Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 35, Pages 5455-5459Publisher
WILEY-BLACKWELL
DOI: 10.1002/ejic.200800947
Keywords
f elements; Neodymium; Uranium; Imido complexes; Cluster compounds; Structure elucidation
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Funding
- Direction de I'Energie Nucleaire (DSOE-DEN)
- Commissariat it I'Energie Atomique for Financial support
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NdI3 reacted with 1 or 8/6 equiv. of [PhNMg(thf)], in thf or pyridine, to afford the imido Clusters [Nd-4(NPh)(n)I-4(thf)(n)] (n = 3, 4) or [Nd-6(NPh)(8)I-2(py)(6)], which display a cubane or rhombododecahedron core structure, respectively. In contrast, the tetranuclear U-IV derivative [U-4(NPh)(6)I-4(PY)(6)] was obtained from the reaction Of UI3(py)(4) with [PhNMg(thf)]. The crystal Structures of these Clusters are presented. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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