Journal
GREEN CHEMISTRY
Volume 16, Issue 4, Pages 2136-2141Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc42310g
Keywords
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Funding
- NNSFC [20902070, 21025207]
- ZJNSF [Y4100579]
- ZJQJTP [QJD0902004]
- Zhejiang Provincial Top Key Discipline of New Materials and Process Engineering [20110949]
- Undergraduate Training Program for Innovation and Pioneering of Wenzhou University [JWDC2012064]
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Unexpected dimethylsulfinyl anions (I), generated in situ from the superbase system CsOH-DMSO, was found to be a highly active catalyst for controllable nitrile hydration reactions in water, which selectively afforded the versatile amides via interesting Cs-activated I-catalyzed direct and indirect hydration mechanisms involving an O-transfer process from DMSO onto the nitriles.
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