Journal
GREEN CHEMISTRY
Volume 13, Issue 1, Pages 46-50Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0gc00619j
Keywords
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Funding
- Chubu Bureau of Economy Trade and Industry
- [B21390030]
- [22106515]
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Solkane (R) 365mfc is a proven environmentally benign alternative solvent for catalyst-free Friedel-Crafts (F-C) alkylations of indoles with trifluoropyruvate and glyoxylate. Their enantioselective variants are also achieved by virtue of the high-affinity of fluorous cinchona alkaloids catalysts to Solkane (R) 365mfc to provide F-C adducts in excellent yields with good to excellent ees (up to 96% ee).
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