4.4 Article

Simultaneous adsorption of SO2 and NO from flue gas over mesoporous alumina

Journal

ENVIRONMENTAL TECHNOLOGY
Volume 36, Issue 5, Pages 588-594

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/09593330.2014.953600

Keywords

simultaneous adsorption; mesoporous alumina; SO2; coal combustion flue gas; NO

Funding

  1. National Natural Science Foundation [U1137603]

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Mesoporous alumina (MA) with a higher ability to simultaneously remove SO2 and NO was prepared by the evaporation-induced self-assembly process. The adsorption capacities of MA are 1.79 and 0.702 mmol/g for SO2 and NO, respectively. The Brunauer-Emmett-Teller method was used to characterize the adsorbent. Simultaneous adsorption of SO2 and NO from flue gas over MA in different operating conditions had been studied in a fixed bed reactor. The effects of temperature, oxygen concentration and water vapour were investigated. The experimental results showed that the optimum temperature for MA to simultaneously remove SO2 and NO was 90 degrees C. The simultaneous adsorption capacities of SO2 and NO could be enhanced by increasing O-2 when its concentration was below 5%. The changes of simultaneous adsorption capacities were not obvious when O-2 concentration was above 5%. The increase in relative humidity results in an increase after dropping of SO2 adsorption capacity, whereas the adsorption capacity of NO showed an opposite trend. The results suggest that MA is a great adsorbent for simultaneous removal of SO2 and NO from flue gas.

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