Journal
EXPRESS POLYMER LETTERS
Volume 2, Issue 7, Pages 485-493Publisher
BUDAPEST UNIV TECHNOL & ECON
DOI: 10.3144/expresspolymlett.2008.58
Keywords
nanocomposites; polyimide; ceramic nanotubes and nanoparticles; rheology; mechanical properties
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Funding
- U.S. National Science Foundation [CBET 0317646, CBET 0752150]
- Russian Foundation of Basic Research [07-03-00846-a]
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [0752150] Funding Source: National Science Foundation
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New polyimide nanocomposites containing organically modified montmorillonite (MMT), synthetic silicate (chrysotile) nanotubes (SNT), and zirconium dioxide (ZrO(2)) were prepared to investigate the influence of the nanoparticle morphology on the nanocomposite rheology and mechanical properties under selected conditions that the materials are likely to encounter during use. The efficiency of homogeneous dispersion of the nanoparticles in the polyimide matrix was studied by measuring the rheology of model oligoimides (OI) dispersions containing the desired amounts of the nanoparticles. The OI/nanoparticles dispersions showed significant increase in complex viscosity with increasing concentration of the nanoparticles that depended strongly on the nanoparticle morphology and aspect ratio. Polyimide nanocomposite films (PI-PM) prepared from the poly(amic acid) of poly(pyromellitic dianhydride-co-4,4'-oxydianiline) (PM) filled with the desired concentration of the nanoparticles showed an increase in tensile modulus with increasing nanoparticle concentration in the order MMT>SNT>ZrO(2). In contrast to the PI-PM/MMT films, the PI-PM films filled with 10 vol% of SNT and ZrO(2) showed higher sample failure strains, suggesting that the SNT and ZrO2 may be more effective in improving the ductility of the polyimide nanocomposites for applications where the relatively brittle polyimide/MMT nanocomposites films are not useable.
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