4.8 Article

Toward green metallurgy: low-temperature solution synthesis of bulk-scale intermetallic compounds in edible plant and seed oils

Journal

GREEN CHEMISTRY
Volume 11, Issue 7, Pages 974-978

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b815443k

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Funding

  1. U. S. Department of Energy [DE-FG02-06ER46333]
  2. Beckman Young Investigator
  3. Sloan Research Fellowship

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Binary intermetallic compounds have been synthesized in edible plant and seed oils through the reaction of molten metal dispersions of low-melting p-block metals with late transition metal powders. Specifically, apricot kernel, almond, safflower, and canola oils have been used to synthesize FeSn(2), Ni(3)Sn(4), CoSn(3), CoGa(3), Cu(6)Sn(5), and Bi(3)Ni. This low-temperature strategy yields bulk-scale products that are highly crystalline, and the solvents used to synthesize them can be re-used several times.

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