Enzymatic assembly of carbon–carbon bonds via iron-catalysed sp3 C–H functionalization

Stereospecific Radical-Mediated B12-Dependent Methyl Transfer by the Fosfomycin Biosynthesis Enzyme Fom3

(2018) Martin I. McLaughlin et al.   BIOCHEMISTRY

Enantioselective Radical Cyclization for Construction of 5-Membered Ring Structures by Metalloradical C–H Alkylation

(2018) Yong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–C bond forming radical SAM enzymes involved in the construction of carbon skeletons of cofactors and natural products

(2018) Kenichi Yokoyama et al.   NATURAL PRODUCT REPORTS

Enantioselective C(sp3)‒H bond activation by chiral transition metal catalysts

(2018) Tyler G. Saint-Denis et al.   SCIENCE

Catalytic C(sp3)–H Alkylation via an Iron Carbene Intermediate

(2017) Jennifer R. Griffin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Decarboxylative alkenylation

(2017) Jacob T. Edwards et al.   NATURE

Enantioselective, intermolecular benzylic C–H amination catalysed by an engineered iron-haem enzyme

(2017) Christopher K. Prier et al.   Nature Chemistry

Identification of Mechanism-Based Inactivation in P450-Catalyzed Cyclopropanation Facilitates Engineering of Improved Enzymes

(2016) Hans Renata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Abiological catalysis by artificial haem proteins containing noble metals in place of iron

(2016) Hanna M. Key et al.   NATURE

Iron-catalyzed arylation of α-aryl-α-diazoesters

(2016) Ji-Min Yang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Directed evolution of cytochrome c for carbon–silicon bond formation: Bringing silicon to life

(2016) S. B. Jennifer Kan et al.   SCIENCE

Iridium(iii)-bis(imidazolinyl)phenyl catalysts for enantioselective C–H functionalization with ethyl diazoacetate

(2016) N. Mace Weldy et al.   Chemical Science

Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

(2016) John F. Hartwig et al.   ACS Central Science

Catalytic Asymmetric Arylation of α-Aryl-α-diazoacetates with Aniline Derivatives

(2015) Bin Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Glycyl radical activating enzymes: Structure, mechanism, and substrate interactions

(2014) Krista A. Shisler et al.   ARCHIVES OF BIOCHEMISTRY AND BIOPHYSICS

Heme Enzyme Structure and Function

(2014) Thomas L. Poulos   CHEMICAL REVIEWS

Mechanistic Diversity of RadicalS-Adenosylmethionine (SAM)-dependent Methylation

(2014) Matthew R. Bauerle et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Fundamental Challenges in Mechanistic Enzymology: Progress toward Understanding the Rate Enhancements of Enzymes

(2013) Daniel Herschlag et al.   BIOCHEMISTRY

A serine-substituted P450 catalyzes highly efficient carbene transfer to olefins in vivo

(2013) Pedro S Coelho et al.   Nature Chemical Biology

Olefin Cyclopropanation via Carbene Transfer Catalyzed by Engineered Cytochrome P450 Enzymes

(2012) P. S. Coelho et al.   SCIENCE

Advances in the Chemistry of Tetrahydroquinolines

(2011) Vellaisamy Sridharan et al.   CHEMICAL REVIEWS

Total Synthesis of Malyngamides K, L, and 5′′-epi-C and Absolute Configuration of Malyngamide L

(2011) Jun-Tao Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Silver-Catalyzed C-C Bond Formation Between Methane and Ethyl Diazoacetate in Supercritical CO2

(2011) A. Caballero et al.   SCIENCE

Catalytic C−H Insertions Using Iron(III) Porphyrin Complexes

(2008) Harun M. Mbuvi et al.   ORGANOMETALLICS