Journal
FARADAY DISCUSSIONS
Volume 157, Issue -, Pages 89-100Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2fd20004j
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- National Science Council of Taiwan, Academia Sinica
- Air Force Office of Scientific research [AOARD-12-4020]
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One quantum excitation of methane to CH4(nu(3) = 1) was found to prohibit the CH bond rupture, thus slowing down the total reactivity toward F atoms, and when the reaction does occur, only stretch-excited methyl radical CH3(nu(1)/nu(3) =1) products have significant yields.
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