Article
Materials Science, Multidisciplinary
Nada S. Al-Kadhi, Hoda A. Ahmed, Rami Adel Pashameah, Awatif Rashed Z. Almotairy, Arafat Toghan, Shoug M. Alghamdi, Fowzia S. Alamro, Ayman M. Mostafa
Summary: The effect of lithium titanium oxide nanoparticles (Li4Ti5O12 NPs) on the optical and electrical performance of polyether sulfone (PES) nanocomposite films was investigated. The interaction between PES and Li4Ti5O12 NPs was confirmed by XRD and FT-IR. The addition of Li4Ti5O12 NPs increased the crystallinity of PES and formed charge transfer complexes. The results suggest that Li4Ti5O12 NPs are a promising dopant for improving the electrical properties of PES and have potential applications in various fields.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Chemistry, Physical
Rosinildo Fideles do Nascimento, Anielle Christine Almeida Silva, Tasso O. Sales, Artur F. Sonsin, Eduardo Jorge da Silva Fonseca, Samuel T. Souza, Ygor M. de Oliveira, Fabiane C. de Abreu, Noelio Oliveira Dantas
Summary: The study demonstrates that the ratio of CdSe/CdS ultrasmall quantum dots conjugated with reduced graphene oxide significantly affects the properties of the nanocomposites, with a higher proportion of USQDs leading to luminescence quenching and an increase in nonradiative decay rate due to electron transfer processes.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Chemistry, Inorganic & Nuclear
Habib Chenaina, Charfeddine Messaadi, Jalila Jalali, Hatem Ezzaouia
Summary: This study focuses on sol-gel derived SnO2-TiO2 thin films deposited on silicon wafer type Si (100) substrate using spin coating technique, followed by heat treatments at four different temperatures. XRD characterization reveals the formation of nano-crystalline phase at 400 degrees C and further crystallization with increasing annealing temperature. Optical and dielectric properties analysis demonstrates universal many body response over a broad frequency range, presenting variations in structure and performance of the films.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Materials Science, Multidisciplinary
Emad M. Ahmed, Ali A. Alkathiri
Summary: CeO(2)NPs successfully incorporated into chitosan to synthesize nanocomposites showed improved thermal stability and enhanced optical properties. The dielectric constant increased with CeO(2)NPs concentration, making them suitable for future bio-applications.
MATERIALS RESEARCH EXPRESS
(2022)
Review
Materials Science, Multidisciplinary
Binh M. Trinh, Boon P. Chang, Tizazu H. Mekonnen
Summary: The current packaging materials market is dominated by single-use plastics derived from petrochemicals, which are inexpensive and environmentally stable. However, these plastics pose a threat to the environment as they are rarely recycled and often end up in landfills or littered in the environment. Nature-derived and biodegradable polymers offer potential alternatives, but their barrier properties fall short compared to traditional plastics. Therefore, there is a need to enhance the barrier properties of sustainable polymer systems through chemistry and processing technology. This review summarizes the important contributions and advancements in improving the gas and moisture barrier properties of sustainable polymer systems for packaging applications, including microstructure tuning, surface energy modification, morphology control, and self-assembly.
PROGRESS IN MATERIALS SCIENCE
(2023)
Article
Construction & Building Technology
Esequiel Mesquita, Israel Sousa, Mylene Vieira, Ana Mafalda Matos, Luis P. M. Santos, Laura Silvestro, Renan Salvador, Antonella D'Alessandro, Filippo Ubertini
Summary: In recent years, the use of nanomaterials, particularly carbon nanotubes, in cement-based composites has attracted considerable attention due to their potential in monitoring civil structures and infrastructures. However, the challenge lies in dispersing the nanotubes effectively and efficiently, which is typically addressed using sonic treatments or surfactants. This study aims to analyze the self-sensing properties of cementitious composites developed with NaOH as the dispersing agent, and the findings suggest that the dispersing strategy using NaOH is promising for enhancing the sensing properties of the composites.
