Radical Coordination Chemistry and Its Relevance to Metal-Mediated Radical Polymerization

Copper Catalyzed Atom Transfer Radical Addition (ATRA) and Cyclization (ATRC) Reactions in the Presence of Reducing Agents

(2010) William T. Eckenhoff et al.   CATALYSIS REVIEWS-SCIENCE AND ENGINEERING

Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications

(2010) Jeffrey J. Warren et al.   CHEMICAL REVIEWS

Catalyst Regeneration in Transition-Metal-Mediated Atom-Transfer Radical Addition (ATRA) and Cyclization (ATRC) Reactions

(2010) Tomislav Pintauer   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Photoactivated Biological Activity of Transition-Metal Complexes

(2010) Ulrich Schatzschneider   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Comparison of Rh−OCH3and Rh−CH2OH Bond Dissociation Energetics from Methanol C−H and O−H Bond Reactions with Rhodium(II) Porphyrins

(2010) Sounak Sarkar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exploring Chromium(III)−Alkyl Bond Homolysis with CpCr[(ArNCMe)2CH](R) Complexes

(2010) K. Cory MacLeod et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Linear Free-Energy Relationships for the Alkyl Radical Affinities of Nitroxides: A Theoretical Study

(2010) Jennifer L. Hodgson et al.   MACROMOLECULES

Controlled Radical Polymerization of Vinyl Acetate with Cyclopentadienyl Chromium β-Diketiminate Complexes: ATRP vs OMRP

(2010) Yohan Champouret et al.   ORGANOMETALLICS

Transition metal catalysts for controlled radical polymerization

(2010) Fabio di Lena et al.   PROGRESS IN POLYMER SCIENCE

Proton-Coupled Electron Transfer in Biology: Results from Synergistic Studies in Natural and Model Systems

(2009) Steven Y. Reece et al.   Annual Review of Biochemistry

Transition Metal-Catalyzed Living Radical Polymerization: Toward Perfection in Catalysis and Precision Polymer Synthesis

(2009) Makoto Ouchi et al.   CHEMICAL REVIEWS

Radical Polymerization of Vinyl Acetate with Bis(tetramethylheptadionato)cobalt(II): Coexistence of Three Different Mechanisms

(2009) K. S. Santhosh Kumar et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electronic and Steric Ligand Effects in the Radical Polymerization of Vinyl Acetate Mediated by β-Ketoiminate Complexes of Cobalt(II)

(2009) Santhosh Kumar K. S. et al.   Chemistry-An Asian Journal

Insertion of Molecular Oxygen into a Palladium(II) Methyl Bond: A Radical Chain Mechanism Involving Palladium(III) Intermediates

(2009) Luc Boisvert et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organometallic-Mediated Radical Polymerization: Developing Well-Defined Complexes for Reversible Transition Metal-Alkyl Bond Homolysis

(2009) Kevin M. Smith et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Recent developments in ruthenium anticancer drugs

(2009) Aviva Levina et al.   Metallomics

DFT Study of the Transition States and Products of Methyl Radical Addition to Olefins Coordinated in an Asymmetrical Mode to [Cp2Zr(OtBu)]+: Predictions of Reversed Regioselectivities Compared to the Noncoordinated Reactions

(2009) Faraj Hasanayn et al.   ORGANOMETALLICS

Cyclopentadienyl Chromium β-Diketiminate Complexes: Initiators, Ligand Steric Effects, and Deactivation Processes in the Controlled Radical Polymerization of Vinyl Acetate

(2009) Yohan Champouret et al.   ORGANOMETALLICS

Overview of cobalt-mediated radical polymerization: Roots, state of the art and future prospects

(2009) Antoine Debuigne et al.   PROGRESS IN POLYMER SCIENCE

Precision Control of Radical Polymerization via Transition Metal Catalysis: From Dormant Species to Designed Catalysts for Precision Functional Polymers

(2008) Makoto Ouchi et al.   ACCOUNTS OF CHEMICAL RESEARCH

Atom transfer radical addition and polymerization reactions catalyzed by ppm amounts of copper complexes

(2008) Tomislav Pintauer et al.   CHEMICAL SOCIETY REVIEWS

Cobalt-Mediated Radical Polymerization of Acrylonitrile: Kinetics Investigations and DFT Calculations

(2008) Antoine Debuigne et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic Insights into the Cobalt-Mediated Radical Polymerization (CMRP) of Vinyl Acetate with Cobalt(III) Adducts as Initiators

(2008) Antoine Debuigne et al.   CHEMISTRY-A EUROPEAN JOURNAL

Understanding Atom Transfer Radical Polymerization: Effect of Ligand and Initiator Structures on the Equilibrium Constants

(2008) Wei Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Exchange of Organic Radicals with Organo-Cobalt Complexes Formed in the Living Radical Polymerization of Vinyl Acetate

(2008) Shan Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ab Initio Evaluation of the Thermodynamic and Electrochemical Properties of Alkyl Halides and Radicals and Their Mechanistic Implications for Atom Transfer Radical Polymerization

(2008) Ching Yeh Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organo-Cobalt Mediated Living Radical Polymerization of Vinyl Acetate

(2008) Chi-How Peng et al.   MACROMOLECULES

Synthesis of Novel Well-Defined Poly(vinyl acetate)-b-poly(acrylonitrile) and Derivatized Water-Soluble Poly(vinyl alcohol)-b-poly(acrylic acid) Block Copolymers by Cobalt-Mediated Radical Polymerization

(2008) Antoine Debuigne et al.   MACROMOLECULES

Calculations on the Kinetics, Thermodynamics, and Selectivity of Methyl Radical Addition to Olefins Coordinated to d8and d0Transition-Metal Fragments: Two Distinct and Opposite anti-Evans−Polanyi Effects with Potential Practical Implications

(2008) Faraj Hasanayn et al.   ORGANOMETALLICS

DFT Study of the Products, Potential Energy Surface, and Substituent Effects for Methyl Radical Addition to [Rh(PMe3)2(CO)X] (X = Halogen or CN)

(2008) Nadeen H. Nsouli et al.   ORGANOMETALLICS

Carbon−Oxygen Bond Cleavage by Bis(imino)pyridine Iron Compounds: Catalyst Deactivation Pathways and Observation of Acyl C−O Bond Cleavage in Esters

(2008) Ryan J. Trovitch et al.   ORGANOMETALLICS

Copper(I/II) and cobalt(II) coordination chemistry of relevance to controlled radical polymerization processes

(2008) Ulrich Baisch et al.   POLYHEDRON

Addition of Alkyl Radicals to Transition-Metal-Coordinated CO:  Calculation of the Reaction of [Ru(CO)5] and Related Complexes and Relevance to Alkane Carbonylation

(2007) Faraj Hasanayn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY