Cooperative Catalysis: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Enecarbamates Using Ruthenium/Phosphoramide Hybrid Catalysts

Asymmetric Organocatalysis Combined with Metal Catalysis: Concept, Proof of Concept, and Beyond

(2014) Dian-Feng Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Organocatalytic Asymmetric Hydrolysis of Epoxides

(2014) Mattia Riccardo Monaco et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Highly Functionalized Dihydrofurans through Copper-Catalyzed Asymmetric Formal [3+2] Cycloaddition of β-Ketoesters with Propargylic Esters

(2014) Fu-Lin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synergistic–cooperative combination of enamine catalysis with transition metal catalysis

(2014) Yongming Deng et al.   CHEMICAL COMMUNICATIONS

Highly diastereo- and enantioselective copper-catalyzed propargylic alkylation of acyclic ketone enamines for the construction of two vicinal stereocenters

(2014) De-Yang Zhang et al.   CHEMICAL COMMUNICATIONS

Enantioselective intramolecular propargylic amination using chiral copper–pybox complexes as catalysts

(2014) Masashi Shibata et al.   CHEMICAL COMMUNICATIONS

Complete Field Guide to Asymmetric BINOL-Phosphate Derived Brønsted Acid and Metal Catalysis: History and Classification by Mode of Activation; Brønsted Acidity, Hydrogen Bonding, Ion Pairing, and Metal Phosphates

(2014) Dixit Parmar et al.   CHEMICAL REVIEWS

Beyond Classical Reactivity Patterns: Hydroformylation of Vinyl and Allyl Arenes to Valuable β- and γ-Aldehyde Intermediates Using Supramolecular Catalysis

(2014) Paweł Dydio et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent α-Allylation of Linear Aldehydes with Dual Iridium and Amine Catalysis

(2014) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric α-Photoalkylation of β-Ketocarbonyls by Primary Amine Catalysis: Facile Access to Acyclic All-Carbon Quaternary Stereocenters

(2014) Yunbo Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A cooperative N-heterocyclic carbene/palladium catalysis system

(2014) Kun Liu et al.   Chemical Science

Enantioselective Copper-Catalyzed Decarboxylative Propargylic Alkylation of Propargyl β-Ketoesters with a Chiral Ketimine P,N,N-Ligand

(2013) Fu-Lin Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Supramolecular catalysis. Part 1: non-covalent interactions as a tool for building and modifying homogeneous catalysts

(2013) Matthieu Raynal et al.   CHEMICAL SOCIETY REVIEWS

Enantio- and Diastereodivergent Dual Catalysis:  -Allylation of Branched Aldehydes

(2013) S. Krautwald et al.   SCIENCE

Methods for direct generation of α-alkyl-substituted aldehydes

(2013) David M. Hodgson et al.   TETRAHEDRON

Copper-catalyzed asymmetric propargylic amination of propargylic acetates with amines using BICMAP

(2013) Takashi Mino et al.   TETRAHEDRON-ASYMMETRY

Chiral Tridentate P,N,N Ligands for Highly Enantioselective Copper-Catalyzed Propargylic Amination with both Primary and Secondary Amines as Nucleophiles

(2012) Cheng Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective alkylation of β-keto phosphonates by direct use of diaryl methanols as electrophiles

(2012) Masashi Shibata et al.   CHEMICAL COMMUNICATIONS

Combining transition metal catalysis and organocatalysis – an update

(2012) Zhenting Du et al.   CHEMICAL SOCIETY REVIEWS

Cooperative Catalytic Reactions Using Distinct Transition-Metal Catalysts: Ruthenium- and Copper-Catalyzed Enantioselective Propargylic Alkylation

(2012) Masahiro Ikeda et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transition-Metal-Catalyzed Enantioselective Propargylic Substitution Reactions of Propargylic Alcohol Derivatives with Nucleophiles

(2012) Yoshiaki Nishibayashi   SYNTHESIS-STUTTGART

Synergistic catalysis: A powerful synthetic strategy for new reaction development

(2012) Anna E. Allen et al.   Chemical Science

Modulating the Acidity: Highly Acidic Brønsted Acids in Asymmetric Catalysis

(2011) Magnus Rueping et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Direct Catalytic Asymmetric Transformations under Proton-Transfer Conditions

(2011) Naoya Kumagai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Multiple Catalysis with Two Chiral Units: An Additional Dimension for Asymmetric Synthesis

(2011) Susy Piovesana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SN1-Type Reactions in the Presence of Water: Indium(III)-Promoted Highly Enantioselective Organocatalytic Propargylation of Aldehydes

(2011) Riccardo Sinisi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Copper-Catalysed Propargylic Substitution: Synthetic Scope Study and Application in Formal Total Syntheses of (+)-Anisomycin and (−)-Cytoxazone

(2011) Remko J. Detz et al.   CHEMISTRY-A EUROPEAN JOURNAL

A one-pot catalysis: the strategic classification with some recent examples

(2011) Nitin T. Patil et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Bifunctional organo/metal cooperative catalysis with cinchona alkaloid scaffolds

(2011) Linus Stegbauer et al.   Chemical Science

Cooperative Catalytic Reactions Using Organocatalysts and Transition-Metal Catalysts: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Aldehydes

(2010) Masahiro Ikeda et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Structural Aspects ofN-Triflylphosphoramides and Their Calcium Salts-Highly Acidic and Effective Brønsted Acids

(2010) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

Merging Organocatalysis with an Indium(III)-Mediated Process: A Stereoselective α-Alkylation of Aldehydes with Allylic Alcohols

(2010) Montse Guiteras Capdevila et al.   CHEMISTRY-A EUROPEAN JOURNAL

Unifying Metal and Brønsted Acid Catalysis-Concepts, Mechanisms, and Classifications

(2010) Magnus Rueping et al.   CHEMISTRY-A EUROPEAN JOURNAL

When Organocatalysis Meets Transition-Metal Catalysis

(2010) Cheng Zhong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper−Allenylidene Complexes as Key Intermediates

(2010) Gaku Hattori et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Transformations

(2010) Masahiro Terada   SYNTHESIS-STUTTGART

Asymmetric Reductive Amination by Combined Brønsted Acid and Transition-Metal Catalysis

(2009) Martin Klussmann   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of Hemiaminal Ethers by Chiral Brønsted Acids for Facile Access to Enantioselective Two-Carbon Homologation Using Enecarbamates

(2009) Masahiro Terada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Alkynylation of Imines by Cooperative Hydrogen Bonding and Metal Catalysis

(2009) Pedro de Armas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Propargylic Substitution Reactions

(2009) Yoshihiro Miyake et al.   ChemCatChem

Allenylidene and Higher Cumulenylidene Complexes

(2009) Victorio Cadierno et al.   CHEMICAL REVIEWS

Enantioselective Ring-Opening Reactions of Racemic Ethynyl Epoxides via Copper−Allenylidene Intermediates: Efficient Approach to Chiral β-Amino Alcohols

(2009) Gaku Hattori et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Copper-Catalyzed Propargylic Substitution Reaction of Propargylic Acetates with Enamines

(2009) Ping Fang et al.   ORGANIC LETTERS

Enantioselective Activation of Aldehydes by Chiral Phosphoric Acid Catalysts in an Aza-ene-type Reaction between Glyoxylate and Enecarbamate

(2008) Masahiro Terada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper-Catalyzed Propargylic Amination

(2008) Remko J. Detz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Asymmetric Propargylic Substitution Reactions of Propargylic Acetates with Amines

(2008) Gaku Hattori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium-Catalyzed Enantioselective Carbon−Carbon Bond Forming Reaction via Allenylidene-Ene Process: Synthetic Approach to Chiral Heterocycles Such As Chromane, Thiochromane, and 1,2,3,4-Tetrahydroquinoline Derivatives

(2008) Koji Fukamizu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY