Palladium-Mediated Heck-Type Reactions of [(Bromodifluoromethyl)sulfonyl]benzene: Synthesis of α-Alkenyl- and α-Heteroaryl-Substituted α,α-Difluoromethyl Phenyl Sulfones

Rh-catalyzed intramolecular sp2 C–H bond difluoromethylenation

(2012) Yajun Li et al.   CHEMICAL COMMUNICATIONS

Copper-Mediated Oxidative Cross-Coupling Reaction of Terminal Alkynes with α-Silyldifluoromethylphosphonates: An Efficient Method for α,α-Difluoropropargylphosphonates

(2012) Xueliang Jiang et al.   ORGANIC LETTERS

Copper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkenes Using Nucleophilic CF3SiMe3: Efficient C(sp3)–CF3 Bond Formation

(2012) Lingling Chu et al.   ORGANIC LETTERS

Recent Advances in Palladium-Catalyzed Cascade Cyclizations

(2011) Tjøstil Vlaar et al.   ADVANCED SYNTHESIS & CATALYSIS

Intermolecular Dehydrogenative Heck Reactions

(2011) Jean Le Bras et al.   CHEMICAL REVIEWS

Synthesis of 3,7-Disubstituted Imipramines by Palladium-Catalysed Amination/Cyclisation and Evaluation of Their Inhibition of Monoamine Transporters

(2011) Helle Christensen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Friedel-Crafts-Type Alkylation with Bromodifluoro(phenylsulfanyl)methane through α-Fluorocarbocations: Syntheses of Thioesters, Benzophenones and Xanthones

(2011) Chutima Kuhakarn et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

α,α-Difluoro-α-phenylsulfanyl-α-trimethylsilylmethane as a difluoromethyl building block: A general strategy to α,α-difluoromethyl aryl ketones

(2011) Kanhokthron Boonkitpattarakul et al.   JOURNAL OF FLUORINE CHEMISTRY

Synopsis of Some Recent Tactical Application of Bioisosteres in Drug Design

(2011) Nicholas A. Meanwell   JOURNAL OF MEDICINAL CHEMISTRY

Room Temperature Aryl Trifluoromethylation via Copper-Mediated Oxidative Cross-Coupling

(2011) Todd D. Senecal et al.   JOURNAL OF ORGANIC CHEMISTRY

Cu-Mediated Chemoselective Trifluoromethylation of Benzyl Bromides Using Shelf-Stable Electrophilic Trifluoromethylating Reagents

(2011) Hiroyuki Kawai et al.   ORGANIC LETTERS

Copper-Catalyzed Trifluoromethylation of Aryl and Vinyl Boronic Acids with An Electrophilic Trifluoromethylating Reagent

(2011) Tianfei Liu et al.   ORGANIC LETTERS

Palladium-Catalyzed C–H Perfluoroalkylation of Arenes

(2011) Rebecca N. Loy et al.   ORGANIC LETTERS

Trifluoromethylation of aryl and heteroaryl halides

(2011) Sudipta Roy et al.   TETRAHEDRON

Direct ethoxycarbonyldifluoromethylation of aromatic compounds using Fenton reagent

(2011) Yuhki Ohtsuka et al.   TETRAHEDRON

Synthesis of 4-Substituted 3,3-Difluoropiperidines

(2010) Riccardo Surmont et al.   JOURNAL OF ORGANIC CHEMISTRY

Aryl−CF3Bond-Forming Reductive Elimination from Palladium(IV)

(2010) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(II)-Catalyzedortho-Trifluoromethylation of Arenes Using TFA as a Promoter

(2010) Xisheng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reductive Heck Reactions of N-Methyl-substituted Tricyclic Imides

(2010) Gokce Goksu et al.   MOLECULES

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides

(2010) E. J. Cho et al.   SCIENCE

Highly regioselective Pd-catalyzed allylic alkylation of fluorobis(phenylsulfonyl)methane

(2010) Xiaoming Zhao et al.   TETRAHEDRON LETTERS

Aromatic trifluoromethylation catalytic in copper

(2009) Masahiro Oishi et al.   CHEMICAL COMMUNICATIONS

Zn-Mediated, Pd-Catalyzed Cross-Couplings in Water at Room TemperatureWithoutPrior Formation of Organozinc Reagents

(2009) Arkady Krasovskiy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron-Deficient Phosphines Accelerate the Heck Reaction of Electronrich Olefins in Ionic Liquid

(2009) Shifang Liu et al.   LETTERS IN ORGANIC CHEMISTRY

Update 1 of: Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions

(2008) Jun-An Ma et al.   CHEMICAL REVIEWS

A New Class of Easily Activated Palladium Precatalysts for Facile C−N Cross-Coupling Reactions and the Low Temperature Oxidative Addition of Aryl Chlorides

(2008) Mark R. Biscoe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heck Couplings at Room Temperature in Nanometer Aqueous Micelles†

(2008) Bruce H. Lipshutz et al.   ORGANIC LETTERS

Olefin Cross-Metathesis Reactions at Room Temperature Using the Nonionic Amphiphile “PTS”:  Just Add Water†

(2008) Bruce H. Lipshutz et al.   ORGANIC LETTERS

Free radical (phenylsulfonyl)difluoromethylation of alkynes with PhSO2CF2I reagent: stereoselective preparation of PhSO2CF2- and CF2H-substituted alkenes

(2008) Ya Li et al.   TETRAHEDRON

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS