Journal
FUNCTIONAL MATERIALS LETTERS
Volume 4, Issue 3, Pages 299-303Publisher
WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S1793604711002111
Keywords
Coprecipitation method; LiMn0.4Fe0.6PO4; homogeneous distribution; rate capability
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Funding
- National Basic Research Program of China [2009CB220100]
- National High Technology Research and Development Program of China [2009AA035200]
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A multicomponent olivine cathode material, LiMn0.4Fe0.6PO4, was synthesized via a novel coprecipitation method of the mixed transition metal oxalate. X-ray diffraction patterns indicate that carbon-coated LiMn0.4Fe0.6PO4 has been prepared successfully and that LiMn0.4Fe0.6PO4/C is crystallized in an orthorhombic structure without noticeable impurity. Homogeneous distribution of Mn and Fe in LiMn0.4Fe0.6PO4/C can be observed from the scanning electron microscopy (SEM) and the corresponding energy dispersive X-ray spectrometry (EDS) analysis. Hence, the electrochemical activity of each transition metal in the olivine synthesized via coprecipitation method was enhanced remarkably, as indicated by the galvanostatic charge/discharge measurement. The synthesized LiMn0.4Fe0.6PO4/C exhibits a high capacity of 158.6 +/- 3 mAhg(-1) at 0.1 C, delivering an excellent rate capability of 122.6 +/- 3 mAhg(-1) at 10C and 114.9 +/- 3 mAhg(-1) at 20C.
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