Highly diastereo- and enantioselective copper-catalyzed propargylic alkylation of acyclic ketone enamines for the construction of two vicinal stereocenters

Vinyl Dihydropyrans and Dihydrooxazines: Cyclizations of Catalytic Ruthenium Carbenes Derived from Alkynals and Alkynones

(2014) Fermín Cambeiro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective intramolecular propargylic amination using chiral copper–pybox complexes as catalysts

(2014) Masashi Shibata et al.   CHEMICAL COMMUNICATIONS

Stereodivergent α-Allylation of Linear Aldehydes with Dual Iridium and Amine Catalysis

(2014) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Cu-catalyzed decarboxylative propargylic amination of propargyl carbamates

(2014) Yuan Zou et al.   TETRAHEDRON LETTERS

Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargyl β-Ketoesters with a Chiral Ketimine P,N,N-Ligand

(2013) Fu-Lin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters via Ir-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation and Applications in Sequential Pd Catalysis

(2013) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Control of Diastereoselectivity for Iridium-Catalyzed Allylation of a Prochiral Nucleophile with a Phosphate Counterion

(2013) Wenyong Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio-, Diastereo-, and Regioselective Iridium-Catalyzed Asymmetric Allylic Alkylation of Acyclic β-Ketoesters

(2013) Wen-Bo Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Copper-Catalyzed Propargylic Substitution of Propargylic Acetates with 1,3-Dicarbonyl Compounds

(2013) Fu-Zhong Han et al.   ORGANIC LETTERS

Enantio- and Diastereodivergent Dual Catalysis:  -Allylation of Branched Aldehydes

(2013) S. Krautwald et al.   SCIENCE

Copper-catalyzed asymmetric propargylic amination of propargylic acetates with amines using BICMAP

(2013) Takashi Mino et al.   TETRAHEDRON-ASYMMETRY

Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with both Primary and Secondary Amines as Nucleophiles

(2012) Cheng Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Cooperative Catalytic Reactions Using Distinct Transition-Metal Catalysts: Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation

(2012) Masahiro Ikeda et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Diastereo- and Enantioselective Cu-Catalyzed [3 + 3] Cycloaddition of Propargyl Esters with Cyclic Enamines toward Chiral Bicyclo[n.3.1] Frameworks

(2012) Cheng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative Catalytic Reactions Using Organocatalysts and Transition Metal Catalysts: Propargylic Allylation of Propargylic Alcohols with α,β-Unsaturated Aldehydes

(2012) Masahiro Ikeda et al.   ORGANOMETALLICS

Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation of Propargylic Alcohols with β-Keto Phosphonates

(2012) Kazuki Motoyama et al.   ORGANOMETALLICS

Transition-Metal-Catalyzed Enantioselective Propargylic Substitution Reactions of Propargylic Alcohol Derivatives with Nucleophiles

(2012) Yoshiaki Nishibayashi   SYNTHESIS-STUTTGART

Enantioselective rhodium-catalyzed allylic alkylation of acyclic α-alkoxy substituted ketones using a chiral monodentate phosphite ligand

(2012) P. Andrew Evans et al.   Chemical Science

Catalytic Asymmetric Propargylation

(2011) Chang-Hua Ding et al.   CHEMICAL REVIEWS

Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions

(2011) Jimmie D. Weaver et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalysed Propargylic Substitution: Synthetic Scope Study and Application in Formal Total Syntheses of (+)-Anisomycin and (−)-Cytoxazone

(2011) Remko J. Detz et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Enantioselective Propargylic Amination of Nonaromatic Propargylic Esters with Amines

(2011) Akiko Yoshida et al.   ORGANIC LETTERS

Cooperative Catalytic Reactions Using Organocatalysts and Transition-Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Aldehydes

(2010) Masahiro Ikeda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversal of Diastereoselectivity in Reactions of the Trifluoroacetaldehyde Ethyl Hemiacetal with Enamines and Imines: Metal-Free, Complementaryanti- andsyn-Selective Synthesis of 4,4,4-Trifluoro-1-aryl-3-hydroxy-2-methyl-1-butanones

(2010) Kazumasa Funabiki et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates

(2010) Jian-Ping Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper−Allenylidene Complexes as Key Intermediates

(2010) Gaku Hattori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient palladium-catalyzed asymmetric allylic alkylation of ketones and aldehydes

(2010) Xiaohu Zhao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ruthenium-Catalyzed Enantioselective [3+3] Cycloaddition of Propargylic Alcohols with 2-Naphthols

(2010) Keiichiro Kanao et al.   ORGANOMETALLICS

Intramolecular Edge-to-Face Aromatic π−π Interaction in Optically Active Ruthenium−Allenylidene Complexes for Enantioselective Propargylic Substitution Reactions

(2010) Keiichiro Kanao et al.   ORGANOMETALLICS

Copper-Catalyzed Diastereo- and Enantioselective Sequential Reactions of Propargylic Acetates with (E)-2,4-Pentadienylamine

(2009) Gaku Hattori et al.   ChemCatChem

Enantioselective Ring-Opening Reactions of Racemic Ethynyl Epoxides via Copper−Allenylidene Intermediates: Efficient Approach to Chiral β-Amino Alcohols

(2009) Gaku Hattori et al.   JOURNAL OF ORGANIC CHEMISTRY

Highly Diastereo- and Enantioselective Pd-Catalyzed Cyclopropanation of Acyclic Amides with Substituted Allyl Carbonates

(2009) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Copper-Catalyzed Propargylic Substitution Reaction of Propargylic Acetates with Enamines

(2009) Ping Fang et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Enantioselective Intramolecular Propargylation of Thiophenes with Propargylic Alcohols

(2009) Keiichiro Kanao et al.   ORGANOMETALLICS

Enantioselective Copper-Catalyzed Propargylic Amination

(2008) Remko J. Detz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Propargylic Substitution Reactions of Propargylic Acetates with Amines

(2008) Gaku Hattori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Asymmetric Cross-Couplings of Racemic Propargylic Halides with Arylzinc Reagents

(2008) Sean W. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Enantioselective Carbon−Carbon Bond Forming Reaction via Allenylidene-Ene Process: Synthetic Approach to Chiral Heterocycles Such As Chromane, Thiochromane, and 1,2,3,4-Tetrahydroquinoline Derivatives

(2008) Koji Fukamizu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY