Journal
FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES
Volume 18, Issue 4-6, Pages 386-391Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/1536383X.2010.487436
Keywords
Dimerized C-60; In-situ high-pressure; Phase transition; Synchrotron radiation; X-ray powder diffraction
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Similarly to preformed polymeric phases such as 1D-Pmnn [O] or 2D-Immm [T], and in contrast to monomeric FCC C-60, dimeric C-60 [D or R'] is expected to yield new polymerized phases of higher dimensions when subjected to high pressure. We have carried out an in-situ high-pressure powder diffraction experiment in a diamond anvil cell using MoK alpha laboratory X-rays, on a pure dimeric sample previously carefully characterized at ambient pressure using synchrotron X-ray HR XRPD and Raman spectroscopy. A transition is indeed observed from 1.2 to 8.6 GPa. A robust analysis shows that the volume per C-60 unit decreases from 689 angstrom(3) (0 GPa) to 550 angstrom(3) (8.6 GPa), resulting in a 20% effect. The new phase can no longer be described by a cubic (FCC) unit cell, whereas it can now be indexed and LeBail-refined using a trigonal/rhombohedral unit cell predicted by Dzyabchenko et al. in 1999.
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