4.7 Review

Contrasting types of metasomatism in dunite, wehrlite and websterite xenoliths from Kimberley, South Africa

Journal

GEOCHIMICA ET COSMOCHIMICA ACTA
Volume 72, Issue 23, Pages 5722-5756

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.gca.2008.08.020

Keywords

-

Funding

  1. Deutsche Forschungsgemeinschaft [Fo181/17-1, Fo181/17-2]

Ask authors/readers for more resources

Dunite, wehrlite and websterite are rare members of the mantle xenolith suite in the Kimberley kimberlites or the Kaapvaal Craton in southern Africa. All three types were originally residues of extensive melt extraction and experienced varying amounts and types of melt re-enrichment. The melt depletion event, dated by Re-Os isotope systematics at 2.9 Ga or older, is evidenced by the high Mg# (Mg/(Mg + Fe)) of silicate minerals (olivine (0.89-0.93); pyroxene (0.88-0.93); garnet (0.72-0.85)), high Cr# (Cr/(Cr + Al)) of spinel (0.53-0.84) and mostly low whole-rock SiO2, CaO and Al2O3 contents. Shortly after melt depletion, websterites were formed by reaction between depleted peridotites and silica-rich melt (>60 wt% SiO2) derived by partial melting of eclogite before or during cratonization. The melt-peridotite interaction converted olivine into orthopyroxene. All three xenolith types have secondary metasomatic clinopyroxene and garnet, which occur along olivine grain boundaries and have an amoeboid texture. As indicated by the preservation of oxygen isotope disequilibrium in the minerals and trace-element concentrations in clinopyroxene and garnet, this metasomatic event is probably of Mesozoic age and was caused by percolating alkaline basaltic melts. This melt metasomatism enriched the xenoliths in CaO, Al2O3, FeO and high-field-strength-elements, and might correspond to the Karoo magmatism at 200 Ma. The websterite xenoliths experienced both the orthoyproxene-enrichment and clinopyroxene-garnet metasomatic events, whereas dunite and wehrlite xenoliths only saw the later basaltic melt event, and may have been situated further away from the source of melt migration channels. (C) 2008 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Geosciences, Multidisciplinary

The formation of TTGs by hydrous partial melting and anatexis from a gabbroic mantle source in Viti Levu, Fiji Islands

Holger Sommer, Alfred Kroner, Dorrit E. Jacob, Xiao-chao Che, Jean Wong, Hangqiang Xie

Summary: The TTG rocks in Viti Levu, Fiji Islands were formed through hydrous partial melting of gabbroic oceanic crust and anatexis of gabbro, resulting in the formation of tonalite and quartz diorite units during the late-Eocene to mid-Miocene. The zircon ages indicate different formation times for the parental gabbro and TTGs, with evidence of interaction with hydrothermally altered seafloor and a homogenous mantle source. Whole-rock calculations support the formation of tonalite through decompression at water-saturated amphibolite-facies conditions, while quartz diorite formed by anatexis under granulite-facies conditions at shallow depth in the South Pacific region.

PRECAMBRIAN RESEARCH (2021)

Article Environmental Sciences

Quantification of Non-Exhaust Particulate Matter Traffic Emissions and the Impact of COVID-19 Lockdown at London Marylebone Road

William Hicks, Sean Beevers, Anja H. Tremper, Gregor Stewart, Max Priestman, Frank J. Kelly, Mathias Lanoiselle, Dave Lowry, David C. Green

Summary: This study quantified the sources of non-exhaust particulate matter traffic emissions in London using highly time-resolved measurements over a 12-month period. The results revealed that brake wear is the primary source of non-exhaust emissions, and the emission factors are influenced by speed and road surface conditions. Further statistical analysis and advanced source apportionment techniques were used to enhance understanding of these important vehicle sources.

ATMOSPHERE (2021)

Article Geochemistry & Geophysics

Trace element and isotopic zoning of garnetite veins in amphibolitized eclogite, Franciscan Complex, California, USA

Alicia M. Cruz-Uribe, F. Zeb Page, Emilie Lozier, Maureen D. Feineman, Thomas Zack, Regina Mertz-Kraus, Dorrit E. Jacob, Kouki Kitajima

Summary: Garnet from an amphibolitized eclogite block in California shows complex growth patterns with similarities in composition between vein and matrix garnet. Major and trace element zoning in garnet reveals multiple growth stages, while oxygen isotope analyses suggest late-stage growth involved interaction with serpentinites.