JOURNAL OF BUILDING ENGINEERING
(2023)
Article
Materials Science, Ceramics
Oykum Basgoz, Omer Guler, Ertan Evin, Cagdas Yavuz, Ghada ALMisned, Shams A. M. Issa, Hesham M. H. Zakaly, H. O. Tekin
Summary: In this study, Fe2O3, TiO2, and CdO semiconductor metal oxides were incorporated into the ZnO-MWCNT composite at different weight percentages. Experimental analyses were conducted to investigate the impact of these nanocomposites on electrical, optical, and radiation shielding characteristics. The results showed that the addition of 5% oxide resulted in the highest electrical conductivity and reflection characteristics. Among the CdO doped materials, CZnOCd5 exhibited the highest electrical conductivity and had the greatest Eg values. Furthermore, CZnOCd5 demonstrated the highest reflectance and gamma-ray attenuation properties.
CERAMICS INTERNATIONAL
(2022)
Article
Nanoscience & Nanotechnology
Poushali Das, Sayan Ganguly, Andreas Rosenkranz, Bo Wang, Jinhong Yu, Seshasai Srinivasan, Amin Reza Rajabzadeh
Summary: MXenes are highly versatile materials that can compete with and outperform graphene in certain applications. The self-restacking issue can be addressed by hybridizing with low-dimensional nanostructures. This review highlights recent advancements and emerging applications in this field, as well as the challenges that need to be overcome.
MATERIALS TODAY NANO
(2023)
Review
Chemistry, Physical
Mahsa Khorshidi, Saeid Asadpour, Narges Sarmast, Mohammad Dinari
Summary: This review paper describes the properties of LDHs, carbon nanomaterials, and their combined nanocomposites, and presents current techniques for synthesizing these hierarchical nanocomposites. Recent advancements show that LDH/carbon material nanocomposites have promising applications as adsorbents, photocatalysts, catalysts, energy storage systems, materials with improved properties, and highly sensitive sensors. However, there is still a need for further research on the structure-application relationship, synthesis methods, theoretical calculations, and application in other fields.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Review
Materials Science, Multidisciplinary
Hamed Aghamohammadi, Nima Amousa, Reza Eslami-Farsani
Summary: MXene, a novel 2D nanomaterial synthesized by selective etching of A elements in MAX phases, has unique mechanical, tribological, thermal, and electrical properties, making it suitable for reinforcing polymeric composites. However, research on the properties of MXene/polymer nanocomposites is still limited.
Review
Chemistry, Inorganic & Nuclear
Vivek Sharma, Dipak Kumar Das, Ram K. Gupta, Ghulam Yasin, Anuj Kumar
Summary: MXenes-based nanomaterials show great potential as efficient and low-cost electrocatalysts for oxygen reduction reaction. Their synthesis strategies, electronic and structural properties, and ORR performance are of significant importance. However, there are still challenges and potential aspects that need further research.
INORGANIC CHEMISTRY COMMUNICATIONS
(2022)
Article
Materials Science, Characterization & Testing
Marcos Antonio Gimenes Benega, Wellington Marcos Silva, Mariane Cristina Schnitzler, Ricardo Jorge Espanhol Andrade, Helio Ribeiro
Summary: Polymeric nanocomposites incorporating carbon nanomaterials have shown significant improvements in thermal and mechanical properties compared to their conventional counterparts, making them attractive materials for various technological applications.
Article
Polymer Science
Ali Atta, Mohammed F. Alotiby, Nuha Al-Harbi, Mohamed R. El-Aassar, Mohamed A. M. Uosif, Mohamed Rabia
Summary: This research paper aims to fabricate flexible PVA/Cs/TiO2 nanocomposite films for energy storage devices. Various analytical techniques confirmed the successful fabrication of the PVA/Cs/TiO2 films, with homogenous distribution of TiO2 in the PVA/Cs chains. The composite films exhibited improved electrical conductivity and dielectric constant compared to pure PVA/Cs films.
