Journal
GREEN CHEMISTRY
Volume 15, Issue 11, Pages 3015-3019Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3gc41089g
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Funding
- Centrale Initiatives Foundation
- European Framework Programme FP7 [241718]
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The ammoxidation of allyl alcohol was demonstrated over antimony-iron oxide catalysts with a Sb/Fe ratio of 0.6 and 1. Both catalysts showed high performance with 83 and 84% yield of acrylonitrile, respectively, whereby the main difference was found in the initial performance. This was ascribed to the in-operando formation of the SbFeO4 mixed oxide on the catalyst surface under reaction conditions, as proven by XPS analysis.
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