Journal
GREEN CHEMISTRY
Volume 14, Issue 11, Pages 2996-2998Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2gc36203a
Keywords
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Funding
- NRF WCU program [R31-2008-10029]
- NRF Priority Research Centers Program [2012R1A6A1040282]
- Human Resources Development Program of the KETEP [20124010203270]
- National Research Foundation of Korea [2009-0094023] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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We developed a protocol for the transition metal-free, direct oxidation of allylic alcohols using the simple base (NaOBu)-Bu-t under an oxygen atmosphere. The (NaOBu)-Bu-t-O-2 system exhibited unprecedented activity and selectivity in this oxidation reaction. In particular, a competing epoxidation reaction was suppressed under these conditions.
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