Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 12, Pages 1871-1875Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201001285
Keywords
Manganese; Tungsten; Sandwich complexes; Epoxidation; Heterogeneous catalysis; Phosphotungstate
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Funding
- Department of Science and Technology (DST), New Delhi [SR/S1/IC-13/2007]
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The dimeric, tetranuclear manganese(II)-substituted sandwich-type phosphotungstate complex has been synthesized in high yield using a straightforward one-pot synthesis by reacting commercially available H-3[PW12O40] with MnCl2. The complex has been characterized by single-crystal X-ray structure analysis. The complex is oxidatively and solvolytically stable and has been used as a heterogeneous catalyst in the efficient, selective aerobic epoxidation of styrene, cyclohexene and cis-cyclooctene.
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