Journal
GREEN CHEMISTRY
Volume 15, Issue 11, Pages 3150-3154Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc41154k
Keywords
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Funding
- 973 Program [2013CB933800, 2012CB821705]
- NSFC [91027003, 21072118, 21271120]
- PCSIRT
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A self-assembled nano-sized Pd6L8 (L = 1,3,5-tris(4'-pyridyloxadiazole)-2,4,6-triethylbenzene) ball was constructed based on a new oxadiazole-containing tripod. In H2O-EtOH mixed-solvent system, Pd(II)-ball displays excellent performance in Suzuki-Miyaura cross-coupling reactions at low catalyst loading under ambient conditions in a homogeneous fashion. Furthermore, it shows heterogeneous catalyst nature in o-xylene and can be reused without loss of catalytic activity.
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