Role of the Isolable Hydride Intermediate in the Hydrosilylation of Carbonyl Compounds Catalyzed by the High-Valent Mono-Oxido-Rhenium(V) Complex

High-valent oxo-molybdenum and oxo-rhenium complexes as efficient catalysts for X–H (X = Si, B, P and H) bond activation and for organic reductions

(2012) Sara C. A. Sousa et al.   CHEMICAL SOCIETY REVIEWS

Mechanistic Aspects of Hydrosilylation Catalyzed by (ArN=)Mo(H)(Cl)(PMe3)3

(2012) Andrey Y. Khalimon et al.   INORGANIC CHEMISTRY

An Efficient Iridium Catalyst for Reduction of Carbon Dioxide to Methane with Trialkylsilanes

(2012) Sehoon Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Taking the F out of FLP: Simple Lewis Acid–Base Pairs for Mild Reductions with Neutral Boranes via Borenium Ion Catalysis

(2012) Patrick Eisenberger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrosilylation of Carbonyls Catalyzed by the Rhenium(V) Oxo Complex [Re(O)(hoz)2]+—A Non-Hydride Pathway

(2012) Piao Gu et al.   ORGANOMETALLICS

Facile Catalytic Hydrosilylation of Pyridines

(2011) Dmitry V. Gutsulyak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrosilylation of epoxides catalyzed by a cationic η1-silane iridium(iii) complex

(2011) Sehoon Park et al.   CHEMICAL COMMUNICATIONS

Nonhydride Mechanism of Metal-Catalyzed Hydrosilylation

(2011) Oleg G. Shirobokov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Olefin–Borane “van der Waals Complexes”: Intermediates in Frustrated Lewis Pair Addition Reactions

(2011) Xiaoxi Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preorganized Frustrated Lewis Pairs

(2011) Federica Bertini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development and Mechanistic Investigation of a Highly Efficient Iridium(V) Silyl Complex for the Reduction of Tertiary Amides to Amines

(2011) Sehoon Park et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis Pairs beyond the Main Group: Synthesis, Reactivity, and Small Molecule Activation with Cationic Zirconocene–Phosphinoaryloxide Complexes

(2011) Andy M. Chapman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemoselective Catalytic Hydrosilylation of Nitriles

(2010) Dmitry V. Gutsulyak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The unexpected mechanism of carbonyl hydrosilylation catalyzed by (Cp)(ArN)Mo(H)(PMe3)

(2010) Oleg G. Shirobokov et al.   CHEMICAL COMMUNICATIONS

First-row transition metal catalyzed reduction of carbonyl functionalities: a mechanistic perspective

(2010) Sumit Chakraborty et al.   DALTON TRANSACTIONS

Proton-Catalyzed Hydrogenation of a d8Ir(I) Complex Yields atransIr(III) Dihydride

(2010) Michael Findlater et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide

(2010) Andreas Berkefeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cationic Silane σ-Complexes of Ruthenium with Relevance to Catalysis

(2010) Dmitry V. Gutsulyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Ionic Hydrogenation of Ketones by {[Cp*Ru(CO)2]2(μ-H)}+

(2010) Paul J. Fagan et al.   ORGANOMETALLICS

Catalysis by cationic oxorhenium(v): hydrolysis and alcoholysis of organic silanes

(2009) Rex A. Corbin et al.   DALTON TRANSACTIONS

Expanding the role of oxo-molybdenum(vi) catalysts: a DFT interpretation of X–H activation leading to reduction or oxidation

(2009) Maria José Calhorda et al.   DALTON TRANSACTIONS

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions

(2009) Aleksandr V. Marenich et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Investigations of Iridium-Mediated Reversible C−H Bond Cleavage: Characterization of a 16-Electron Iridium(III) Methyl Hydride Complex

(2009) Wesley H. Bernskoetter et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lutidine/B(C6F5)3: At the Boundary of Classical and Frustrated Lewis Pair Reactivity

(2009) Stephen J. Geier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Cr−Mn Interaction insyn-Facial [Tricarbonyl(benzyl)chromium]manganesetricarbonyl Complexes: A Non-Covalent Metal−Metal Bond

(2009) Isabella Hyla-Kryspin et al.   ORGANOMETALLICS

Steric and Electronic Effects in Half-Sandwich Ruthenium Silane σ-Complexes with Si−H and Si−Cl Interligand Interactions†

(2009) Dmitry V. Gutsulyak et al.   ORGANOMETALLICS

Reduction of Alkyl Halides by Triethylsilane Based on a Cationic Iridium Bis(phosphinite) Pincer Catalyst: Scope, Selectivity and Mechanism

(2008) Jian Yang et al.   ADVANCED SYNTHESIS & CATALYSIS

Structural and Spectroscopic Characterization of an Unprecedented Cationic Transition-Metal η1-Silane Complex

(2008) Jian Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxo and Imido Complexes of Rhenium and Molybdenum in Catalytic Reductions

(2008) Guodong Du et al.   CURRENT ORGANIC CHEMISTRY

Scope and Mechanism of the Iridium-Catalyzed Cleavage of Alkyl Ethers with Triethylsilane

(2008) Jian Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cp(Pri2MeP)FeH2SiR3:  Nonclassical Iron Silyl Dihydride

(2008) Dmitry V. Gutsulyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diversity of Catalysis by an Imido-Hydrido Complex of Molybdenum. Mechanism of Carbonyl Hydrosilylation and Silane Alcoholysis

(2008) Erik Peterson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrosilylation of Aldehydes and Ketones Catalyzed by Nickel PCP-Pincer Hydride Complexes

(2008) Sumit Chakraborty et al.   ORGANOMETALLICS