Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2011, Issue 15, Pages 2772-2776Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201100100
Keywords
Asymmetric catalysis; Hydrogenation; Carbene ligands; Ketones; Rhodium
Categories
Funding
- Interchim Company
- Centre National de la Recherche Scientifique (CNRS-UMR) [8182]
- Universite Paris-Sud 11
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A new and flexible procedure for the preparation of chiral azolium salts derived from (S)-pyroglutamic acid has been developed. The efficiency of these ligands has been evaluated in the metal-catalyzed asymmetric transfer hydrogenation of aromatic ketones in isopropanol. Good enantioselectivities up to 90% ee were observed.
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