction of Chiral Tri- and Tetra-Arylmethanes Bearing Quaternary Carbon Centers: Copper-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Esters

Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles

(2016) Hirohisa Ohmiya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Desilylation-Activated Propargylic Transformation: Enantioselective Copper-Catalyzed [3+2] Cycloaddition of Propargylic Esters with β-Naphthol or Phenol Derivatives

(2016) Long Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper-Catalyzed Formal [4 + 2] Cycloaddition of o-Aminophenol Derivatives with Propargylic Esters for Synthesis of Optically Active 3,4-Dihydro-2H-1,4-benzoxazines

(2016) Zhen-Ting Liu et al.   ORGANIC LETTERS

Highly diastereo-/enantioselective Cu-catalyzed propargylic alkylations of propargyl acetates with cyclic enamines

(2016) Cheng Zhang et al.   RSC Advances

Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules

(2015) Yiyang Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Copper-Catalyzed Intermolecular Asymmetric Propargylic Dearomatization of Indoles

(2015) Wen Shao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Catalysis: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Enecarbamates Using Ruthenium/Phosphoramide Hybrid Catalysts

(2015) Yasushi Senda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Enantioselective 1,6-Boration ofpara-Quinone Methides and Efficient Transformation ofgem-Diarylmethine Boronates to Triarylmethanes

(2015) Yazhou Lou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Brønsted Acid Catalyzed Synthesis of Triarylmethanes-Construction of Communesin and Spiroindoline Scaffolds

(2015) Hsuan-Hung Liao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric 1,6-Conjugate Addition ofpara-Quinone Methides: Formation of All-Carbon Quaternary Stereocenters

(2015) Zhaobin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Brønsted acid-catalyzed Friedel–Crafts alkylation of electron-rich arenes with in situ-generated ortho-quinone methides: highly enantioselective synthesis of diarylindolylmethanes and triarylmethanes

(2015) Satyajit Saha et al.   CHEMICAL COMMUNICATIONS

Enantioselective Synthesis of Tunable Chiral Clickphine P,N-Ligands and Their Application in Ir-Catalyzed Asymmetric Hydrogenation

(2015) Jeroen Wassenaar et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Enantioselective Propargylic Etherification of Propargylic Esters with Alcohols

(2015) Kazunari Nakajima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Triarylmethanes by Rhodium-Catalyzed Enantioselective Arylation of Diarylmethylamines with Arylboroxines

(2015) Yinhua Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Trialkyl Methanetricarboxylate as Dialkyl Malonate Surrogate in Copper-Catalyzed Enantioselective Propargylic Substitution

(2015) Guanxin Huang et al.   ORGANIC LETTERS

Expedient Access to Unsymmetrical Diarylindolylmethanes through Palladium-Catalyzed Domino Electrophilic Cyclization–Extended Conjugate Addition Approach

(2015) Virsinha Reddy et al.   ORGANIC LETTERS

Recent Advances in Catalytic Stereocontrolled Cycloaddition with Terminal Propargylic Compounds

(2015) Xiang-Ping Hu et al.   SYNTHESIS-STUTTGART

Recent advances in copper-catalyzed propargylic substitution

(2015) De-Yang Zhang et al.   TETRAHEDRON LETTERS

Recent Advances in the Synthesis of Triarylmethanes by Transition Metal Catalysis

(2015) Masakazu Nambo et al.   ACS Catalysis

Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargylic Esters with β-Keto Acids

(2014) Fu-Lin Zhu et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Asymmetric Synthesis of 3,3′-Diaryloxindoles as Triarylmethanes with a Chiral All-Carbon Quaternary Center: Phase-Transfer-Catalyzed SNAr Reaction

(2014) Seiji Shirakawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly diastereo- and enantioselective copper-catalyzed propargylic alkylation of acyclic ketone enamines for the construction of two vicinal stereocenters

(2014) De-Yang Zhang et al.   CHEMICAL COMMUNICATIONS

Enantioselective intramolecular propargylic amination using chiral copper–pybox complexes as catalysts

(2014) Masashi Shibata et al.   CHEMICAL COMMUNICATIONS

1,2,3-Triazole in Heterocyclic Compounds, Endowed with Biological Activity, through 1,3-Dipolar Cycloadditions

(2014) Antonino Lauria et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Enantiomerically Enriched Triarylmethanes by Enantiospecific Suzuki–Miyaura Cross-Coupling Reactions

(2014) Smitha C. Matthew et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

All-Carbon Quaternary Stereogenic Centers in Acyclic Systems through the Creation of Several C–C Bonds per Chemical Step

(2014) Ilan Marek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic enantioselective synthesis of quaternary carbon stereocentres

(2014) Kyle W. Quasdorf et al.   NATURE

Enantioselective Synthesis of Triarylmethanes by Chiral Imidodiphosphoric Acids Catalyzed Friedel–Crafts Reactions

(2014) Ming-Hua Zhuo et al.   ORGANIC LETTERS

Diastereo- and Enantioselective Propargylation of Benzofuranones Catalyzed by Pybox-Copper Complex

(2014) Long Zhao et al.   ORGANIC LETTERS

Enantioselective Cu-catalyzed decarboxylative propargylic amination of propargyl carbamates

(2014) Yuan Zou et al.   TETRAHEDRON LETTERS

Copper-catalyzed enantioselective propargylic substitution of propargylic acetates with enamines

(2014) Bo Wang et al.   RSC Advances

Synthetic methodologies of achiral diarylmethanols, diaryl and triarylmethanes (TRAMs) and medicinal properties of diaryl and triarylmethanes-an overview

(2014) Sankalan Mondal et al.   RSC Advances

Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargyl β-Ketoesters with a Chiral Ketimine P,N,N-Ligand

(2013) Fu-Lin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Click Chemistry for Drug Development and Diverse Chemical–Biology Applications

(2013) Prakasam Thirumurugan et al.   CHEMICAL REVIEWS

Synthetic Strategies for the Biotinylation of Bioactive Small Molecules

(2013) Paul C. Trippier   ChemMedChem

The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis

(2013) Allen Y. Hong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ligand-enabled multiple absolute stereocontrol in metal-catalysed cycloaddition for construction of contiguous all-carbon quaternary stereocentres

(2013) Kohsuke Ohmatsu et al.   Nature Chemistry

Highly Enantioselective Copper-Catalyzed Propargylic Substitution of Propargylic Acetates with 1,3-Dicarbonyl Compounds

(2013) Fu-Zhong Han et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed Allylic Substitution Reactions: Stereoselective Construction of α- and β-Substituted Carbonyl Compounds

(2013) P. Evans et al.   SYNTHESIS-STUTTGART

Copper-catalyzed asymmetric propargylic amination of propargylic acetates with amines using BICMAP

(2013) Takashi Mino et al.   TETRAHEDRON-ASYMMETRY

Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with both Primary and Secondary Amines as Nucleophiles

(2012) Cheng Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Cooperative Catalytic Reactions Using Distinct Transition-Metal Catalysts: Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation

(2012) Masahiro Ikeda et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Propargylic Allylation of Propargylic Alcohols with α,β-Unsaturated Aldehydes

(2012) Masahiro Ikeda et al.   ORGANOMETALLICS

Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation of Propargylic Alcohols with β-Keto Phosphonates

(2012) Kazuki Motoyama et al.   ORGANOMETALLICS

Transition-Metal-Catalyzed Enantioselective Propargylic Substitution Reactions of Propargylic Alcohol Derivatives with Nucleophiles

(2012) Yoshiaki Nishibayashi   SYNTHESIS-STUTTGART

Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems

(2011) Jaya Prakash Das et al.   CHEMICAL COMMUNICATIONS

Catalytic Asymmetric Propargylation

(2011) Chang-Hua Ding et al.   CHEMICAL REVIEWS

Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions

(2011) Jimmie D. Weaver et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalysed Propargylic Substitution: Synthetic Scope Study and Application in Formal Total Syntheses of (+)-Anisomycin and (−)-Cytoxazone

(2011) Remko J. Detz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Esters with Aldehydes

(2011) Akiko Yoshida et al.   ORGANIC LETTERS

Copper-Catalyzed Enantioselective Propargylic Amination of Nonaromatic Propargylic Esters with Amines

(2011) Akiko Yoshida et al.   ORGANIC LETTERS

Cooperative Catalytic Reactions Using Organocatalysts and Transition-Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Aldehydes

(2010) Masahiro Ikeda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper−Allenylidene Complexes as Key Intermediates

(2010) Gaku Hattori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nonlinear Effects in Asymmetric Catalysis

(2009) Tummanapalli Satyanarayana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Propargylic Substitution Reactions

(2009) Yoshihiro Miyake et al.   ChemCatChem

Copper-Catalyzed Diastereo- and Enantioselective Sequential Reactions of Propargylic Acetates with (E)-2,4-Pentadienylamine

(2009) Gaku Hattori et al.   ChemCatChem

Enantioselective Synthesis of Unsymmetrical Triarylmethanes by Chiral Brønsted Acids

(2009) Feng-Lai Sun et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalyzed Propargylic Substitution

(2009) Remko J. Detz et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Copper(I) Complexes Containing Enantiopure Pybox Ligands. First Assays on Enantioselective Synthesis of Propargylamines Catalyzed by Isolated Copper(I) Complexes

(2009) María Panera et al.   INORGANIC CHEMISTRY

Enantioselective Ring-Opening Reactions of Racemic Ethynyl Epoxides via Copper−Allenylidene Intermediates: Efficient Approach to Chiral β-Amino Alcohols

(2009) Gaku Hattori et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Copper-Catalyzed Propargylic Substitution Reaction of Propargylic Acetates with Enamines

(2009) Ping Fang et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Enantioselective Intramolecular Propargylation of Thiophenes with Propargylic Alcohols

(2009) Keiichiro Kanao et al.   ORGANOMETALLICS

Enantioselective Copper-Catalyzed Propargylic Amination

(2008) Remko J. Detz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Propargylic Substitution Reactions of Propargylic Acetates with Amines

(2008) Gaku Hattori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Propargylic Substitution

(2008) Natalie Ljungdahl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper-Catalyzed Conjugate Addition and Allylic Substitution Reactions

(2008) A. Alexakis et al.   CHEMICAL REVIEWS

Copper-Catalyzed Asymmetric Allylic Alkylation

(2008) Caroline A. Falciola et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed Enantioselective Carbon−Carbon Bond Forming Reaction via Allenylidene-Ene Process: Synthetic Approach to Chiral Heterocycles Such As Chromane, Thiochromane, and 1,2,3,4-Tetrahydroquinoline Derivatives

(2008) Koji Fukamizu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

(2007) Zhan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION