Article
Engineering, Environmental
Shuang Zhang, Baohui Li, Yi Chen, Mengqiang Zhu, Joel A. Pedersen, Baohua Gu, Zimeng Wang, Hui Li, Jinling Liu, Xin-Quan Zhou, Yun-Yun Hao, Hong Jiang, Fan Liu, Yu-Rong Liu, Hui Yin
Summary: Methylmercury (MeHg) is a potent neurotoxin with adverse health impacts on humans. This research demonstrates that trivalent manganese (Mn(III)) can degrade MeHg in natural environments, suggesting potential applications for remediating heavily polluted soils and engineered systems containing MeHg.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Chemistry, Physical
Kishor Kumar Sahu, Rakesh K. Sahoo, L. D. Beshra, Mamata Mohapatra
Summary: A surfactant-free method was used to synthesize porous nickel oxalate (NiOX) and cabbage-like nickel oxide (NiO) nanostructures, which showed increased surface area and enhanced electrochemical performance after annealing at different temperatures in open atmosphere. The fabricated electrodes exhibited specific capacitance values of up to 888 Cg(-1) and energy density of 26.1 Wh kg(-1) for super capacitor application, demonstrating improved charge storage capacity and performance.
Article
Chemistry, Physical
Pamela Machado, Roger Guzman, Ramon J. . Morera, Jordi Alcala, Anna Palau, Wu Zhou, Mariona Coll
Summary: The need for highly performant and stable p-type transparent electrodes based on abundant metals is driving research on perovskite oxide thin films. Cost-efficient and scalable solution-based techniques are being explored to prepare these materials and extract their full potential.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Physical
Martin Stastny, Gloria Issa, Daniela Popelkova, Jakub Ederer, Martin Kormunda, Sylvie Krizenecka, Jiri Henych
Summary: Nanostructured MnOx catalysts prepared via redox reactions and alkaline precipitation exhibit high catalytic activity in degrading organic molecules and methanol decomposition reactions. The catalytic properties are highly dependent on the synthesis method and the fractions of redox-active surface sites.
CATALYSIS SCIENCE & TECHNOLOGY
(2021)
Article
Engineering, Environmental
Jifang Zheng, Dong Li, Huiping Zeng, Sen Yang, Zhaoxiang Zhang, Jie Zhang
Summary: This study found that Fe(II) significantly inhibited the removal of Mn(II) and prolonged the start-up of biofilters. Fe(II) and the Fe(III) oxyhydroxides generated from Fe(II) oxidation inhibited the removal of Mn(II) by affecting the proliferation of MnOB and the activity of MnOx in the biofilter.
JOURNAL OF WATER PROCESS ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Chao Feng, Gaoyan Xiong, Yaping Li, Qianqian Gao, Yuan Pan, Zhaoyang Fei, Yanpeng Li, Yukun Lu, Chenguang Liu, Yunqi Liu
Summary: The study found that the alpha-MnO2 nanowires with mainly exposed (110) facets exhibited the highest catalytic activity, which was attributed to the generation of reactive oxygen species and the regulation of Mn surface valence on this facet.
Article
Chemistry, Physical
Nicolay N. Golovnev, Marina A. Gerasimova, Maxim S. Molokeev, Mikhail E. Plyaskin, Mikhail E. Baronin
Summary: This study reports the hydrothermal synthesis of two lead-free zero-dimensional luminescent organic-inorganic hybrid compounds and discusses the influence of halide ion and metal ion on their photoluminescence properties. The compounds exhibit a distorted tetrahedral geometry around the manganese(II) metal center and show bright green emission upon UV excitation with moderate PLQY. The structures are stabilized by various hydrogen bonds and pi-pi stacking interactions.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Multidisciplinary
Kyubin Shim, Kyeong-Deok Seo, Hae Jin Kim
Summary: This study proposes a method to synthesize a Mn2+- coordinated polymer precursor ligated by sulfur atoms with acetate counter ions. MnS/MnO decorated N, S-doped carbon nanoparticles are prepared by calcination of the Mn ion-coordinated polymer for the practical applications of catalytic reactions. The performance of the nanoparticles in catalytic oxidation reactions is mainly related to the MnO decorated outside the SNC particles compared to MnS formed inside the particles.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Environmental Sciences
Yuheng Huang, Xiaoliu Huangfu, Chengxue Ma, Ziqiang Liu
Summary: Microorganisms can oxidize Mn(II) to biogenic Mn oxides through enzyme-mediated and non-enzyme-mediated processes, which are considered as the source and sink of heavy metals. Understanding the interactions between Mn(II) oxidizing microorganisms and heavy metals is important for studying microbial-mediated self-purification of water bodies.
Article
Chemistry, Analytical
Zhuqing Fang, Shukui Li, Jiping Liu, Chuang Yu, Dongsen Zheng, Meizhuang Qiao
Summary: This study investigates the influence of lithium aluminium hydride (LiAlH4) on the decomposition process of cyclotrimethylenetrinitramine (RDX). The results show that LiAlH4 significantly decreases the decomposition temperature of RDX and alters its decomposition pattern.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2022)
Article
Chemistry, Physical
Xueqiang Liu, Diandi Li, Jiguang Li, Jianle Wang, Shujie Liang, Hong Deng
Summary: Heavy metal ion pollution poses a significant threat to human health, and finding an economical and efficient technology for metal removal is necessary. Modified biochar has been proven effective, but traditional modification methods have limitations. In this study, a new HMBC material was synthesized using a simple method and showed high adsorption performance and selectivity for lead and cadmium. This newly prepared HMBC has the potential to treat industrial wastewater contaminated with lead and cadmium.
SURFACES AND INTERFACES
(2022)
Article
Chemistry, Physical
Zarife Sibel Sahin, Mehmet Demir, Tugrul Yildirim, Omer Yurdakul, Dursun Ali Kose
Summary: Four novel metal organic framework (MOF) structures containing acesulfame and 1,10-phenanthroline ligands of Co2+, Ni2+, Cu2+ and Zn2+ metal cations were synthesized and characterized. Crystal structure analysis of three compounds was performed and proposed for complex 4. The highest hydrogen gas adsorption was found for the Ni complex among the synthesized MOF structures.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Engineering, Chemical
Miao Fei, Lei Ni, Tianyi Yan, Juncheng Jiang, Hang Yao, Han Zhang, Chenwei Dai
Summary: In this study, the exothermic and mechanism of the synthesis of tert-butyl hydrogen peroxide were investigated by combining experiments with theoretical calculation. The exothermic characteristic was analyzed using reaction calorimeter, while the thermal decomposition characteristics of reactants and products were analyzed using differential scanning calorimeter and adiabatic calorimeter. The reaction mechanism was analyzed using reaction calorimeter, gas chromatography, and density functional theory. The risk level of the reaction process was evaluated using risk matrix and Stoessel critical diagram.