CONTRIBUTIONS TO MINERALOGY AND PETROLOGY (2021)

Article Geology

Protogenetic sulfide inclusions in diamonds date the diamond formation event using Re-Os isotopes

M. G. Pamato, D. Novella, D. E. Jacob, B. Oliveira, D. G. Pearson, S. Greene, J. C. Afonso, M. Favero, T. Stachel, M. Alvaro, F. Nestola

Summary: Sulfides are the most abundant inclusions in diamonds and can be used to date diamond formation via Re-Os isotopic analyses. The study found that Re-Os isotope equilibration in sulfide inclusions is sufficiently fast at mantle temperatures to be reset by the diamond-forming event, confirming that the Re-Os isochrons likely reflect the ages of diamond formation.

GEOLOGY (2021)

Article Environmental Sciences

Methane emissions in Kuwait: Plume identification, isotopic characterisation and inventory verification

A. Al-Shalan, D. Lowry, R. E. Fisher, E. G. Nisbet, G. Zazzeri, M. Al-Sarawi, J. L. France

Summary: The largest observed source of methane in Kuwait is landfill sites, with smaller contributions from fossil fuel industry, wastewater treatment, and ruminant animals. Isotopic analysis helps identify the sources of methane and their relative contributions.

ATMOSPHERIC ENVIRONMENT (2022)

Article Multidisciplinary Sciences

Isotopic signatures of methane emissions from tropical fires, agriculture and wetlands: the MOYA and ZWAMPS flights

Euan G. Nisbet, Grant Allen, Rebecca E. Fisher, James L. France, James D. Lee, David Lowry, Marcos F. Andrade, Thomas J. Bannan, Patrick Barker, Prudence Bateson, Stephane J-B Bauguitte, Keith N. Bower, Tim J. Broderick, Francis Chibesakunda, Michelle Cain, Alice E. Cozens, Michael C. Daly, Anita L. Ganesan, Anna E. Jones, Musa Lambakasa, Mark F. Lunt, Archit Mehra, Isabel Moreno, Dominika Pasternak, Paul Palmer, Carl J. Percival, Joseph R. Pitt, Amber J. Riddle, Matthew Rigby, Jacob T. Shaw, Angharad C. Stell, Adam R. Vaughan, Nicola J. Warwick, Shona E. Wilde

Summary: This study reports methane isotopologue data from Africa and South America, highlighting the importance of tropical wetlands and fires as sources of methane emissions. The isotopic signatures of methane have significant implications for global methane budget models and efforts to reduce air pollution in Africa.

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES (2022)

Article Multidisciplinary Sciences

δ13C methane source signatures from tropical wetland and rice field emissions

James L. France, Rebecca E. Fisher, David Lowry, Grant Allen, Marcos F. Andrade, Stephane J-B Bauguitte, Keith Bower, Timothy J. Broderick, Michael C. Daly, Grant Forster, Mangaliso Gondwe, Carole Helfter, Alison M. Hoyt, Anna E. Jones, Mathias Lanoiselle, Isabel Moreno, Peter B. R. Nisbet-Jones, David Oram, Dominika Pasternak, Joseph R. Pitt, Ute Skiba, Mark Stephens, Shona E. Wilde, Euan G. Nisbet

Summary: The rising atmospheric methane burden and the uncertainty surrounding its causes are the focus of this study. The researchers present a collection of new delta C-13(CH4) signatures for tropical wetlands and rice fields, which provide insights into isotopic variation and potential seasonal shifts. Long-term monitoring at two observatories in Bolivia and Botswana shows that biogenic methane sources, particularly wetlands, dominate the records. The findings suggest significant seasonal variation in tropical wetland delta C-13(CH4) signatures, highlighting the need to incorporate this variability into future global and regional models.

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES (2022)

Article Multidisciplinary Sciences

Is the destruction or removal of atmospheric methane a worthwhile option?

Peter B. R. Nisbet-Jones, Julianne M. Fernandez, Rebecca E. Fisher, James L. France, David Lowry, David A. Waltham, Ceres A. Woolley Maisch, Euan G. Nisbet

Summary: This note examines the justifiability of removing methane from the atmosphere, highlighting the significant positive impact it can have on reducing greenhouse effects, but also acknowledging the energy costs associated with various oxidation methods.

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES (2022)

Article Environmental Sciences

Street-level methane emissions of Bucharest, Romania and the dominance of urban wastewater.

J. M. Fernandez, H. Maazallahi, J. L. France, M. Menoud, M. Corbu, M. Ardelean, A. Calcan, A. Townsend-Small, C. van der Veen, R. E. Fisher, D. Lowry, E. G. Nisbet, T. Rockmann

Summary: Atmospheric methane continues to increase and it is crucial to target specific anthropogenic source categories for emissions reduction. In Bucharest, Romania, mobile measurement techniques were used to locate street-level methane leaks and determine their sources. The study found a significant number of leak indications, with a majority attributed to biogenic wastewater and natural gas. Bucharest's methane emissions exceeded those of Hamburg and Paris.

ATMOSPHERIC ENVIRONMENT-X (2022)

Article Environmental Sciences

Stable isotopic signatures of methane from waste sources through atmospheric measurements

Semra Bakkaloglu, Dave Lowry, Rebecca E. Fisher, Malika Menoud, Mathias Lanoiselle, Huilin Chen, Thomas Rockmann, Euan G. Nisbet

Summary: This study characterizes the carbon isotopic signatures of methane waste sources and explores the use of hydrogen isotopes for waste source identification. The results show distinct signatures for different waste sources, providing valuable information for regional modeling.

ATMOSPHERIC ENVIRONMENT (2022)

Article Geology

Protogenetic clinopyroxene inclusions in diamond and Nd diffusion modeling-Implications for diamond dating

L. Pasqualetto, F. Nestola, D. E. Jacob, M. G. Pamato, B. Oliveira, S. Perritt, I Chinn, P. Nimis, S. Milani, J. W. Harris

Summary: This study evaluated the reliability of Sm-Nd ages in clinopyroxene inclusions in diamonds. Through crystallographic orientation analyses and Nd diffusion modeling, it was found that some inclusions were co-genetic with diamonds, while others were older. Based on the modeling results, clinopyroxene inclusions smaller than 0.2 mm and equilibrated at temperatures higher than 1050-1080 degrees C may be the most suitable for age determinations.

GEOLOGY (2022)

Article Multidisciplinary Sciences

The nano- and meso-scale structure of amorphous calcium carbonate

Simon M. Clark, Bruno Colas, Dorrit E. Jacob, Joerg C. Neuefeind, Hsiu-Wen Wang, Katherine L. Page, Alan K. Soper, Philipp Schodder, Patrick Duchstein, Benjamin Apeleo Zubiri, Tadahiro Yokosawa, Vitaliy Pipich, Dirk Zahn, Erdmann Spiecker, Stephan E. Wolf

Summary: Understanding the processes of biomineralization is important for various disciplines, such as quantifying the effects of climate change on marine organisms and advancing biomimetic materials. This study focuses on determining the structure of intermediate amorphous phases, specifically amorphous calcium carbonate (ACC), using simulations and experimental data. The researchers found that ACC consists of ordered nano-domains and a matrix of water molecules, resulting in a gel-like structure. These findings provide a new atomic-scale understanding of ACC and contribute to the general exploration of biomineralization and biomimetic processes.

SCIENTIFIC REPORTS (2022)

Article Chemistry, Multidisciplinary

The Kinetics of Aragonite Formation from Solution via Amorphous Calcium Carbonate

Simon M. Clark, Vili Grigorova, Bruno Colas, Tamim A. Darwish, Kathleen Wood, Joerg Neuefeind, Dorrit E. Jacob

Summary: Magnesium doped Amorphous Calcium Carbonate can be synthesized by adjusting the Mg/Ca ratio in the precursor solution. The resultant Amorphous Calcium Carbonate crystallizes as aragonite, with no Mg present. Changes in the Mg to Ca ratio have minimal effect on nucleation rates but strongly impact crystal growth rates, suggesting a dissolution-reprecipitation model for aragonite formation via an Amorphous Calcium Carbonate intermediate.

NANOMATERIALS (2022)

Article Environmental Sciences

Quantification and assessment of methane emissions from offshore oil and gas facilities on the Norwegian continental shelf

Amy Foulds, Grant Allen, Jacob T. Shaw, Prudence Bateson, Patrick A. Barker, Langwen Huang, Joseph R. Pitt, James D. Lee, Shona E. Wilde, Pamela Dominutti, Ruth M. Purvis, David Lowry, James L. France, Rebecca E. Fisher, Alina Fiehn, Magdalena Puehl, Stephane J. B. Bauguitte, Stephen A. Conley, Mackenzie L. Smith, Tom Lachlan-Cope, Ignacio Pisso, Stefan Schwietzke

Summary: The oil and gas sector is a significant source of methane emissions, and quantifying these emissions remains challenging. This study compares methane emission data collected from 21 offshore facilities with operator-reported emissions and a global inventory. The results show that operator-reported emissions are accurate, while the global inventory underestimates the emissions.

ATMOSPHERIC CHEMISTRY AND PHYSICS (2022)

Article Environmental Sciences

Atmospheric composition in the European Arctic and 30 years of the Zeppelin Observatory, Ny-Ålesund

Stephen M. Platt, Oystein Hov, Torunn Berg, Knut Breivik, Sabine Eckhardt, Konstantinos Eleftheriadis, Nikolaos Evangeliou, Markus Fiebig, Rebecca Fisher, Georg Hansen, Hans-Christen Hansson, Jost Heintzenberg, Ove Hermansen, Dominic Heslin-Rees, Kim Holmen, Stephen Hudson, Roland Kallenborn, Radovan Krejci, Terje Krognes, Steinar Larssen, David Lowry, Cathrine Lund Myhre, Chris Lunder, Euan Nisbet, Pernilla B. Nizzetto, Ki-Tae Park, Christina A. Pedersen, Katrine Aspmo Pfaffhuber, Thomas Rockmann, Norbert Schmidbauer, Sverre Solberg, Andreas Stohl, Johan Strom, Tove Svendby, Peter Tunved, Kjersti Tornkvist, Carina van der Veen, Stergios Vratolis, Young Jun Yoon, Karl Espen Yttri, Paul Zieger, Wenche Aas, Kjetil Torseth

Summary: The Zeppelin Observatory is an important atmospheric measurement site located on Zeppelin Mountain in the Svalbard archipelago. It is part of several European and global monitoring programmes and research infrastructures. This article provides details on the establishment of the observatory and presents a review of the current state of the European Arctic atmosphere and future research directions.

ATMOSPHERIC CHEMISTRY AND PHYSICS (2022)

Article Geochemistry & Geophysics

Uranium isotopes in non-euxinic shale and carbonate reveal dynamic Katian marine redox conditions accompanying a decrease in biodiversity prior to the Late Ordovician Mass Extinction

Xinze Lu, Geoffrey J. Gilleaudeau, Brian Kendall

Summary: The Late Ordovician mass extinction is the first major extinction event in the Phanerozoic, but the reasons for the decline in global biodiversity before the extinction are not well understood.

GEOCHIMICA ET COSMOCHIMICA ACTA (2024)

Article Geochemistry & Geophysics

Trace element evidence for diverse origins of superheavy pyrite in Neoproterozoic sedimentary strata

Junyao Kang, Daniel D. Gregory, Benjamin Gill, Shiqiang Huang, Changxin Lai, Zhaoshan Chang, Huan Cui, Ivan Belousov, Shuhai Xiao

Summary: Sedimentary pyrite is an important geological archive, but it can be altered by diagenetic and hydrothermal processes. This study successfully trained machine learning algorithms to distinguish pyrite origins using trace element data. The approach was validated and applied to identify the origins of pyrite in two sedimentary successions in South China.

GEOCHIMICA ET COSMOCHIMICA ACTA (2024)