Journal
GREEN CHEMISTRY
Volume 11, Issue 5, Pages 733-737Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b823543k
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Funding
- DST, New Delhi [SR/S5/GC-02/2006]
- CSIR
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A simple and efficient procedure for the synthesis of 2-substituted benzimidazoles has been developed by a one-pot reaction of o-phenylenediamine with aromatic aldehydes in the presence of an ionic liquid, 1-methyl-3-pentylimidazolium tetrafluoroborate, [pmim]BF4 at room temperature in open air without any organic solvent. The ionic liquid is recycled. A remarkable influence of the substituent on the imidazolium unit of the ionic liquid on the outcome of the reaction is observed.
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