Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2014, Issue 3, Pages 498-501Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201301372
Keywords
Synthetic methods; Allylation; C-O activation; C-C coupling; Hydrogen transfer; Iron
Categories
Funding
- National Natural Science Foundation of China (NSFC) [21162013]
- Beijing National Laboratory for Molecular Sciences (BNLMS)
Ask authors/readers for more resources
A novel and efficient allylic alkylation reaction between -activated ethers and allylsilane was realized under mild conditions through iron(III)-catalyzed Csp3-O ether bond cleavage. The present protocol provides an attractive approach for the construction of sp(3)-sp(3) C-C bonds and can be potentially applied for the selective reduction of benzyl and allyl ethers to their corresponding hydrocarbon compounds by using triethylsilane as a hydride-transfer reagent.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
