Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2012, Issue 8, Pages 1495-1498Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201101618
Keywords
Amination; Cross-coupling; Arynes
Categories
Funding
- National Nature Science Foundation of China [20932002, 20972144, 90813008, 20772188, J1030412]
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Direct base-mediated amination of aryl halides with aliphatic tertiary amines via an aryne intermediate was developed under transition-metal-free conditions. This operationally simple C-N bond-coupling protocol could tolerate a variety of functionalized aryl halides as well as several aliphatic tertiary amines. Moreover, this environmentally benign process provides a new strategy for direct C-N bond formation.
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