Article
Green & Sustainable Science & Technology
Krystof Skrbek, Vilem Bartunek, David Sedmidubsky
Summary: Among alternative energy storage and production technologies, advanced heat transfer technologies have gained popularity. By adding nanomaterials, the thermophysical properties of molten salt-based composites can be improved. This review focuses on summarizing the progress in this area, including the influencing factors and preparation techniques.
RENEWABLE & SUSTAINABLE ENERGY REVIEWS
(2022)
Article
Biochemistry & Molecular Biology
Malgorzata Noworyta, Monika Topa-Skwarczynska, Pawel Jamroz, Dawid Oksiuta, Malgorzata Tyszka-Czochara, Klaudia Trembecka-Wojciga, Joanna Ortyl
Summary: Photopolymerization is an environmentally friendly and versatile field, commonly used for curing coatings and producing 3D objects. This study investigates the effects of inorganic nanofillers on the conversion rates and viscosity of polymer nanocomposites using Real Time FT-IR. It also presents 3D prints of the selected nanocomposites.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2023)
Article
Chemistry, Multidisciplinary
Mariafrancesca Baratta, Giovanni De Filpo, Antonio Tursi, Alexander Mashin, Fiore P. Nicoletta
Summary: Polymer-dispersed liquid crystals (PDLCs) are formed by liquid crystal droplets embedded in a polymer matrix, which can have different liquid crystal director configurations. Pressure sensors are an important recent application of PDLCs, where applying pressure causes changes in droplet shape and liquid crystal orientation, leading to a variation in overall electric resistance.
Article
Biochemistry & Molecular Biology
Manuela Curcio, Matteo Brindisi, Giuseppe Cirillo, Luca Frattaruolo, Antonella Leggio, Vittoria Rago, Fiore Pasquale Nicoletta, Anna Rita Cappello, Francesca Iemma
Summary: In this study, actively-targeted and dual stimuli-responsive lipid-polymer nanoparticles were used to deliver doxorubicin hydrochloride in triple negative breast cancer cell lines. The nanoparticles were efficiently internalized in cancer cells and modulated drug release based on the surrounding pH and redox potential. In vitro experiments demonstrated the safety and efficacy of the nanoparticles in enhancing the cytotoxic effect of the anticancer drug.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Chemistry, Multidisciplinary
Antonio Tursi, Mariafrancesca Baratta, Giovanni De Filpo, Aleksey Nezhdanov, Alexander Mashin, Fiore P. Nicoletta
Summary: In this study, the morphology and electro-optical properties of PDLCs were investigated by polymerizing epoxy/LC mixtures under different electric field strengths. It was found that the strength of the electric field during curing process had a significant impact on the droplet shape and memory states of the PDLCs.
Article
Food Science & Technology
Monica R. Loizzo, Vincenzo Sicari, Umile G. Spizzirri, Rosa Romeo, Rosa Tundis, Antonio Mincione, Fiore P. Nicoletta, Donatella Restuccia
Summary: The study found that the best ratio of extra virgin olive oil and apple vinegar in a water-oil emulsion was 85/15 (v/v), and the addition of lecithin ensured stability and viscosity over time. However, storage for 180 days resulted in an increase in lightness parameters and affected the quality of the product.
Article
Chemistry, Medicinal
Manuela Curcio, Giuseppe Cirillo, Rosario Amato, Lorenzo Guidotti, Diana Amantea, Michele De Luca, Fiore Pasquale Nicoletta, Francesca Iemma, Mercedes Garcia-Gil
Summary: This study proposes a new strategy to address the ototoxicity caused by cisplatin. By delivering lipoic acid to HEI-OC1 cells, the protective activity of lipoic acid can be stabilized, leading to significantly improved cell viability. Lipoic acid is encapsulated in hybrid liposomes and incorporated into an injectable hydrogel carrier suitable for ear applications.
Article
Biochemistry & Molecular Biology
Mariafrancesca Baratta, Antonio Tursi, Manuela Curcio, Giuseppe Cirillo, Fiore Pasquale Nicoletta, Giovanni De Filpo
Summary: Adsorption is considered the cheapest and most effective method for water decontamination. However, the powder consistency of existing materials is a major drawback. Recently, SWCNT buckypapers have been proposed as self-standing porous membranes for filtration and adsorption processes. In this study, the adsorption capacity and selectivity of GO-SWCNT buckypapers were evaluated, and their effective application for cheap and fast water decontamination from lead was confirmed.
Article
Biochemistry & Molecular Biology
Mariafrancesca Baratta, Antonio Tursi, Manuela Curcio, Giuseppe Cirillo, Aleksey Vladimirovich Nezhdanov, Alexandr Ivanovic Mashin, Fiore Pasquale Nicoletta, Giovanni De Filpo
Summary: This study investigated the adsorption capacity of graphene oxide/single-walled carbon nanotube composite membranes for the removal of NSAIDs from drinking water. The results showed that the adsorption capacities strongly depended on the graphene oxide content. The GO-SWCNT BPs exhibited high adsorption capacities for Diclofenac, Ketoprofen, and Naproxen under optimized conditions.
Editorial Material
Chemistry, Multidisciplinary
Fiore Pasquale Nicoletta, Francesca Iemma
Article
Chemistry, Multidisciplinary
Mariafrancesca Baratta, Aleksey Nezhdanov, Alexander I. Mashin, Manuela Curcio, Giuseppe Cirillo, Fiore P. Nicoletta, Giovanni De Filpo
Summary: The reduction of energy consumption is considered one of the most important measures to combat climate change. Smart windows, particularly PDLCs, provide an easy solution to increase energy efficiency and promote energy saving in various fields such as interior design, architecture, and automotive. This study focuses on the preparation and characterization of a reverse mode PDLC that allows the on-demand modification of both transmittance and color.
Article
Biochemistry & Molecular Biology
Giuseppe Cirillo, Manuela Curcio, Cesare Oliviero Rossi, Giovanni De Filpo, Mariafrancesca Baratta, Michele De Luca, Francesca Iemma, Fiore Pasquale Nicoletta
Summary: The conjugation of polyphenols is an effective method to modify the properties of biomedical materials. In this study, curcumin (CUR) was conjugated to sodium alginate (CA) and chitosan (CS) to increase the viscosity of the conjugates and control the release of loaded therapeutics. Calorimetric and rheological analyses confirmed the enhanced rigidity and interconnection between polymer chains in the conjugates. The evaluation of drug delivery performance showed sustained release profiles, indicating the potential for the development of controlled delivery systems.
Article
Biochemical Research Methods
Nazer Rajoub, Charline J. J. Gerard, Elvira Pantuso, Enrica Fontananova, Rocco Caliandro, Benny D. Belviso, Efrem Curcio, Fiore P. Nicoletta, James Pullen, Wenqian Chen, Jerry Y. Y. Heng, Sean Ruane, John Liddell, Natalie Alvey, Joop H. ter Horst, Gianluca Di Profio
Summary: This study investigates the use of template-assisted membrane crystallization for purifying monoclonal antibodies, replacing the protein A affinity stage in traditional chromatography-based purification. By using crystallization with templates attached to a membrane, protein purification can be achieved in a more cost-effective and environmentally sustainable manner.
Article
Materials Science, Multidisciplinary
Lorenzo Francesco Madeo, Manuela Curcio, Francesca Iemma, Fiore Pasquale Nicoletta, Silke Hampel, Giuseppe Cirillo
Summary: In this study, two hybrid hydrogel systems were synthesized using two crosslinking methods: physical (ionic gelation) and chemical (radical polymerization). The chemical method (H-A-GO(C)) resulted in hydrogels with higher swelling degree and pronounced pH responsivity, while the physical method (H-A-GO(P)) led to degradation under external voltages. The release profiles of the hybrid hydrogels, extensively analyzed using mathematical models, showed sustained drug release and the ability to modulate the release amount and rate by electro-stimulation of H-A-GO(C).
C-JOURNAL OF CARBON RESEARCH
(2023)
