Journal
FARADAY DISCUSSIONS
Volume 151, Issue -, Pages 263-270Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0fd00020e
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- UK Engineering and Physical Sciences Research Council
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The hydrogenation of Li3N at low chemical potential has been studied in situ by time-of-flight powder neutron diffraction and the formation of a non-stoichiometric Li4-2xNH phase and Li4NH observed. The results are interpreted in terms of a model for the reaction pathway involving the production of Li4NH and Li2NH, which subsequently react together to form Li4-2xNH. Possible mechanisms for the production of Li4NH from the hydrogenation of Li3N are discussed.
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