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
(2023)
Article
Chemistry, Physical
Romain Vollondat, Stephane Roques, Celine Chevalier, Jeremy Bartringer, Jean-Luc Rehspringer, Abdelilah Slaoui, Thomas Fix
Summary: Type I (Na8Si46) or type II (Nax <= 24Si136) silicon clathrates films with a large surface area have been synthesized using a two-step process. The specific type of silicon clathrates phase can be selectively obtained by finely tuning the synthesis conditions. These films demonstrate higher optical absorption coefficients compared to diamond silicon in the visible light range, with type II films showing a direct bandgap suitable for photovoltaic applications. The surface defects and inhomogeneities of the as-prepared type II films have been significantly reduced through pressure annealing treatment.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Engineering, Environmental
Fengyang Jing, Zhipeng Ma, Jing Wang, Yuqian Fan, Xiujuan Qin, Guangjie Shao
Summary: In this study, in-situ Raman and electrochemical quartz crystal microbalance techniques combined with density functional theory (DFT) calculations were employed to investigate the charge storage mechanism of MnOx@graphene microspheres electrode in alkaline electrolyte. The results revealed the transformation of layered MnO(2) into spinel Mn3O4 phase during the discharge process, accompanied by the insertion of potassium ions. Moreover, it was found that the presence of potassium ions contributed to the stability of the MnO structure. Additionally, the MnOx@graphene microspheres electrode demonstrated excellent cyclic stability.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Analytical
Miroslava A. Nedyalkova, Borjana V. Donkova, Vasil D. Simeonov
JOURNAL OF AOAC INTERNATIONAL
(2017)
Article
Materials Science, Multidisciplinary
B. Donkova, P. Vasileva, D. Nihtianova, N. Velichkova, P. Stefanov, D. Mehandjiev
JOURNAL OF MATERIALS SCIENCE
(2011)
Article
Physics, Condensed Matter
I. A. Pronin, B. V. Donkova, D. Tz. Dimitrov, I. A. Averin, J. A. Pencheva, V. A. Moshnikov
Article
Biochemistry & Molecular Biology
Dimitar S. Dimitrov, Miroslava A. Nedyalkova, Borjana V. Donkova, Vasil D. Simeonov
Article
Chemistry, Multidisciplinary
Miroslava Nedyalkova, Dimitar Dimitrov, Borjana Donkova, Vasil Simeonov
Article
Multidisciplinary Sciences
Miroslava Nedyalkova, Dimitar Dimitrov, Borjana Donkova, Vasil Simeonov
Article
Chemistry, Multidisciplinary
Haruna L. Barazorda-Ccahuana, Miroslava Nedyalkova, Ilia Kichev, Sergio Madurga, Borjana Donkova, Vasil Simeonov
Article
Materials Science, Multidisciplinary
T. Chouki, B. Donkova, B. Aktarla, P. Stefanov, S. Emin
Summary: The study demonstrates that MoSe2 thin films can be successfully grown using colloidal molybdenum nanoparticles (Mo NPs) synthesized through a wet-chemical method and the chemical vapor deposition (CVD) approach, showing promising potential as efficient catalysts for the hydrogen evolution reaction (HER).
MATERIALS TODAY COMMUNICATIONS
(2021)
Proceedings Paper
Biotechnology & Applied Microbiology
I. A. Pronin, I. A. Averin, N. D. Yakushova, V. A. Moshnikov, B. Donkova, D. Tz Dimitrov, A. Tz Georgieva, S. S. Nalimova, A. A. Karmanov
PROCEEDINGS OF THE II INTERNATIONAL CONFERENCE: MODERN SYNTHETIC METHODOLOGIES FOR CREATING DRUGS AND FUNCTIONAL MATERIALS (MOSM2018)
(2019)
Article
Chemistry, Physical
Miroslava Nedyalkova, Borjana Donkova, Julia Romanova, George Tzvetkov, Sergio Madurga, Vasil Simeonov
ADVANCES IN COLLOID AND INTERFACE SCIENCE
(2017)
Proceedings Paper
Engineering, Electrical & Electronic
N. D. Yakushova, I. A. Averin, B. V. Donkova, D. Tz. Dimitrov, I. A. Pronin, D. S. Mazing, O. A. Aleksandrova, V. A. Moshnikov
PROCEEDINGS OF THE 2016 IEEE NORTH WEST RUSSIA SECTION YOUNG RESEARCHERS IN ELECTRICAL AND ELECTRONIC ENGINEERING CONFERENCE (ELCONRUSNW)
(2016)
Article
Chemistry, Multidisciplinary
B. Donkova, V. Petkova
BULGARIAN CHEMICAL COMMUNICATIONS
(2015)
Article
Multidisciplinary Sciences
Boriana Donkova, Dimitar Mehandjiev
COMPTES RENDUS DE L ACADEMIE BULGARE DES SCIENCES
(2013)
Article
Chemistry, Multidisciplinary
B. V. Donkova, K. I. Milenova, M. S. Khristova, D. R. Mehandjiev
BULGARIAN CHEMICAL COMMUNICATIONS
(2011)